Related references
Note: Only part of the references are listed.
Article
Chemistry, Inorganic & Nuclear
Ying Huang et al.
Summary: Neutral homotrinuclear complexes [{Zn-3(L)(2)(mu-OAc)(2)}(2)].5EtOH and [Ni-3(L)(2)(mu-OAc)(2)(MeOH)(2)].2MeOH were synthesized and structurally characterized with X-ray diffraction. The Zn(II) and Ni(II) complexes consist of two (L)(2-) units combined with three metal(II) ions, with bridging mu-OAc- ions neutralizing the charge and stabilizing the trinuclear structure. The Zn(II) complex has mu-OAc- ions on the same side, while the Ni(II) complex has them on different sides. UV-vis absorption analysis confirmed the coordination of the ligand to Zn(II) and Ni(II) atoms, DFT calculations revealed the higher kinetic stability and lower chemical reactivity of the complexes. Fluorescence analysis showed electron transfer to the empty orbitals of Zn(II) and Ni(II) atoms. Hirshfeld surfaces and electrostatic potential analyses provided insights into the crystal structures and sites favorable for hydrogen bonds.
INORGANICA CHIMICA ACTA
(2023)
Article
Chemistry, Inorganic & Nuclear
Ya-Ting La et al.
Summary: A novel N2O3-donor aldehyde-appended salamo-like ligand H2L has been successfully designed and synthesized, which can be used to prepare two different nuclearity and extraordinary structures of copper complexes by changing the reaction conditions. The structures of these complexes were determined by single-crystal X-ray diffraction experiments. The results showed that complex 1 is a novel non-centrosymmetrical homobinuclear dimeric Cu(II) complex, while complex 2 is a novel homotrinuclear centrosymmetric sandwich-like dimeric structure.
INORGANICA CHIMICA ACTA
(2023)
Article
Chemistry, Inorganic & Nuclear
Shi-Zhen Li et al.
Summary: A penta-coordinated dinuclear Zn(II) complex and a hexa-coordinate tetranuclear Cd(II) complex have been synthesized using a single-armed salamo-based ligand and two kinds of transition metal salts. The structures of the complexes have been characterized by various analytical techniques. The Zn complex consists of a deprotonated ligand, Zn ions, a counter-anion, and a coordinated ethanol molecule. The Cd complex is composed of deprotonated ligands, Cd ions, counter-anions, and coordinated ethanol molecules.
JOURNAL OF COORDINATION CHEMISTRY
(2023)
Article
Chemistry, Physical
Ying Huang et al.
Summary: Two trinuclear Co(II) and Ni(II) complexes, [{Co3(L)2(mu-OAc)2 }2]·3CH2Cl2 (1) and [Ni3(L)2(mu-OAc)2(EtOH)2]·2EtOH (2), have been successfully synthesized using a new nonsymmetrical Salamo-type ligand H2L with Co(OAc)2·4H2O and Ni(OAc)2·6H2O. X-ray crystallography analysis revealed that complex 1 is an unsymmetric trinuclear structure with penta-coordinated and hexa-coordinated Co(II) atoms, while complex 2 is a centrosymmetrical trinuclear structure with hexa-coordinated Ni(II) atoms. Physicochemical and spectroscopic characterization confirmed the formation of chemical bonds between the phenolic oxygen atoms in the ligand H2L and the Co(II) and Ni(II) atoms.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Mathato P. Motaung et al.
Summary: An experimental and quantum chemical study was conducted on Cu(II) dithiocarbamate complexes, specifically N-butyl-N-phenyldithiocarbamate ([Cu(L-1)(2)]) and N-ethyl-N-ethanoldithiocarbamate ([Cu(L-2)(2)]), to investigate their structures in different media. The study examined the crystal structure, as well as the geometric features in polar and non-polar solvents resembling the biological system environment. Both experimental techniques, including crystallography and spectroscopy, and theoretical calculations using density functional methods were employed to analyze the structure. The results showed that the two copper complexes were semiconductors with indirect bandgaps, and the stability of [Cu(L-2)(2)] was attributed to the oxygen's s-states. Additionally, the study explored the optical properties, such as the absorption spectrum, electronic transitions, and reflectivity, providing important insights into the structural characteristics of these copper complexes when combined with experimental and theoretical findings.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Jian Zhang et al.
