4.7 Article

Control of side reactions using LiNbO3 mixed/doped solid electrolyte for enhanced sulfide-based all-solid-state batteries

Related references

Note: Only part of the references are listed.
Article Nanoscience & Nanotechnology

Enhancing Moisture and Electrochemical Stability of the Li5.5PS4.5Cl1.5 Electrolyte by Oxygen Doping

Linfeng Peng et al.

Summary: This research successfully synthesized O-substituted Li5.5PS4.5-xOxCl1.5 solid electrolytes, among which Li5.5PS4.425O0.075Cl1.5 exhibits high ionic conductivity, improved moisture resistance, and enhanced electrochemical stability in higher voltage windows. Solid-state batteries using Li5.5PS4.425O0.075Cl1.5 show higher capacities and superior cyclability when operated at a high end-of-charge voltage, and exhibit outstanding performance in a wide temperature range.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Engineering, Environmental

Chlorine-rich lithium argyrodite enabling solid-state batteries with capabilities of high voltage, high rate, low-temperature and ultralong cyclability

Linfeng Peng et al.

Summary: This study successfully improved the rate capability and cyclability of solid-state batteries by synthesizing a high-conductivity chloride Li5.5PS4.5Cl1.5 electrolyte and unraveling the role of carbon in the cathode mixture.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Data-driven systematic parameter identification of an electrochemical model for lithium-ion batteries with artificial intelligence

Weihan Li et al.

Summary: This study develops a data-driven parameter identification framework for electrochemical models of lithium-ion batteries in real-world operations using artificial intelligence. The framework improves the accuracy of parameter identification and overcomes the overfitting problem caused by limited battery data.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

Synergistic effects of chlorine substitution in sulfide electrolyte solid state batteries

Eva Gil-Gonzalez et al.

Summary: The chlorine substitution effect in sulfide electrolytes improves the ionic conductivity and stability of all-solid-state batteries. Chlorine-substituted sulfide solid electrolytes can better inhibit instabilities caused by bulk decompositions and interfacial reactions through increased voltage stability. This understanding provides an important design principle for all-solid-state batteries.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

A Li-contained air-stable cathode for high-performance all-organic lithium-ion batteries

Wenwen Deng et al.

Summary: All-organic lithium-ion batteries (AOLBs) are sustainable, versatile, and potentially low-cost energy storage devices. However, their development is limited by the performance and stability of the Li-contained organic cathodes. This study introduces LiTCNQ as a new cathode material for AOLBs and demonstrates its air-stable nature and high performance.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

Aqueous electrolyte with moderate concentration enables high-energy aqueous rechargeable lithium ion battery for large scale energy storage

Xueqian Zhang et al.

Summary: This study explores the use of a new deep eutectic electrolyte and graphene coating to improve the energy density and cycle life of aqueous rechargeable lithium ion batteries. The results show that using this electrolyte and coating can significantly enhance the cycle life and energy density of the batteries.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

A multiphysics understanding of internal short circuit mechanisms in lithium-ion batteries upon mechanical stress abuse

Xudong Duan et al.

Summary: This study reveals the formation process of various internal short circuit modes in lithium-ion batteries upon abusive loading and establishes a multiphysics-coupled model to describe the evolution process of the battery, highlighting the underlying mechanism of safety issues.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

A new cyclic carbonate enables high power/low temperature lithium-ion batteries

Yunxian Qian et al.

Summary: This study addresses the issue of poor performance of lithium-ion batteries at low temperatures by designing and synthesizing a double ethylene carbonate molecule as an electrolyte additive. The electrolyte reduces interphase thickness and impedance, enabling effective charging and discharging of the battery at sub-zero temperatures.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Physical

A high-performance organic cathode customized for sulfide-based all-solid-state batteries

Weixiao Ji et al.

Summary: This article reveals for the first time the chemical incompatibility between quinone-based active materials and sulfide-based electrolytes, and reports a poly-(anthraquinonyl sulfide)-graphene nanocomposite as a customized quinone cathode exhibiting excellent performance and cycling stability.

