☆ 4.7 Review

Multivariate metal-organic frameworks generated through post-synthetic modification: impact and future directions

DALTON TRANSACTIONS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Stepwise Assembly of Quinary Multivariate Metal-Organic Frameworks via Diversified Linker Exchange and Installation

Yuchen Hu et al.

Summary: By reducing the size of the primary ligand, we synthesized NPF-320, a Zr-MOF with optimized pocket sizes. This MOF allows for the post-synthetic installation of three secondary linkers in all six permuted sequences, forming a quinary MTV-MOF. With the functionalization of these linkers, we can construct MTV-MOFs with variable porosity and unprecedented complexity and encoded synthetic sequence information.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2023)

Add to Collection

Review Chemistry, Multidisciplinary

Post-synthetic modifications in porous organic polymers for biomedical and related applications

Ji Hyeon Kim et al.

Summary: Porous organic polymers (POPs) are prepared through crosslinked polymerization of multidimensional rigid aromatic building blocks, and can be classified into crystalline COFs and other porous polymers. Due to their outstanding properties, such as high porosity and stability, POPs are being developed for applications in various scientific fields. The recently developed post-synthetic modification (PSM) strategies have allowed for advanced applications of POPs, particularly in biomedical applications, leading to a resurgence in their diverse functions.

CHEMICAL SOCIETY REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Post-synthetic modification within MOFs: a valuable strategy for modulating their ferroelectric performance

Meiying Liu et al.

Summary: Ferroelectrics, including MOF materials, are promising functional materials with wide applications. Post-synthetic modification of MOFs is an efficient tool to design new MOF ferroelectrics with improved properties. The strategies of metal-ion doping, ligand modification, and guest molecule tuning can enhance the overall structure's polarizability, leading to enhanced ferroelectricity.

CRYSTENGCOMM (2022)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Multivariate metal-organic framework MTV-MIL-101 via post-synthetic cation exchange: is it truly achievable?

Mahmoud Y. Zorainy et al.

Summary: The post-synthetic exchange (PSE) method is an effective approach to modify metal-organic frameworks (MOFs). The solvent-assisted cation substitution (SACS) technique can prepare mixed-metal multivariate MOFs (MTV-MOFs), but it is not applicable to all MOFs. This study successfully achieved mixed-metal MIL-101 (Cr/Fe) by changing the solvent and reaction conditions.

DALTON TRANSACTIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Heterometallic Molecular Complexes Act as Messenger Building Units to Encode Desired Metal-Atom Combinations to Multivariate Metal-Organic Frameworks

Clara Lopez-Garcia et al.

Summary: A novel synthetic approach is described for the targeted preparation of multivariate metal-organic frameworks (MTV-MOFs) with specific combinations of metal elements, providing more flexibility for the structure of building units by preserving specific metal element combinations during the synthesis process.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Chemistry, Physical

Sequence control of metals in MOF by coordination number precoding for electrocatalytic oxygen evolution

Hongnan Jia et al.

Summary: The study achieved precise positioning of different metals in multivariate metal-organic frameworks, forming an alternating sequence to improve the efficiency of oxygen evolution reaction.

CHEM CATALYSIS (2022)

Add to Collection

Article Engineering, Environmental

Synthesis of metal-organic framework HKUST-1 via tunable continuous flow supercritical carbon dioxide reactor

Elizabeth G. Rasmussen et al.

Summary: This study presents a rapid synthesis of high-quality copper-based MOFs in a continuous flow supercritical carbon dioxide reactor, evaluating the effects of different conditions on the properties of MOFs. The experiments demonstrated that high-quality MOFs can be obtained with a residence time in the range of 70-170 seconds using scCO(2) assisted synthesis.

CHEMICAL ENGINEERING JOURNAL (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Post-Synthetic Modification of Metal-Organic Frameworks Toward Applications

Sukhendu Mandal et al.

Summary: Post-synthetic modification (PSM) is a useful technique for preparing new MOFs with enhanced properties by modifying linkers and metal nodes. Widening applications of MOFs with compatible metals or ligands through PSM shows considerable potential for introducing desired properties and increasing structural stability.

