Related references
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Dan Huo et al.
Summary: Optimization of deep eutectic solvents (DESs) with different acidity and alkalinity for biomass pretreatment was conducted. The combination of lactic acid/betaine hydrochloride showed the highest pretreatment efficiency, with removal rates of hemicellulose and lignin reaching 89% and 73% respectively, and enzymolysis efficiency as high as 92%. The introduction of chloride salts of different valence states into the DESs improved the pretreatment efficiency, particularly with AlCl3 showing superior performance and enzymolysis efficiency reaching 96% due to destruction of the crystalline region and esterification of partial cellulose. Thus, it is suggested that adding highly valent metal salts to acidic DESs enhances pretreatment and enzymatic efficiency.
BIORESOURCE TECHNOLOGY
(2023)
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Xiaoxue Zhao et al.
Summary: This study investigated the interaction mechanism between pseudo-lignin (PL) and cellulase, as well as its impact on cellulose hydrolysis. PLs were extracted from pretreated bamboo holocellulose (HC) using different organic solvents, and the real-time interaction of PL and cellulase was analyzed using surface plasmon resonance (SPR). The results demonstrated that the extraction effect of tetrahydrofuran and 1,4-dioxane/water solution on PL was more effective than ethanol/water solution. Furthermore, PL obtained from higher temperature pretreatment had a lower dissociation rate after adsorption with cellulase.
BIORESOURCE TECHNOLOGY
(2023)
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Zheng-Yu Tang et al.
Summary: Researchers have found that deep eutectic solvents (DESs) have the potential to improve lignocellulose pretreatment efficiency. They developed an effective pretreatment approach using the DES [AA][CATB], made with acetic acid (AA) and cetyltrimethylammonium bromide (CTAB), which significantly improved enzymatic saccharification and removed lignin and xylan from waste rice hull (RCH). The study also demonstrated the morphological changes in RCH and the reduction in lignin surface area and hydrophobicity as possible reasons for the improved enzymatic hydrolysis efficiency. This work highlights the potential of functional and recoverable DESs in improving the efficiency of lignocellulose pretreatment in biorefineries.
BIORESOURCE TECHNOLOGY
(2023)
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Guangyong Zeng et al.
Summary: Avicel cellulose was pretreated with two commonly used carboxylic acid-based deep eutectic solvents, choline chloride-lactic acid and choline chloride-formic acid. The pretreatment led to the formation of cellulose esters with lactic acid and formic acid, which was confirmed through spectroscopic analysis. Surprisingly, the esterified cellulose showed a significant decrease in enzymatic glucose yield compared to the untreated cellulose, but this reduction could be recovered by removing the ester groups through saponification. The decreased enzymatic cellulose hydrolysis may be attributed to changes in the interaction between the cellulose-binding domain of cellulase and the esterified cellulose.
BIORESOURCE TECHNOLOGY
(2023)
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Wei Tang et al.
Summary: Surfactant-assisted pretreatment improves the enzymatic hydrolysis of lignocellulose by removing xylan and lignin. This study proposes the use of sodium ligno-sulfonate as an additive in alkaline pretreatment and evaluates its influence on the digestibility of wheat straw. The results show that introducing 15 g/L SL to the AP process greatly improves the cellulosic digestibility to 83.5%, compared to 63.6% and 70.2% for hydrothermal and alkaline pretreated WS. This improvement is attributed to the removal of xylan and lignin, leading to positive changes in structural characteristics.
BIORESOURCE TECHNOLOGY
(2023)
Review
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Ruolin Li et al.
Summary: The recalcitrance of lignocellulosic biomass poses challenges for its conversion to liquid fuels. Biphasic solvent pretreatment, with its ability to provide economically viable biomass upgrading, has shown promising application prospects. Different types of biphasic solvents were systematically reviewed, including their effect on biomass component fractionation and enzymatic hydrolysis performance, as well as coproduction of furan and hydroxymethylfurfural. The main advantages and disadvantages of these solvents were summarized, and future development directions were proposed. This review provides a reference for designing effective biphasic pretreatment methods for lignocellulosic biomass.
Article
Agricultural Engineering
El-Sayed R. E. Hassan et al.
Summary: This study demonstrates that pretreatment with a mixture of choline chloride and glycerol can efficiently extract cellulose from miscanthus and produce a stable ethanol yield, indicating the potential key role of Choline chloride based DESs pretreatment in enhancing the efficiency of biorefinery.
BIORESOURCE TECHNOLOGY
(2022)
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Agricultural Engineering
Ning Li et al.
Summary: In this study, a three-constituent deep eutectic solvent (3c-DES) pretreatment was used to examine its efficiency on bamboo residues. The results showed that the 3c-DES pretreatment effectively removed xylan and improved the hydrolysis yield. The introduction of ethylene glycol (EG) and the addition of Tween 80 further enhanced the effectiveness of the pretreatment. This research has significant implications for the development of bamboo biorefinery.
BIORESOURCE TECHNOLOGY
(2022)
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Agricultural Engineering
Premeshworii Devi Maibam et al.
