Durable multifunctional cotton fabric with superior biocidal efficacy and flame retardancy based on an ammonium phosphate N-halamine

Multifunctional textiles have become the mainstreams along with development of textile industry and the increased need of public. But a facile fabrication method with well-balance of multiple functions is still a challenge. In this work, an ammonium salt of tris(methylphosphonate)aminomethane (TAMPU), which can directly react with cellulose molecules and transform to N-halamine antibacterial structure, was easily synthesized and used to achieve multifunctional cotton fabric. As a result, the modified cotton fabric of 15.8 % weight gain exhibited excellent fire resistance with LOI value of 33.8 % and self-extinguishing behavior. Due to the good char-forming capacity of TAMPU, strong heat suppression was achieved and the peak of heat release rate (PHRR) and total heat release (THR) were decreased by 87.6 % and 60.8 %, respectively. Besides, the modified samples presented outstanding bactericidal effects, and all of S. aureus and E. coli could be inactivated within 5 min without dissolution phenomenon. Furthermore, the TAMPU-modified cotton fabric owned good washing durability and LOI value was remained at 29.8 % after 50 washing cycles. This TAMPU multifunctional modification had slight influence on the mechanical property and air permeability of cotton fabric. Thus, this work provides a convenient and friendly way to fabricate multifunctional flame-retardant and antibacterial cotton fabric.

Automated summary

This study developed a facile method to synthesize TAMPU salt and successfully applied it for the fabrication of multifunctional cotton fabric. The modified cotton fabric exhibited excellent fire resistance and antibacterial properties, while maintaining stability after washing cycles. This research is of great significance for the fabrication of multifunctional textiles.