ENERGY STORAGE MATERIALS (2022)

Review Chemistry, Physical

Garnet Solid Electrolyte for Advanced All-Solid-State Li Batteries

Laiqiang Xu et al.

Summary: This article discusses the importance of all-solid-state lithium batteries in the field of energy storage, explores the challenges faced by garnet-type solid electrolytes, and proposes prospective developments and alternative approaches to solving the issues of solid-state electrolytes.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Superionic Si-Substituted Lithium Argyrodite Sulfide Electrolyte Li6+xSb1-xSixS5I for All-Solid-State Batteries

Yongheum Lee et al.

Summary: The study investigated the high ionic conductivities of Li6+xSb1-xSixS5I using first-principles calculations and experiments, demonstrating favorable characteristics like high ionic conductivity, low activation energy, and good stability. The high Si content in the superionic conductor Li6.75Sb0.25Si0.75S5I shows substantial promise for practical use in all-solid-state Li batteries.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Electrochemistry

Electrochemical Properties of Cathode according to the Type of Sulfide Electrolyte and the Application of Surface Coating

Da Hye Yoon et al.

Summary: The electrochemical performance of all-solid-state cells based on sulfide electrolytes is significantly influenced by interfacial reactions, which are less reactive with cathodes when using argyrodite electrolyte. Introducing a Li2MoO4-LiI coating and pulverizing the electrolyte can effectively enhance the stability and capacity of the cells.

JOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY (2021)

Article Chemistry, Physical

The Working Principle of a Li2CO3/LiNbO3 Coating on NCM for Thiophosphate-Based All-Solid-State Batteries

Felix Walther et al.

Summary: This study improves the performance of all-solid-state batteries (ASSBs) by using a Li2CO3/LiNbO3 coating, which suppresses the interfacial reaction between the cathode active material and solid electrolyte, leading to a significant enhancement in battery performance.

CHEMISTRY OF MATERIALS (2021)

Article Chemistry, Physical

Tunable Lithium-Ion Transport in Mixed-Halide Argyrodites Li6-xPS5-xClBrx: An Unusual Compositional Space

Sawankumar Patel et al.

Summary: This study introduces a new compositional space of argyrodite superionic conductors, Li6-xPS5-xClBrx [0 <= x <= 0.8], with high ionic conductivity and low lithium migration barrier. Bromination treatment can maintain the parent Li6PS5Cl structure within a certain range, leading to enhanced Li+ ion dynamics and a liquid-like Li sublattice. Halogen-rich compositions induce hypercoordination and coordination entropy, enhancing Li+ ion transport in the material.

CHEMISTRY OF MATERIALS (2021)

Article Chemistry, Physical

Insight into cathode surface to boost the performance of solid-state batteries

Sixu Deng et al.

Summary: Through X-ray characterization and electrochemical analysis, it was found that residual lithium compounds on the surface of Ni-rich LiNi0.8Mn0.1Co0.1O2 (NMC811) are the main reason triggering the oxidation of sulfide solid-state electrolytes (SSEs), inducing severe side-reactions at the cathode interface and structural degradation of NMC811. Cleaning the cathode surface can significantly suppress the degradation of the cathode interface, thereby improving the performance of the battery.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Carbon Dots Evoked Li Ion Dynamics for Solid State Battery

Laiqiang Xu et al.

Summary: The study introduces the design of using carbon dots as fillers to enhance the ionic conductivity and lithium ion migration ability of solid composite electrolytes, leading to long cycling life and excellent performance of all-solid-state batteries.

SMALL (2021)

Article Chemistry, Physical

Ultra-thin free-standing sulfide solid electrolyte film for cell-level high all-solid-state lithium batteries

Gaozhan Liu et al.

Summary: By coating a thin, homogenous polydopamine layer on Li6PS5Cl electrolyte particles, this study successfully enhanced the energy density of all-solid-state lithium batteries while maintaining high cycling stability. The energy density of the full-cell was increased by reducing the thickness and weight of the electrolyte layer.

