4.6 Article

Unravelling the effect of benzoquinone intercalators on the aqueous zinc-ion storage performance toward a vanadium pentoxide cathode

Related references

Note: Only part of the references are listed.
Article Nanoscience & Nanotechnology

Molecular Engineering Design for High-Performance Aqueous Zinc-Organic Battery

Tianjiang Sun et al.

Summary: Novel small sulfur heterocyclic quinones (4S6Q and 4S4Q) have been developed as cathode materials for aqueous zinc organic batteries. These compounds exhibit improved conductivity and dissolution inhibition due to the presence of conjugated thioether (-S-) bonds as connected units. The batteries based on these compounds show satisfactory electrochemical performance, including high discharge capacity, excellent rate capability, and superlong cycle life. The 4S6Q compound also demonstrates H+-storage mechanism and its battery can work at extremely low temperatures with high discharge capacity.

NANO-MICRO LETTERS (2023)

Review Nanoscience & Nanotechnology

Designing modern aqueous batteries

Yanliang Liang et al.

Summary: The emergence of new materials and cell designs has made aqueous batteries competitive candidates for reliable and affordable energy storage. This review critically examines scientific advances and explores future research prospects.

NATURE REVIEWS MATERIALS (2023)

Article Chemistry, Physical

Cobalt-doped MoS2•nH2O nanosheets induced heterogeneous phases as high-rate capability and long-term cyclability cathodes for wearable zinc-ion batteries

Fan Liu et al.

Summary: An effective strategy of cobalt-doped MoS2 nanosheets directly grown on carbon nanotube fibers was proposed to develop efficient cathodes for fiber-shaped aqueous zinc-ion batteries (FAZIBs). The introduction of cobalt-ion activates the transformation of MoS2 crystal structure and expands the interlayer spacing, resulting in remarkable capacity, high rate capability, and impressive durability.

ENERGY STORAGE MATERIALS (2023)

Article Green & Sustainable Science & Technology

All-temperature zinc batteries with high-entropy aqueous electrolyte

Chongyin Yang et al.

Summary: The global electrification of transportation and the increasing demand for grid energy storage are driving the growth of batteries worldwide. However, the supply chain of Li-ion batteries is facing challenges in sourcing essential and scarce materials. Therefore, there is a growing incentive to develop more sustainable battery chemistries.

NATURE SUSTAINABILITY (2023)

Article Chemistry, Multidisciplinary

Enhanced H plus Storage of a MnO2 Cathode via a MnO2 Nanolayer Interphase Transformed from Manganese Phosphate

You Zuo et al.

Summary: In this study, a manganese phosphate nanolayer was synthesized on a MnO2 cathode, which could be transformed into a delta-MnO2 nanolayer interphase. This interphase with abundant interlayer water significantly enhanced H+ (de)insertion in the MnO2 cathode, leading to a kinetics conversion and improved rate and cycle performances.

ACS NANO (2023)

Article Chemistry, Multidisciplinary

Carbon Nitride Pillared Vanadate Via Chemical Pre-Intercalation Towards High-Performance Aqueous Zinc-Ion Batteries

Yue Xu et al.

Summary: Through a facile self-engaged hydrothermal strategy, oxygen-deficient vanadate pillared by carbon nitride (C3N4) is utilized as the cathode material for aqueous zinc-ion batteries (AZIBs), which enhances the Zn-ion storage ability and conductivity of the vanadate.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Multidisciplinary Sciences

Intercalant-induced V t2g orbital occupation in vanadium oxide cathode toward fast-charging aqueous zinc-ion batteries

Yixiu Wang et al.

Summary: In this study, NH4+-intercalated vanadium oxide (NH4+-V2O5) is designed as a cathode material for high-rate ZIBs. The insertion of NH4+ promotes electron transition to the 3dxy state of V t2g orbital in V2O5, leading to accelerated electron transfer and Zn-ion migration.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2023)

Article Chemistry, Physical

Ultrafast 3D Hybrid-Ion Transport in Porous V2O5 Cathodes for Superior-Rate Rechargeable Aqueous Zinc Batteries

Tianhao Wang et al.