ADVANCED FUNCTIONAL MATERIALS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

25 Years of Reticular Chemistry

Ralph Freund et al.

Summary: The core of reticular chemistry has brought precision and expertise of organic and inorganic synthesis to the solid state. The most profound scientific innovation of this field has been the design strategies for the synthesis of extended crystalline solids through strong directional bonds, highlighting the different classes of reticular materials developed and how complexity can be introduced into their backbones. Structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Engineering, Environmental

Efficient biofuel production by MTV-UiO-66 based catalysts

Asmaa Jrad et al.

Summary: This study focuses on developing highly defected and functionalized metal-organic framework structures for catalyzing esterification reactions in biofuel production. The multivariate approach and modulation synthesis method lead to structures with catalytic activity higher than those of highly defective fully functionalized structures, bridging the gap between homogeneous and heterogeneous catalysis for efficient biofuel production. The research also suggests a weighted linear regression model to predict catalytic conversion based on specific parameters governing MOF catalyst activity, emphasizing the importance of active sites density over surface area or catalyst loading.

CHEMICAL ENGINEERING JOURNAL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Vapor Transport Deposition: Vapor Transport Deposition of Highly Efficient Sb 2 (S,Se) 3 Solar Cells via Controllable Orientation Growth (Adv. Funct. Mater. 28/2021)

Yanlin Pan et al.

ADVANCED FUNCTIONAL MATERIALS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Post-Synthetic Modification Unlocks a 2D-to-3D Switch in MOF Breathing Response: A Single-Crystal-Diffraction Mapping Study

Elliot J. Carrington et al.

Summary: Post-synthetic modification of the interpenetrated diamondoid metal-organic framework leads to the transition from predominantly 2D breathing motion to a distinct 3D breathing motion. This indicates a decoupling of the pore-width and pore-length breathing motions, as revealed by single-crystal diffraction studies.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Large-Scale Production of Hierarchically Porous Metal-Organic Frameworks by a Reflux-Assisted Post-Synthetic Ligand Substitution Strategy

Guorui Cai et al.

Summary: A versatile post-synthetic ligand substitution strategy has been developed to convert typical microporous MOFs into hierarchically porous metal-organic frameworks (HP-MOFs) in a simple reflux system, enabling mass production at levels exceeding 10 grams. The resulting HP-MOFs feature intrinsic micropores and abundant defective mesopores, facilitating the transport and activation of large substrates for stable and efficient heterogeneous catalysis. This strategy opens up new possibilities for fast, facile, general, and scale-up production of HP-MOFs and related composites, expanding the applications of conventional microporous MOF-based materials.

ACS CENTRAL SCIENCE (2021)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Post-synthetic modifications (PSM) on metal-organic frameworks (MOFs) for visible-light-initiated photocatalysis

Yuhuan Qin et al.

Summary: Utilizing solar energy through photocatalysis is a promising strategy for addressing energy shortages and environmental issues. Metal-organic frameworks (MOFs) are emerging as a new type of photocatalytic material, with post-synthetic modifications (PSM) being a powerful strategy for fabricating photoactive MOFs based on existing MOFs. Various PSM strategies, including coordination on unsaturated metal sites, metalation on open coordinated sites, and ligand exchange, have been summarized for the development of photoactive MOFs.

DALTON TRANSACTIONS (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Modulation of CO2 adsorption in novel pillar-layered MOFs based on carboxylate-pyrazole flexible linker

Andres Lancheros et al.

Summary: This study presents three new MOFs with pillar-paddlewheel structures that exhibit high crystalline stability and CO2 adsorption capacity, making them potential materials for CO2 capture.

DALTON TRANSACTIONS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Aqueous Flow Reactor and Vapour-Assisted Synthesis of Aluminium Dicarboxylate Metal-Organic Frameworks with Tuneable Water Sorption Properties

Timothee Stassin et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Postsynthetic Modification: An Enabling Technology for the Advancement of Metal-Organic Frameworks

Mark Kalaj et al.

ACS CENTRAL SCIENCE (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Fabrication of a Luminescence-Silent System Based on a Post-Synthetic Modification Cd-MOFs: A Highly Selective and Sensitive Turn-on Luminescent Probe for Ascorbic Acid Detection

Jiannan Xiao et al.

