4.8 Article

Rhodium-Catalyzed Asymmetric Arylation-Induced Glycolate Aldol Additions of Silyl Glyoxylates

Related references

Note: Only part of the references are listed.
Review Chemistry, Inorganic & Nuclear

Transmetalation of boronic acids and their derivatives: mechanistic elucidation and relevance to catalysis

Kohtaro Osakada et al.

Summary: The Suzuki-Miyaura reaction is a useful synthetic organic reaction that forms a C(sp(2))-C(sp(2)) bond, and the catalytic cycle involves the transmetalation of aryl- and alkenylboronic acids with Pd(ii) complexes. Research has focused on understanding the mechanism of transmetalation and its fundamental role in catalytic reactions.

DALTON TRANSACTIONS (2022)

Article Chemistry, Organic

Dearomative Synthesis of Chiral Dienes Enables Improved Late-Stage Ligand Diversification

Evan T. Crawford et al.

Summary: An efficient method for the synthesis of chiral nonracemic diene ligands is presented, using an enantioselective dearomative intermolecular arene cyclopropanation of anisole. The resulting cycloheptatriene can be selectively functionalized, allowing for the synthesis of diverse symmetric and pseudo-symmetric dienes through iterative palladium-catalyzed cross-coupling reactions.

ORGANIC LETTERS (2022)

Article Chemistry, Multidisciplinary

Catalytic asymmetric addition of thiols to silyl glyoxylates for synthesis of multi-hetero-atom substituted carbon stereocenters

Mingming Guan et al.

Summary: A chiral Lewis acid-catalyzed enantioselective addition of thiols to silyl glyoxylates was developed, affording tertiary chiral alpha-silyl-alpha-sulfydryl alcohols with multi-hetero-atom carbon stereocenters in excellent yields and enantioselectivities. A series of control experiments were conducted to elucidate the reaction mechanism.

CHEMICAL SCIENCE (2021)

Article Chemistry, Inorganic & Nuclear

Synthesis and reactivity of boryloxorhodium complexes. Relevance to intermolecular transmetalation from boron to rhodium in Rh-catalyzed reactions

Yasushi Nishihara et al.

Summary: A novel dimeric boryloxorhodium complex was synthesized and used as a catalyst for the addition reaction of arylboronic acid to cyclohexene-2-one through transmetalation.

DALTON TRANSACTIONS (2021)

Article Chemistry, Organic

Organocatalytic Asymmetric Vinylogous Aldol Reaction of Allyl Aryl Ketones to Silyl Glyoxylates

Man-Yi Han et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Enantioselective 1,2-Anionotropic Rearrangement of Acylsilane through a Bisguanidinium Silicate Ion Pair

Weidi Cao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Synthesis of Complex Tertiary Glycolates by Enantioconvergent Arylation of Stereochemically Labile α-Keto Esters

Samuel L. Bartlett et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Rhodium-Catalyzed Asymmetric 1,4-Addition of α,β-Unsaturated Imino Esters Using Chiral Bicyclic Bridgehead Phosphoramidite Ligands

Ansoo Lee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Review Chemistry, Organic

Progress in Catalytic Asymmetric Protonation

Sylvain Oudeyer et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2014)

Article Chemistry, Inorganic & Nuclear

Rhodium-catalyzed arylation of acylsilanes with sodium tetraarylborates

Takanori Matsuda et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2014)

Review Chemistry, Multidisciplinary

Lactic acid as a platform chemical in the biobased economy: the role of chemocatalysis

Michiel Dusselier et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

Article Chemistry, Organic

Silyl Glyoxylates. Conception and Realization of Flexible Conjunctive Reagents for Multicomponent Coupling

Gregory R. Boyce et al.

JOURNAL OF ORGANIC CHEMISTRY (2012)

Review Chemistry, Physical

Rhodium-Catalyzed Asymmetric Arylation

Ping Tian et al.

ACS CATALYSIS (2012)

Article Chemistry, Multidisciplinary

Catalytic Enantioselective Protonation of alpha-Oxygenated Ester Enolates Prepared through Phospha-Brook Rearrangement

Masashi Hayashi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Article Chemistry, Multidisciplinary

Distinguishing Between Pathways for Transmetalation in Suzuki-Miyaura Reactions

Brad P. Carrow et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Multidisciplinary

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

Feng Cai et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Biochemistry & Molecular Biology

Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters

Yasunori Yamamoto et al.

MOLECULES (2011)

Article Chemistry, Multidisciplinary

Chiral cobalt-catalyzed enantioselective aerobic oxidation of alpha-hydroxy esters

Santosh Kumar Alamsetti et al.

CHEMICAL COMMUNICATIONS (2010)

Article Chemistry, Organic

Catalytic Redox-Initiated Glycolate Aldol Additions of Silyl Glyoxylates

Stephen N. Greszler et al.

ORGANIC LETTERS (2009)

Article Chemistry, Multidisciplinary

Enantioselective rhodium-catalyzed addition of arylboronic acids to alpha-ketoesters

Hai-Feng Duan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Review Chemistry, Multidisciplinary

Chiral olefins as steering ligands in asymmetric catalysis

Christian Defieber et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Multidisciplinary

Self-Consistent Synthesis of the Squalene Synthase Inhibitor Zaragozic Acid C via Controlled Oligomerization

David A. Nicewicz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Chemistry, Organic

TERT-BUTYL TERT-BUTYLDIMETHYLSILYLGLYOXYLATE: A USEFUL CONJUNCTIVE REAGENT

David A. Nicewicz et al.

ORGANIC SYNTHESES (2008)

Article Chemistry, Organic

Enantioselective equilibration - Access to chiral aldol adducts of mandelic acid esters

Stefan Scholtis et al.

ORGANIC LETTERS (2006)

Article Chemistry, Multidisciplinary

Three-component coupling reactions of silylglyoxylates, alkynes, and aldehydes: A chemoselective one-step glycolate aldol construction

DA Nicewicz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Article Chemistry, Multidisciplinary

Rhodium-catalyzed enantioselective reductive aldol reaction

SJ Taylor et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

Article Chemistry, Multidisciplinary

Rhodium-catalyzed asymmetric arylation of imines with organostannanes. Asymmetric synthesis of diarylmethylamines

T Hayashi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)