Summary: In this study, hierarchically porous V2O5 nanosheets vertically grown on carbon cloth were prepared, providing additional ion-diffusion channels and abundant active sites. The V2O5/C electrode exhibited exceptional high-rate capability and ultralong cycling durability in rechargeable aqueous zinc-based batteries. Moreover, the quasi-solid-state wearable zinc batteries employing the porous V2O5/C cathode demonstrated respectable performance even under severe deformations and low temperatures.

ADVANCED ENERGY MATERIALS (2023)

Article Chemistry, Physical

Enabling Multi-electron Reactions in NASICON Positive Electrodes for Aqueous Zinc-Metal Batteries

Kaidi Wang et al.

Summary: In this study, the effect of Cr substitution on the performance of Na3V2-xCrx(PO4)(3) cathode material for aqueous zinc-metal batteries was investigated. It was found that the Cr substitution significantly improved the rate capability and cycling stability, with the optimal Na3V1.5Cr0.5(PO4)(3) electrode demonstrating 68% capacity retention after 10,000 cycles at 1000 mA g(-1). The research also revealed a two-electron reaction mechanism for Zn-ion storage in NASICON-type cathodes, demonstrating the feasibility of multi-electron reactions in aqueous zinc batteries and providing insights for the design of advanced cathode materials for other aqueous batteries.

ACS ENERGY LETTERS (2023)

Article Chemistry, Multidisciplinary

Unlocking the Capacity of Vanadium Oxide by Atomically Thin Graphene-Analogous V2O5•nH2O in Aqueous Zinc-Ion Batteries

Danyang Zhao et al.

Summary: The capacity increase of classical vanadium oxide cathode in aqueous Zn-ion batteries (AZIBs) is achieved by designing atomic thickness of 2D structure, introducing abundant Zn2+ storage sites. The work also reveals the Zn2+ storage mechanism and introduces carbon nanotubes (CNTs) for large-scale cathode fabrication. The hybrid cathode exhibits ultra-stable cycling, excellent rate capability, and high energy density.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Multidisciplinary

Anomalous Zn2+ Storage Behavior in Dual-Ion-In-Sequence Reconstructed Vanadium Oxides

Hanmei Jiang et al.

Summary: In this study, a new dual-ion-in-sequence intercalation strategy is proposed to address the structural instability and sluggish diffusion kinetics of vanadium oxides in ZIBs. The Zn2+ storage mechanism evolves from solid-state ion diffusion kinetic into intercalation pseudocapacitance, resulting from the enlarged interlayer spacing. The improved ionic diffusivity, intercalation pseudocapacitance, and fast charge transferability contribute to the impressive rate capability and cycling stability of the ZIBs.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Engineering, Environmental

Enhanced charge transfer and reaction kinetics of vanadium pentoxide for zinc storage via nitrogen interstitial doping

Xuena Xu et al.

Summary: In this study, nitrogen-doped V2O5 is introduced as the cathode material for aqueous zinc-ion batteries. The N-doping improves electronic conductivity and facilitates Zn2+ diffusion by lowering the bandgap energy of V2O5 and changing its diffusion pathway. Furthermore, N-doping enhances the structural stability of the electrode material, leading to excellent electrochemical properties.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

Long-lifespan benzoquinone-intercalated vanadium oxide with vacancies and disorders on the (00l) facets for efficient sodium-ion battery: A facile approach to Na+ capture and pre-sodiation

Rui Tang et al.

Summary: A facile one-step hydrothermal method was used to synthesize m-BQ-V2O5 hierarchical microflowers with large lattice spacing and crystalline vacancies. The successful intercalation of m-BQ into V2O5 elongates the V-O bonds, resulting in unsaturated V centers and high storage capacity. The layered V-O-V framework prevents the leaching of m-BQ into the electrolyte and provides improved cycle stability.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Environmental

Benzoquinone-intercalated vanadium oxide in the electrolyte with Al3+ for zinc-ion storage: dual-pillar effect and reversible disorder-order conversion

Kai Li et al.

Summary: A new material (1, 2, 3-BQ)-VO has been synthesized by hydrothermal technique with pre-intercalation of BQ organic species into layered vanadium oxide, and Al3+ ions were inserted to improve the cycling performance and storage capacity of the material.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Physical

Layer symmetry and interlayer engineering of birnessites towards high-performance rechargeable aqueous Zn-MnO2 batteries

Jingyi Ding et al.