Summary: Two novel di- and tetra-nuclear Cu(II) complexes were synthesized and structurally characterized. The molecular structures were determined by single crystal X-ray diffraction, revealing the influence of different solvent molecules on the nuclearity of the complexes. DFT calculations and ESP studies were conducted to analyze the molecular orbitals and coordination sites, and Hirshfeld surfaces were used to quantify the weak interactions in the complexes.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Inorganic & Nuclear
Ya-Ting La et al.
Summary: A flexible polydentate Salamo-Salen-Salamohybrid ligand H(4)L containing rich pockets was designed and synthesized to obtain four novel complexes with transition metal(II) ions. The fluorescent properties of these complexes were studied with zebrafish, suggesting their potential as light-emitting materials.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Yang Zhang et al.
Summary: A fluorescent chemosensor PHS based on a novel pyridine-appended half-salamo-based compound has been developed for fast detection of Cu2+. The PHS is easy to synthesize, eco-friendly and cost effective. It demonstrates excellent selectivity and sensitivity towards Cu2+ in the mixed DMF:H2O (9:1, V/V, pH = 7.2) solution by change in fluorescence intensity.
INORGANICA CHIMICA ACTA
(2023)
Article
Pharmacology & Pharmacy
Zahra Kiani Nejad et al.
Summary: This research work presents the first report on the synthesis and stabilization of [Fe-Salophen] and [Fe-Salen] complexes through surface modification and anchoring of synthesized Schiff base ligand on the surface of graphene quantum dots (GQDs). The physicochemical properties of GQDs and the synthesized complexes were characterized using various spectroscopy and microscopy techniques. The biological activity of these complexes on MCF7 cancer cells was investigated, and the results showed that GQDs-[Fe-Salen] and GQDs-[Fe-Salophen] affected cell survival and induced early apoptosis, with higher cellular uptake observed for GQDs-[Fe-Salen].
INTERNATIONAL JOURNAL OF PHARMACEUTICS
(2023)
Article
Chemistry, Inorganic & Nuclear
Le-Chuan Feng et al.
Summary: In this study, new di- and tetranuclear Cu(II) complexes were synthesized and characterized by elemental analyses, IR and UV-vis spectra. Single crystal structure analyses showed a dinuclear Cu(II) structure for 1 and a tetranuclear Cu(II) structure for 2. Additionally, the electrochemical and fluorescence properties of 1 and 2 were investigated.
JOURNAL OF COORDINATION CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Jian Zhang et al.
Summary: Two solvent-induced Ni(II) complexes, [Ni-2(L)(mu-OAc)(CH3OH)] (1) and [Ni-2(L)(mu-OAc)(H2O)] (2), were synthesized using a bis(salamo)-like ligand H3L and Ni(OAc)(2)center dot 4H(2)O in methanol and ethanol solvents. The properties of the complexes were characterized by elemental analyses, single crystal X-ray diffraction, IR spectra, UV-vis spectra, and fluorescence spectra. Complexes 1 and 2 have similar crystal structures but different non-covalent interactions. Complex 1 forms a one-dimensional chain through pi-pi interactions, while complex 2 forms a three-dimensional supramolecular network structure through intermolecular hydrogen bonding interactions. Furthermore, fluorescence experiments showed significant quenching in 1 and 2 compared to H3L. Intermolecular forces were studied using Hirshfeld surface analysis. DFT calculations revealed high chemical reactivity and low kinetic stability in 1 and 2.
JOURNAL OF COORDINATION CHEMISTRY
(2023)
Article
Chemistry, Physical
Long-Jun Ma et al.
