Preparation of pH-sensitive composite polyethersulfone membranes embedded by Ag(I) coordination polymer for the removal of cationic and anionic dyes

A pH-sensitive polyethersulfone (PES) membrane was prepared with the aid of newly synthesized Ag(I) coordination polymer (Ag(I)-CP) particles. Indicating obvious adsorptive property toward dyes, the Ag(I)-based metalorganic framework (MOF) was selected to be used as an additive to improve the dye selectivity of PES membranes for both cationic and anionic dyes. The performance examination and characterization of prepared membranes indicated the influence of Ag(I)-CP in PES membrane improvement. The effect of feed pH approved the membrane response to pH changes in dye removal results. By adjusting feed pH based on pHpzc of Ag(I)-CP, it is possible to remove both anionic and cationic dyes (97% of acid orange 7 (AO) & and 100% of methylene blue (MB)) from the effluent along with an enhanced permeated flux. The results offered a synergism in embedding Ag (I)-CP in PES membrane in dye removal efficiency. The additive particles can be applied with their natural size (200-300 nm) without severe influence on the uniformity of the membrane morphology if the optimum Ag(I)-CP content is considered.

Automated summary

In this study, a pH-sensitive polyethersulfone membrane was improved by adding newly synthesized Ag(I)-CP particles, which showed enhanced selectivity towards dyes. It was found that adjusting the feed pH could improve the dye removal efficiency.