Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 43, Issue 8, Pages 2614-2627Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc202302010
Keywords
palladium catalysis; conjugated dienes; hydrofunctionalization; asymmetric synthesis
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This paper summarizes the development, advancements and mechanistic features of palladium-catalyzed asymmetric hydrofunctionalizations of conjugated dienes. Based on the types of allylic stereogenic centers constructed, the review is divided into six parts.
Because of the broad substrate availability, high atom economy and efficient stereocontrol, palladium-catalzyed asymmetric hydrofunctionalizations of conjugated dienes have emerged as an efficient route to construct enantioenriched allylic motifs, including allylic C-C, C-N, C-S, C-P, C-Si and C-O bonds. The development, advance and mechanistic features of this area in the past decades are summarized. Based on the types of allylic stereogenic centers constructed via this strategy, the review is divided into six parts, including asymmetric hydroalkylation, hydroamination, hydrophosphinylation, hydrosulfonylation, hydrosilylation and hydroalkoxylation.
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