4.7 Article

Enhanced performance of heterogeneous fenton-like Co-Cu catalysts for metronidazole degradation: Ethylene glycol as a superior fabrication solvent

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ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2023.110597

Keywords

Co-Cu catalysts; Metronidazole degradation; Fenton -like reaction; Hydroxyl radical; Ethylene glycol solvent

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This study investigates the influence of ethylene glycol (EG) solvent on the performance of Cu-Co catalyst for MNZ degradation. The use of EG solvent enhances catalyst surface area, exposing more active sites with higher Cu+ and Cu2+ content, resulting in improved MNZ degradation efficiency. This research provides valuable insights into catalyst design and optimization, highlighting the potential of EG solvent for industrial application in antibiotic organic pollutant remediation.
This study addresses the gap in understanding of fabrication solvent influence on Cu-Co catalyst performance for MNZ degradation. By synthesizing recyclable Cu-Co catalysts using the co-precipitation method, the study in-vestigates the impact of ethylene glycol (EG) solvent compared to conventional water (H2O) solvent. The opti-mized operational parameters resulted in stable and high MNZ degradation efficiency (above 90 % removal) with twice-feeding of 1600 ppm H2O2, pH similar to 7.15, and 50 degrees C. The use of EG solvent enhances catalyst surface area, exposing more active sites with higher Cu+ and Cu2+ content, which incorporated in CoO6 environment with promoted redox property to facilitate H(2)O(2)reaction and center dot OH production. This research contributes valuable insights into catalyst design and optimization, highlighting the potential of EG solvent for industrial application in antibiotic organic pollutant remediation.

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