Summary: Rechargeable aqueous Zn-MnO2 batteries are promising for large-scale energy storage, but the issues of phase transition and structural collapse of MnO2 cathodes still exist. Intercalation of layered MnO2 has become the mainstream strategy, but the characteristics of Mn octahedral layers are often neglected. In this study, the researchers elucidate the impact of layer symmetry on the electrochemical performance of birnessites. The hexagonal birnessite with stabilized Mn(II) ions exhibits better charge storage performance than its monoclinic precursor, due to the generation of layer cation vacancies, interlayer Mn(II) ions, and nanosized morphology. The work provides a new approach for designing high-performance layered cathode materials.

NANO ENERGY (2023)

Article Chemistry, Multidisciplinary

Organic-Inorganic Hybrid Cathode with Dual Energy-Storage Mechanism for Ultrahigh-Rate and Ultralong-Life Aqueous Zinc-Ion Batteries

Xuemei Ma et al.

Summary: This work introduces organic-inorganic hybrid cathodes with a dual energy-storage mechanism for aqueous zinc-ion batteries, providing high specific capacity, elevated voltage, and excellent long-term cycle stability. Density functional theory calculations show remarkable electronic conductivity with an ultralow diffusion barrier, opening new research directions in high-energy secondary batteries.

ADVANCED MATERIALS (2022)

Article Chemistry, Applied

Quench-tailored Al-doped V2O5 nanomaterials for efficient aqueous zinc-ion batteries

Hanmei Jiang et al.

Summary: This study addresses the bottleneck issue in the development of high-performance ZIBs by modifying the surface chemistry of V2O5 cathode nanomaterial. The doping of Al ions and the formation of oxygen vacancies improve the electrical conductivity and Zn2+ diffusion rate of V2O5, resulting in superior electrochemical performance.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Green & Sustainable Science & Technology

Understanding intercalation chemistry for sustainable aqueous zinc-manganese dioxide batteries

Yifei Yuan et al.

Summary: Rechargeable aqueous Zn-MnO2 technology combines favorable sustainability characteristics, including safety, cost, and environmental compatibility. Advanced characterizations and theoretical calculations provide fresh insight into the charge storage mechanism, closing an ongoing debate and suggesting ways forward.

NATURE SUSTAINABILITY (2022)

Article Chemistry, Multidisciplinary

Van der Waals Interaction-Driven Self-Assembly of V2O5 Nanoplates and MXene for High-Performing Zinc-Ion Batteries by Suppressing Vanadium Dissolution

Huan Liu et al.

Summary: The design of a Ti3C2Tx MXene layer on V2O5 nanoplates surface in VPMX materials can suppress vanadium dissolution, improve host electrochemical kinetics, and facilitate interfacial Zn 2+ diffusion with the help of lubricated water molecules, leading to enhanced rate capability for AZIBs.

ACS NANO (2022)

Article Chemistry, Physical

Understanding the Dissolution and Phase Transformation Mechanisms in Aqueous Zn/α-V2O5 Batteries

Kaiyue Zhu et al.

Summary: Anhydrous alpha-V2O5 cathodes in aqueous zinc-ion batteries are hindered by poor cycle life, but understanding dissolution mechanisms and phase transitions can lead to the development of high-capacity systems; H-V2O5 emerges as the active material for Zn2+/H+ storage due to favorable intercalation chemistry, providing a pathway for the advancement of these batteries.

CHEMISTRY OF MATERIALS (2021)

Article Energy & Fuels

Regulating electrodeposition morphology in high-capacity aluminium and zinc battery anodes using interfacial metal-substrate bonding

Jingxu Zheng et al.

Summary: The study presents a novel approach to control reversible metal electrodeposition by promoting oxygen-mediated chemical bonding, leading to improved reversibility and cycle life of aluminum and zinc anodes, ultimately enhancing battery performance.

NATURE ENERGY (2021)

Article Chemistry, Multidisciplinary

Oxygen Defects Engineering of VO2•xH2O Nanosheets via In Situ Polypyrrole Polymerization for Efficient Aqueous Zinc Ion Storage

Zhengchunyu Zhang et al.

