Evaluation of combined thermo-chemical processes for the treatment of landfill leachate using virgin and recovered FeCl3 coagulants

Sludge resulting from treatment of municipal waste landfill leachate contains suitable cationic substances such as Fe-based recovered coagulants which, if not recovered, can cause environmental problems. The present study aimed to maximise coagulant recoverability and investigate its potential reuse for the treatment of municipal waste landfill leachate. The study focused on establishing (i) the effect of mineral acids on leaching of Fe, (ii) the % of maximum recovery of Fe coagulant, (iii) the impact of ultrasound on recovery, and (iv) effectiveness of recovered coagulant when reused in coagulation-flocculation treatment of landfill leachate. Sulfuric acid outran hydrochloric acid in performance, with the acid leaching process leading to the recovery of 70.12% of Fe (acid concentration = 3.80 M, solid-to-liquid ratio = 8%, and heating time = 5 h). Subsequently, a developed acid leaching process was tested, which results showed that the highest rate of Fe recovery occurred without ultra-sound treatment, meaning the use of it could reduce the recovery rate due to the increase in the iron (III) oxide -hydroxide [Fe(OH)3] sedimentation. Comparative experiments were undertaken with the recovered and virgin coagulants. These revealed that Fe-based recovered coagulant led to the 60.21% and 91.40% removal of COD and total suspended solid respectively, while the values of the COD and total suspended solid removal with the virgin FeCl3 were 7.66% and 6.42% lower than that of Fe under optimal conditions (dosage = 9.38 g/L, pH = 8.94, settling time = 52.9 min). The present study established that Fe recovered could be exploited as an eco-friendly coagulant to replace FeCl3 in the landfill leachate treatment.

Automated summary

This study aimed to investigate the potential reuse of recovered Fe-based coagulant for the treatment of municipal waste landfill leachate. The results showed that sulfuric acid was more effective than hydrochloric acid in leaching Fe from the sludge. The highest rate of Fe recovery was achieved without ultrasound treatment. Comparative experiments revealed that the recovered coagulant led to a significant removal of COD and total suspended solid, outperforming the virgin FeCl3 under optimal conditions. This study demonstrated the feasibility and effectiveness of using recovered Fe as an eco-friendly coagulant for landfill leachate treatment.