Summary: Two heterobimetallic complexes [Cu(II)2Ln(III)] (Ln = La and Ce) with flexible bis(salamo)-type ligand H4L, Cu(II) and Ln(III) atoms were successfully synthesized. The complexes were characterized using IR spectra, elemental analyses, UV-Vis spectroscopy, and single-crystal X-ray diffraction analyses. The Cu(II) atoms in the complexes have slightly distorted square planar geometries, while the Ln(III) atoms are located in the cavity of the ligand and coordinated with bidentate nitrate groups, forming an eleven-coordinated structure. DFT calculations and Hirshfeld surfaces analyses were performed, and the fluorescence properties were evaluated.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Li-Li Man et al.
Summary: A single-armed salamo-based fluorescence sensor QANS was designed and synthesized. QANS exhibited aggregation-induced emission (AIE) property and showed high selectivity and sensitivity for Al3+. It was successfully applied in monitoring Al3+ in actual water samples, and the convenient paper strips of QANS were used for selective monitoring of Al3+ ions.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
P. Li et al.
Summary: A new trinuclear nickel(II) complex, [{NiL(EtOH)(mu-OAc)}(2)Ni]center dot 2CH(3)CH(2)OH, was synthesized by reacting a salamo-type ligand H2L with nickel(II) acetate tetrahydrate using a wet-chemical method. The complex exhibits distorted octahedral geometries with the nickel(II) atoms located in N,O-donor cavities. The intermolecular interactions in the complex form a three-dimensional supramolecular structure, and there is a notable lone pair-pi interaction between the complex units.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
T. Zhang et al.
Summary: This study reports the formation of heterotrinuclear zinc(II)-lanthanide(III) complexes using a flexible octadentate bis(salamo)-based ligand. The analysis of intermolecular interactions provides valuable insights into the construction of supramolecular structures.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Wen-Ting Guo et al.
Summary: A novel coordination polymer CP-Cd(II) was synthesized and used as a fluorescent chemical sensor for detecting sulfur ions (S2-) and picric acid (PA). The sensor exhibited good selectivity and sensitivity for S2- and PA, and the quenching efficiency of PA remained unchanged after multiple cycles. The sensing mechanisms were explored through mass spectrometry analysis, spectroscopic studies, and density functional theory (DFT) calculations. The potential application of the sensor for detecting S2- ions and PA in environmental systems was also studied through water sample detection.
INORGANICA CHIMICA ACTA
(2023)
Article
Chemistry, Physical
Yuan-Ji Yan et al.
Summary: A di-nuclear salamo-Zn(II) complex [Zn2(L) Cl2] (1) was synthesized using a salamo-type ligand H2L containing a bare formyl group. A new ligand H2L' was produced through the destruction of the O4 coordination environment of the H2L ligand in the presence of the Claisen-Schmidt reaction catalyzed by triethylamine. This led to the self-assembly reaction and the formation of a tetra-nuclear salamo-Ni(II) complex [Ni4(L ')2(mu 2-Cl)2(mu 3-OMe)2(EtOH)2] (2).
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Ying Huang et al.
Summary: A novel salamo-type fluorescent probe NBS was successfully synthesized for selectively recognizing Cu2+ and B4O72-. The probe NBS showed fluorescence quenching upon coordination with Cu2+. The binding ratio of NBS to Cu2+ was determined to be 1:1, and the limit of detection for Cu2+ was calculated to be 3.57 x 10-8 M with an association constant of 5.45 x 104 M-1. Furthermore, NBS can also selectively detect B4O72- with a limit of detection of 7.13 x 10-8 M and an association constant of 5.66 x 104 M-1. Additionally, the probe can quantitatively detect Cu2+ in water samples.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Yu-Xin Wei et al.
Summary: A novel tetranuclear Ni(II) complex [Ni-4(L)(acac)(4)(EtOH)(2)]center dot 4CH(2)Cl(2) was synthesized using a rigid bis(salamo)-like ligand H4L and Ni(acac)2 in mixed solvents. The X-ray diffraction analysis revealed slightly distorted octahedral geometries for all Ni(II) atoms, with four Ni(II) atoms correlated through inversion. The ligand H4L and its Ni(II) complex were studied for their molecular electrostatic potential surface, Hirshfeld surface, interaction region indicator analysis, and fluorescence spectra.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Yang Zhang et al.
