4.6 Article

Micelle-aided quantitatively controllable light amplification of a water-insoluble pyrene derivative

Journal

NEW JOURNAL OF CHEMISTRY
Volume 47, Issue 43, Pages 19818-19821

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3nj03882c

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This research investigates the influence of micelle charge and length on fluorescence performance, and finds that the fluorescence quantum yield is significantly enhanced with excellent thermal stability beyond the critical micellar concentration.
A water-insoluble pyrene derivative, prone to aggregation-caused quenching, regains fluorescence on micelle incorporation. This research explores micelle charge and length dependency by titrating the dye with cationic, anionic, and neutral micelles, revealing enhanced photoluminescence quantum yield (0.01 to 0.54) beyond the critical micellar concentration with excellent thermal stability. A water insoluble pyrene derivative, prone to aggregation-caused quenching, regains fluorescence on micelle incorporation with enhanced photoluminescence quantum yield.

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