INORGANIC CHEMISTRY (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Post-synthetic modification of covalent organic frameworks

Jose L. Segura et al.

CHEMICAL SOCIETY REVIEWS (2019)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Post-synthetic Modification of a Two-Dimensional Metal-Organic Framework via Photodimerization Enables Highly Selective Luminescent Sensing of Aluminum(III)

Wu-Xiang Li et al.

INORGANIC CHEMISTRY (2018)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Highly sensitive and selective detection of mercury (II) based on a zirconium metal-organic framework in aqueous media

Xin Zhang et al.

JOURNAL OF SOLID STATE CHEMISTRY (2017)

Add to Collection

Article Polymer Science

Poly(acryloyl hydrazide), a versatile scaffold for the preparation of functional polymers: synthesis and post-polymerisation modification

Daniel N. Crisan et al.

POLYMER CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Versatile Tailoring of NH2-Containing Metal-Organic Frameworks with Paddle-Wheel Units

Xiang-Guang Guo et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Postsynthetic Tuning of Metal-Organic Frameworks for Targeted Applications

Timur Islamoglu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Precise Modulation of the Breathing Behavior and Pore Surface in Zr-MOFs by Reversible Post-Synthetic Variable-Spacer Installation to Fine-Tune the Expansion Magnitude and Sorption Properties

Cheng-Xia Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal-Organic Framework Crystals

Alejandro M. Fracaroli et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Deciphering the Spatial Arrangement of Metals and Correlation to Reactivity in Multivariate Metal-Organic Frameworks

Qi Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Multidisciplinary Sciences

Continuous, One-pot Synthesis and Post-Synthetic Modification of NanoMOFs Using Droplet Nanoreactors

Sachin R. Jambovane et al.

SCIENTIFIC REPORTS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Solvent-Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal-Organic Frameworks

Olga Karagiaridi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Add to Collection

Review Chemistry, Multidisciplinary

Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement

Pravas Deria et al.

CHEMICAL SOCIETY REVIEWS (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Metal-Organic Frameworks Containing (Alkynyl)Gold Functionalities: A Comparative Evaluation of Solvent-Assisted Linker Exchange, de Novo Synthesis, and Post-synthesis Modification

Sherzod T. Madrahimov et al.

CRYSTAL GROWTH & DESIGN (2014)

Add to Collection

Article Polymer Science

Post-synthetic modification of conjugated microporous polymers

Thanchanok Ratvijitvech et al.

POLYMER (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Enhancing optical absorption of metal-organic frameworks for improved visible light photocatalysis

Maxim A. Nasalevich et al.

CHEMICAL COMMUNICATIONS (2013)

Add to Collection

Article Multidisciplinary Sciences

Mapping of Functional Groups in Metal-Organic Frameworks

Xueqian Kong et al.

SCIENCE (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis and post-synthetic modification of MIL-101(Cr)-NH2 via a tandem diazotisation process

Dongmei Jiang et al.

CHEMICAL COMMUNICATIONS (2012)

Add to Collection

Article Chemistry, Physical

Post-Synthetic Modifications of Framework Metal Ions in Isostructural Metal-Organic Frameworks: Core-Shell Heterostructures via Selective Transmetalations

Xiaokai Song et al.

CHEMISTRY OF MATERIALS (2012)

Add to Collection

Article Chemistry, Inorganic & Nuclear

A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

Qingxia Yao et al.

DALTON TRANSACTIONS (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical Activation of a Metal-Organic Framework to Reveal Functionality

Kristine K. Tanabe et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Add to Collection

Article Chemistry, Physical

Post-synthetic modification of the metal-organic framework compound UiO-66

Mathivathani Kandiah et al.

JOURNAL OF MATERIALS CHEMISTRY (2010)

Add to Collection

Article Multidisciplinary Sciences

Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks

Hexiang Deng et al.

SCIENCE (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Post-Synthetic Modification of Tagged Metal-Organic Frameworks

Andrew D. Burrows et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Add to Collection

Article Chemistry, Physical

Syntheses and characterization of microporous coordination polymers with open frameworks

K Seki et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2002)

Add to Collection

© Peeref 2019-2024. All rights reserved.