Summary: A new cathode material, oxygen-deficient hydrate vanadium dioxide with polypyrrole coating, has been successfully designed for aqueous zinc-ion batteries, demonstrating improved surface adsorption and internal diffusion of Zn2+ as well as enhanced electrical conductivity and suppressed cathode dissolution. This material shows promising performance in terms of reversible capacity, energy density, and long cycle life, paving the way for advanced AZIBs.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

A Universal Compensation Strategy to Anchor Polar Organic Molecules in Bilayered Hydrated Vanadates for Promoting Aqueous Zinc-Ion Storage

Fang Wan et al.

Summary: Introducing organic molecules with high and low polar groups into the interlayer of layered vanadium oxides can enhance electrochemical performance and promote reversible Zn2+ transfer. The cathode material AlxV2O5 designed based on this strategy shows improved performance, and the pouch cell assembled with dendrite-free N-doped carbon nanofiber@Zn anode exhibits a higher energy density.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Understanding and Calibration of Charge Storage Mechanism in Cyclic Voltammetry Curves

Xiangjun Pu et al.

Summary: This work successfully calibrates the different CSM contributions of three typical cathode materials and achieves a good distinction of physical capacitance, pseudo-capacitance, and diffusive contributions to the total capacity through special treatments and a non-linear fitting algorithm. It corrects misunderstanding concepts about pseudo-capacitance contribution and recognizes the essence of CSM in electrode materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Sub-Thick Electrodes with Enhanced Transport Kinetics via In Situ Epitaxial Heterogeneous Interfaces for High Areal-Capacity Lithium Ion Batteries

Shuhui Zhou et al.

Summary: This study introduces a new concept of sub-thick electrodes to mitigate the Li-ion storage performance of electrodes. By using commercial nickel foam (NF) to develop a monolithic 3D anode with rich in situ heterogeneous interfaces (Cu3P-Ni2P-NiO, denoted NF-CNNOP), the adhesive force of the active materials on NF is reinforced and additional capacity is contributed to the electrode. The enhanced Li-ion storage capability is attributed to the in situ interfacial engineering within the NiO, Ni2P, and Cu3P and the 3D consecutive electron conductive network.

SMALL (2021)

Article Chemistry, Physical

Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode

Xinyue Liang et al.

Summary: This study presents a promising binder-free V2O5 nanorods cathode material for aqueous/quasi-solid-state Zn ion batteries, exhibiting excellent high capacity, robust long-term life span, and impressive energy density. The innovative strategy of oxygen defect modulation and phosphorus doping leads to improved performance of metal oxide electrodes, paving the way for the development of efficient flexible energy storage devices and wearable electronics technology.

NANO ENERGY (2021)

Article Chemistry, Physical

Revealing the impacts of oxygen defects on Zn2+ storage performance in V2O5

Jin Cao et al.

Summary: Introducing oxygen defects into vanadium pentoxide can significantly enhance the performance of zinc-ion batteries, including increasing interlayer spacing, lowering diffusion energy barriers, improving electron transport and storage capabilities, and enhancing cycling stability.

MATERIALS TODAY ENERGY (2021)

Review Chemistry, Multidisciplinary

Designing High Performance Organic Batteries

Yuan Chen et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

Article Chemistry, Physical

Catalyzing zinc-ion intercalation in hydrated vanadates for aqueous zinc-ion batteries

Chaofeng Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Physical

A Hollow-Shell Structured V2O5 Electrode-Based Symmetric Full Li-Ion Battery with Highest Capacity

Chengrui Wang et al.

ADVANCED ENERGY MATERIALS (2019)

Article Chemistry, Multidisciplinary

Reconstructed Orthorhombic V2O5 Polyhedra for Fast Ion Diffusion in K-Ion Batteries

Yun-Hai Zhu et al.

Article Chemistry, Physical

Rechargeable Aqueous Zn-V2O5 Battery with High Energy Density and Long Cycle Life

Ning Zhang et al.

ACS ENERGY LETTERS (2018)

Article Chemistry, Multidisciplinary

Li+ intercalated V2O5•nH2O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode

Yongqiang Yang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Physical

Revitalized interest in vanadium pentoxide as cathode material for lithium-ion batteries and beyond

Jinhuan Yao et al.

ENERGY STORAGE MATERIALS (2018)