Mechanism of regulating pore structure of polyethyleneimine modified mesoporous silica foam

A novel mesoporous silica foam (MCF) with a specific surface area of 712.5 m(2)/g and a pore volume of 2.44 cm(3)/g is synthesized by using triblock copolymer poly (ethylene oxide, polypropylene oxide and ethylene oxide, P123) as template and TEOS (C8H20O4Si) as silicon source. The effect of polyethylenimide (PEI) modified MCF on nanoscale pore structure is studied by positron annihilation lifetime spectroscopy (PALS) and conventional characterization methods, such as N-2 adsorption desorption, transmission electron microscopy, thermogravimetric analysis and Fourier transform infrared spectroscopy. The results show that the synthesized MCF has an obvious disordered mesoporous structure, and a continuous porous network with window connection between the pores is formed. Meanwhile, it can be seen directly that PEI is successfully introduced into MCF pore channels. In order to evaluate the pore size and its distribution more comprehensively, the mechanism of positron annihilation which is highly sensitive to nanometer scale open volumes in PEI loaded MCF is studied. It is found that there are two long life components tau(3) and tau(4), indicating the micropores and mesopores co-existing in the sample. Furthermore, the introduction of PEI molecules results in a significant decrease in tau(3) and tau(4), and the lifetime values are then corrected by using the positron annihilation rate formula in pure gas to calculate the pore size. The results show that the pore size gradually decreases with the filling of the organic molecule PEI. This provides a new insight into the mechanism of regulating the pore structure of MCF by polyethyleneimine modification, as well as the characterization of pore structure in organic-modified mesoporous molecular sieves.

Automated summary

A novel mesoporous silica foam modified by polyethyleneimine (PEI) was synthesized and characterized. The foam showed an obvious disordered mesoporous structure and a continuous porous network. The mechanism of positron annihilation was used to evaluate the pore size and its distribution comprehensively.