Summary: In this study, an elaborately designed nonsymmetric salamo-like ligand (H2L) was used to construct a novel fluorescent coordination polymer. By using the auxiliary ligand 4,4'-bipyridine, a tailored luminescent probe (Ni(II)-CP) was prepared and its structure was determined through single crystal X-ray diffraction. The Ni(II)-CP showed a slightly twisted hexa-coordinate octahedron configuration and formed an infinite one-dimensional chain-shaped structure through the intervention of the auxiliary ligand. The luminescence properties of the Ni(II)-CP demonstrated unusual selectivity, sensitivity, and recyclability for the detection of 4-nitrophenol and Cr2O7 2-. Possible fluorescence quenching mechanisms were also explored.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Wenting Guo et al.
Summary: The development of fluorescent chemical sensors for ratiometric detection of multiple metal ions or anions is in high demand, but there are still many challenges. In this study, an asymmetry salamo-type ratiometric fluorescent probe G1 was designed and synthesized for highly selective and sensitive detection of B4O7 2- and formaldehyde (HCHO). The probe showed a significant turn-off fluorescence behavior upon the introduction of B4O7 2- and a turn-on fluorescence feature when HCHO was injected.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Lin Dou et al.
Summary: A tailored Cd(II) coordination polymer, Cd(II)-CP, was successfully synthesized using the host ligand H2L and auxiliary ligand 1,4-di(pyridin-4-yl)benzene. The Cd(II)-CP exhibited a slightly twisted hexacoordinated octahedron configuration and formed an infinite 1D zigzag-like chain configuration. It showed high selectivity and sensitivity as a luminescent bifunctional chemosensor for nitroaromatic compounds and anions, with turn-off and turn-on fluorescence effects observed for picric acid and sulfide ions, respectively. This study provides new design concepts for CPs in detecting pollutants, potentially reducing health risks to humans and natural ecosystems.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Yin-Xia Sun et al.
Summary: A simple and fast-responsive fluorescent chemical sensor for JT was designed and synthesized, which showed outstanding selectivity and high sensitivity for detecting Al3+ and Fe3+. The sensor was successfully used for the rapid detection of Al3+ and continuous monitoring of Fe3+.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Le-Chuan Feng et al.
Summary: A new bis(salamo)-like compound H3L was synthesized, which exhibited significant fluorescence enhancement and color change from blue-cyan to bright green upon the addition of Zn2+ ions. The interaction mechanism between H3L and Zn2+ ions was proposed based on ESI-MS, UV-Vis spectroscopy, and DFT calculations. The in situ complex sensor L-Zn2+ formed by the coordination of H3L with Zn2+ ions showed high selectivity and sensitivity to phosphates, as demonstrated by various anion recognition experiments. Fluorescence response of H3L and L-Zn2+ was optimal in neutral and weak base environments, and simple test paper strips and real water samples were used for phosphate detection in complex environments.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Yang Zhang et al.
Summary: A novel tetra-nuclear Cu(II) salamo-like complex, [Cu4(L)2(MeOH)2]•2MeOH, containing four- and five-coordinated Cu(II) atoms, was synthesized and structurally characterized. The complex exhibited an asymmetric geometric structure with four Cu(II) atoms and two deprotonated ligand (L)4- units. Spectral analysis showed that the Cu(II) complex had low optical reaction activity. Molecular electrostatic potential analysis identified electrophilic and nucleophilic sites for hydrogen bond formation. Hirshfeld surface analysis indicated the presence of abundant hydrogen bonds in the crystal structure, making the Cu(II) complex more stable.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Hao-Ying Niu et al.
Summary: An unexpected mono-nuclear Cu(II) complex [Cu(L-1)] was synthesized using a new ligand H2L1 and Cu(II) acetate. The crystal structure analysis confirmed that the Cu(II) complex is obtained from the reaction with the ligand H2L1, not the original ligand H3L. Quantum chemical calculations revealed that the energy gap of the Cu(II) complex is reduced compared to the ligand due to orbital combination.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Physical
Li Zhao et al.