ENERGY STORAGE MATERIALS (2021)

Article Engineering, Environmental

Cathode-doped sulfide electrolyte strategy for boosting all-solid-state lithium batteries

Lei Zhou et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Review Nanoscience & Nanotechnology

Understanding interface stability in solid-state batteries

Yihan Xiao et al.

NATURE REVIEWS MATERIALS (2020)

Article Engineering, Environmental

Novel dry deposition of LiNbO3 or Li2ZrO3 on LiNi0.6Co0.2Mn0.2O2 for high performance all-solid-state lithium batteries

Young-Jin Kim et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Review Chemistry, Multidisciplinary

Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes

Abhik Banerjee et al.

CHEMICAL REVIEWS (2020)

Article Materials Science, Multidisciplinary

Ionic conduction mechanism of a lithium superionic argyrodite in the Li-Al-Si-S-O system

Wenze Huang et al.

MATERIALS ADVANCES (2020)

Article Multidisciplinary Sciences

Cathode coating using LiInO2-LiI composite for stable sulfide-based all-solid-state batteries

Hwan Wook Kwak et al.

SCIENTIFIC REPORTS (2019)

Review Chemistry, Physical

Fundamentals of inorganic solid-state electrolytes for batteries

Theodosios Famprikis et al.

NATURE MATERIALS (2019)

Article Chemistry, Physical

Elucidating Reversible Electrochemical Redox of Li6PS5CI Solid Electrolyte

Darren H. S. Tan et al.

ACS ENERGY LETTERS (2019)

Article Chemistry, Physical

Computational Screening of Cathode Coatings for Solid-State Batteries

Yihan Xiao et al.

JOULE (2019)

Article Electrochemistry

Review-Solid Electrolytes for Safe and High Energy Density Lithium-Sulfur Batteries: Promises and Challenges

Xabier Judez et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

Article Nanoscience & Nanotechnology

Degradation Mechanisms at the Li10GeP2S12/LiCoO2 Cathode Interface in an All-Solid-State Lithium-Ion Battery

Wenbo Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Materials Science, Multidisciplinary

Li2MoO4 coated Ni-rich cathode for all-solid-state batteries

Hwan Wook Kwak et al.

THIN SOLID FILMS (2018)

Article Chemistry, Physical

Li3BO3-Li2CO3: Rationally Designed Buffering Phase for Sulfide All Solid-State Li-Ion Batteries

Sung Hoo Jung et al.

CHEMISTRY OF MATERIALS (2018)

Article Chemistry, Multidisciplinary

Inducing High Ionic Conductivity in the Lithium Superionic Argyrodites Li6+x P(1-x)Ge(x)S(5)l for All -Solid-State Batteries

Marvin A. Kraft et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Electrochemistry

Review-Practical Challenges Hindering the Development of Solid State Li Ion Batteries

Kian Kerman et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

Article Chemistry, Physical

Redox-active cathode interphases in solid-state batteries

Raimund Koerver et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Review Chemistry, Physical

Recent advances in all-solid-state rechargeable lithium batteries

Chunwen Sun et al.

NANO ENERGY (2017)

Article Nanoscience & Nanotechnology

The Detrimental Effects of Carbon Additives in Li10GeP2S12-Based Solid-State Batteries

Wenbo Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Chemistry, Physical

Charged and Discharged States of Cathode/Sulfide Electrolyte Interfaces in All-Solid-State Lithium Ion Batteries

Masato Sumita et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

Article Chemistry, Multidisciplinary

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries

Yoshikatsu Seino et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Review Materials Science, Ceramics

Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries

Masahiro Tatsumisago et al.

JOURNAL OF ASIAN CERAMIC SOCIETIES (2013)

Article Chemistry, Physical

A lithium superionic conductor

Noriaki Kamaya et al.

NATURE MATERIALS (2011)

Article Electrochemistry

LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries

Narumi Ohta et al.

ELECTROCHEMISTRY COMMUNICATIONS (2007)