Summary: Two unusual bis(salamo)-based bis(II) complexes, [Co-2(L)(OMe)].2MeOH (1) and [Co-4(L-1)(4)(MeOH)(4)] (2), were designed, prepared, and characterized structurally. The energy gaps of the complexes were reduced compared to the ligand, and the crystal structures of the complexes were consistent with theoretical predictions. The interactions in the complexes, including H-H, C-H, and H-O interactions, were analyzed and found to be important for the construction of supramolecules.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Spectroscopy
Ya-Ting La et al.
Summary: A newly designed and synthesized Salamo-Salen-Salamo-Zn(II) complex sensor (sensor ZT) was studied for anion sensing, specifically for H2PO4- ions. The sensor showed selectivity and sensitivity towards H2PO4- ions through displacement pathways in a short time. The mechanism and binding mode of the sensor were studied using various techniques, and the sensor was found to have excellent association constant and low detection limit. Additionally, the sensor can be used for environmental monitoring and cellular distribution of H2PO4-.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Inorganic & Nuclear
Yun-Hu Deng et al.
Summary: In this study, a novel ligand H5L was designed to form two heterohexanuclear cluster complexes with zinc and calcium/strontium acetate. The IR spectral analysis and fluorescence properties of the complexes were investigated, and theoretical calculations were conducted to better understand the formation mechanism and electron distribution characteristics.
INORGANIC CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Sattar R. Majeed et al.
Summary: Three new palladium complexes with dinitrogen ligands were synthesized and tested against various cancer cell lines. The [Pd(DABA)Cl-2] complex showed the highest inhibition percentage. The hydrolysis mechanism and photophysical properties of the complexes were investigated through computational calculations, revealing the faster hydrolysis process of the Pd(DABA)Cl-2 complex.
Article
Chemistry, Applied
Ruo-Yu Li et al.
Summary: Two helical centrosymmetric homotetranuclear Cu (II) complexes were synthesized and characterized in this study. The coordination modes and molecular stabilities were analyzed through structural analysis and calculations, and the antibacterial activities were also investigated.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Li-Li Li et al.
Summary: Two Ni(II) complexes, dependent on counteranion and solvent, have been constructed using a flexible ligand. The structures of the complexes were confirmed by X-ray diffraction. The complexes exhibit different nuclearities and form stable supramolecular structures via hydrogen bonding.
INORGANICA CHIMICA ACTA
(2022)
Article
Spectroscopy
R-Y Li et al.
Summary: The optical properties of the symmetric salamo-like chemical probe (H2CS) of Cu2+ were investigated and fluorescence quenching was observed. The binding constant and LOD of Cu2+ to the H2CS sensor were calculated, and significant changes in the UV-Vis spectra were observed when Cu2+ ions were added. The fluorescence shutdown phenomenon was achieved by adding EDTA to the H2CS-Cu2+ solution.
JOURNAL OF APPLIED SPECTROSCOPY
(2022)
Article
Chemistry, Physical
Li-Ping Na et al.
Summary: This article presents a reversible fluorescence probe H2L and its nickel(II) complex for the detection of Ni2+ and HPO42- ions in aqueous medium. The probe shows high sensitivity and selectivity, and its structure has been characterized by various techniques.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2022)
Article
Chemistry, Physical
Mei Li et al.
Summary: This article introduces a colorimetric and fluorescent dual-channel chemosensor AMS for glutamic acid (Glu) detection, which displays rapid response and high selectivity for Glu. The chemosensor forms intermolecular hydrogen bonds with Glu and significantly quenches fluorescence, and can also detect glutamic acid through absorption spectroscopy.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
M. Li et al.
Summary: A novel dinuclear Ni(II) complex with two different coordination environments and geometries of Ni(II) atoms has been successfully synthesized. A 1D chain structure is also formed.
JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Dinesh Kumhar et al.
Summary: Three new copper(II) complexes containing benzoic acid (2-hydroxy-3-methoxy-benzylidene)-hydrazide (HL) have been synthesized and characterized. These complexes exhibit different coordination numbers, hydrogen bonds, and pi-pi interactions, leading to supramolecular assemblies of different dimensionalities and architectures. The molecular geometries have been calculated using density functional theory (DFT) method, and various reactivity descriptors have been evaluated. The catalytic measurements show that complex 2 displays effective and selective catalytic activity for the dismutation of superoxide anion (O·2-).
Article
Chemistry, Inorganic & Nuclear
Li-Li Man et al.
Summary: The coordination behaviors of asymmetric quinoline-decorated half-salamo-type ligand HL1 with Cu(II) complexes were studied, and two Cu(II) complexes were isolated and characterized by various spectroscopies. The unexpected cleavage of the oxime N-O bond close to quinoline ring of the ligand HL1 occurred, leading to the formation of an unexpected complex.
JOURNAL OF COORDINATION CHEMISTRY
(2022)
Article
Chemistry, Physical
Jin-Qiang Zhang et al.
Summary: A highly selective off-on fluorogenic sensor was designed and used to detect cyanide ion and cystine. The sensor was fully characterized by spectroscopy techniques and showed good sensitivity and selectivity in a mixed solvent solution.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Sha Li et al.
Summary: Eleven crystalline compounds of 4-methylbenzo[d]thiazol-2-amine with different acids were prepared and analyzed by XRD, providing insight into the assembly of 4-methylbenzo[d]thiazol-2-amine-acid complexes. FT-IR spectroscopy was used to verify the deprotonation of carboxylic groups and identify co-crystals/salts. The results showed the formation of various hydrogen bonding interactions and the role of functional groups in the stabilization of the structures.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Shan-Shan Feng et al.
Summary: Two new fluorescent chemical sensors, H4L and its L-Cu2+ complex, have been developed for the selective detection of Cu2+ and S2- ions in DMF solution. The fluorescence of the L-Cu2+ complex can be switched on by the addition of S2- ions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Ting Zhang et al.
Summary: The first 3D-3D heterobimetallic [Cu(II)(2)Mn(II)] complex was reported in this study, and its structure and intermolecular interactions were characterized using physicochemical and spectroscopic methods. The complex exhibited a two-dimensional supramolecular structure formed by intermolecular hydrogen bonding. The unusual fluorescence behavior of the complex was also investigated.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Inorganic & Nuclear
Y. -N. Yue et al.
Summary: A new bis(salamo)-type ligand and its hetero-trinuclear [Cu(II)(2)Ca(II)] complex have been designed, synthesized, and characterized using various techniques. The complex consists of Cu(II) and Ca(II) atoms with different geometries, and is bridged by nitrate groups. The study provides insights into the structural properties of the complex.
JOURNAL OF STRUCTURAL CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Li-Li Man et al.
Summary: In this study, a symmetrical N2O2-tetradentate dioxime chemical sensor H2L was synthesized for the first time. The sensor H2L demonstrated high efficiency and specificity in detecting S2- ions through dual channels of fluorescence-ultraviolet spectra. pH response experiments and H-1 NMR titration experiments were carried out to determine the recognition mechanism and pH range recognized by H2L. A new method of macro recognition using naked eye recognition and filter paper recognition was also developed. The practical application of H2L in detecting H2S was evaluated in actual water samples and identification experiments.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
(2022)
Article
Chemistry, Inorganic & Nuclear
Prakash Nayak et al.
Summary: A unique zinc salen complex based on phenanthroimidazole was synthesized and used as a photocatalyst for the cycloaddition of carbon dioxide with terminal epoxides at ambient conditions. Density functional theory (DFT) study showed the preference of the reaction pathway when photocatalyzed by zinc salen. This strategy is anticipated to aid in the design of new photocatalysts for CO2 fixation.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Lin Dou et al.
Summary: Two structurally different Cu(II) and Co(II) complexes were synthesized using a new polyhalogen-substituted unsymmetric salamo-based ligand. The complexes were characterized and their structural, absorption, and fluorescence properties were studied.
JOURNAL OF COORDINATION CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Xun Li et al.
Summary: A relatively rigid acyclic salamo-type ligand and its square planar Cu(II) complex were synthesized and characterized. The crystal structures, intermolecular interactions, and fluorescence properties of these compounds were analyzed using various techniques.
JOURNAL OF COORDINATION CHEMISTRY
(2022)
Article
Chemistry, Physical
Shi-Zhen Li et al.
Summary: Two Zn(II) complexes have been successfully synthesized, showing highly distinct configurations due to the introduction of two kinds of counter-anions. Both complexes exhibit obvious pi middotmiddotmiddot pi stacking interactions, and their fluorescence properties have been investigated.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Lijun Zhang et al.
Summary: This study investigates the co-crystallization of 6-methylpyridine-3-carboxamide with different carboxylic acids to obtain new adducts. The structures and supramolecular properties of these adducts are characterized using various techniques.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Jingxuan Zhou et al.
Summary: The present study made important progress in the construction of salts using 2-amino-5-methylthiazole. By introducing it into different carboxylic acids, a total of 12 novel salts were created. The results revealed that the aryl N in 2-amino-5-methylthiazole was the only protonated site in all salts, and the crystal packing was formed by various strong interactions. This study provides a foundation for the development of new solid forms of 2-amino-5-methylthiazole and offers new insights into its salts with carboxylic acids.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Xiu-Juan Han et al.
Summary: Two structurally novel Co(III) complexes, synthesized from pyridine-including half-salamo-like ligands, were characterized and their structural features were confirmed. The fluorescence intensities of the complexes decreased significantly compared to the ligands, suggesting charge transfer from the ligand to Co(III) ion.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Yujiu Wu et al.
Summary: The first utilization of 6-methylnicotinamide to create co-crystal/salts resulted in the generation of six novel adducts. These adducts were characterized using various techniques and their structural and supramolecular portions were fully examined. The crystal packing was found to be stabilized by strong hydrogen bonds and various other non-covalent interactions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Yong-Ning Yue et al.
Summary: A new heterobimetallic complex has been synthesized and characterized. The complex exhibits a stable structure and good thermal stability, providing a reference for future material research.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Li-Li Man et al.
Summary: A facile bifunctional half-salamo-based sensor NQS was developed for the simultaneous detection of Fe3+ and OH- ions using colorimetric and fluoremetric dual-signal sensing mode. Binding with Fe3+ resulted in the quenching of blue fluorescence signal of NQS and a distinct color change from colorless to yellow. On encountering OH-, the deprotonation of phenolic hydroxyl group of NQS led to the enhancement of green fluorescence signal and an instantaneous color change from colorless to bright yellow. Moreover, the addition of H+ could convert the colorimetric and fluoremetric sensing process of OH- by NQS.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Jian Zhang et al.
Summary: In this study, two Cu(II) complexes based on a new bis(salamo) ligand were successfully synthesized and characterized. Complex 1 is a dinuclear complex with a two-dimensional and one-dimensional network structure, while complex 2 is a tetranuclear complex with a three-dimensional and one-dimensional network structure. DFT calculations confirmed the stability of both complexes, and fluorescence spectroscopy research illustrated their luminescent properties.
Article
Spectroscopy
Wen-Kui Dong et al.
Summary: A novel and highly selective fluorescent chemical sensor for Zn2+ and phosphate anions has been synthesized and characterized. The identification processes and coordination mechanism have been explored using characterization methods. The sensors show promising potential in the detection of Zn2+ and phosphate anions.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Chemistry, Inorganic & Nuclear
Lin Dou et al.
Summary: In this study, two new coordination polymers were synthesized and characterized. The structures and properties of the polymers were investigated, revealing interesting supramolecular structures and potential applications in light emitting devices.
JOURNAL OF COORDINATION CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Nicholas M. Hein et al.
Summary: This study investigates the influence of various alkoxy substituents on the ligand electronics of salen manganese nitride complexes, including the first documentation of para Hammett value for the tert-butoxy substituent. Experimental and theoretical methods were used to provide plausible electronic structures of the dications formed during bis-oxidation of the manganese complexes.
INORGANIC CHEMISTRY
(2021)
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Chemistry, Inorganic & Nuclear
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