Summary: In this study, a deep eutectic solvent comprising choline chloride and acetic acid was used for the pretreatment of rice straw. The optimized conditions for pretreatment were determined using a central composite design approach. The pretreated rice straw showed higher cellulose content and crystallinity index, and exhibited a porous surface. Saccharification of the pretreated rice straw using commercial cellulase resulted in high saccharification efficiency.
BIORESOURCE TECHNOLOGY
(2022)
Article
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Tian-Jie Ao et al.
Summary: This study utilized deep eutectic solvent (DES) for pretreating corn stover to improve the efficiency of subsequent saccharification. The optimal conditions were determined using response surface methodology, and it was found that a molar ratio of lactic acid (LA) to choline chloride (ChCl) of 1 at 140 degrees C for 4 hours achieved the highest cellulose and hemicellulose digestibility as well as delignification efficiency. The study also revealed the formation of humins at higher temperatures, which hindered enzymatic accessibility.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
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Salim Massayev et al.
Summary: This study analyzed the deep eutectic solvent (DES) pretreatment of lignocellulosic biomass using principal component analysis (PCA) and partial least square (PLS) methods. The results revealed that severity factor, temperature, type of antisolvent, particle size, agitation intensity, and type of hydrogen bond donor (HBD) were the most significant variables for DES pretreatment. The study also found that using organic solvent or inorganic salt solution as antisolvent led to more efficient enzymatic saccharification, while using water as antisolvent reduced glucose yield. Additionally, intensive stirring during pretreatment negatively affected glucose yield due to the shear thickening properties of DESs.
JOURNAL OF CLEANER PRODUCTION
(2022)
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Kai Song et al.
Summary: This study demonstrates the use of X-ray micro-computed tomography (micro-CT) to observe the changes in the histology of straw caused by dilute acid pretreatment, understand the mechanism of the pretreatment, and visualize the resulting morphological changes in the microstructure of straw. The non-invasive 3D micro-CT technique provides crucial insights into the morphology and microstructural changes of lignocellulose-based materials. It proves to be helpful in prompt in situ analysis and comparison of diverse treatment approaches using lignocellulosic biomass.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
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Yueli Yu et al.
Summary: Choline chloride-based deep eutectic solvents (DESs) were used to pretreat Triarrhena lutarioriparia (TL) in this study. The results showed that ChCl-oxalic acid dihydrate (CO2:1) exhibited effective pretreatment ability. The optimized pretreatment process achieved high enzymatic digestibility while maintaining a high retention of cellulose, hemicelluloses, and lignin.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
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Yu-Ru Lee et al.
Summary: Over the past 20 years, Taiwan has heavily relied on imported energy, leading the government to prioritize indigenous energy supply. To achieve this goal, energy policies and incentives for biomass-to-energy have been established. Analysis of national reports reveals that Taiwan generates an annual amount of agricultural waste ranging from 4.5 to 5.2 million metric tons, of which rice-derived residues and livestock/poultry waste contribute to about 80%. The supply of indigenous bioenergy, primarily from solid-type biomass resources such as waste wood, rice husk, and sugarcane bagasse, has been declining. The government has introduced policies, authorized by acts like the Renewable Energy Development Act, to promote bioenergy through economic incentives such as feed-in-tariffs and installation supports.
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Samuel Ntakirutimana et al.
Summary: This article presents the current state of the art of amine-based pretreatments for lignocellulosic biomass, highlighting their role in component fractionation and biorefinery. The potential benefits of amine solvent systems in the fractionation process are discussed, along with existing challenges and future perspectives.
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Summary: Choline chloride based deep eutectic solvents have great potential in lignocellulosic biomass pretreatment. Multivariate analysis methods were used to reveal the pretreatment mechanism and found that properties of hydrogen bond donnors and severity of DES had significant influence on the pretreatment effect. Molecular simulation and four-dimensional color graphs were utilized for further optimization of pretreatment conditions to improve economic benefits and energy consumption indicators.
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Summary: Biomass recalcitrance poses a significant challenge for biomass utilization, leading to the development of deep eutectic solvents (DES) as a promising solvent for biomass pretreatment. Current research focuses on the fractionation and saccharification enhancement of lignocellulosic biomass using DES.
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Maolin Dong et al.
Summary: This study introduces benzenesulfonic acid as a green hydrotrope for efficient lignocellulose conversion, resulting in high-value building materials and lignin nanoparticles. The method not only removes lignin effectively, but also improves enzymatic hydrolysis efficiency and reduces entangled lignocellulosic nanofibrils, presenting a promising and simple technology for lignocellulose separation and utilization under mild conditions.
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(2021)
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Yan Su et al.
Summary: The promising pretreatment using a biomass-derived deep eutectic solvent (DES) with choline chloride effectively removed lignin and xylan while preserving cellulose, resulting in a glucose yield of 75.8% under optimal conditions. The recovered lignin showed potential as a polyphenolic antioxidant due to its molecular weight, low polydispersity, and abundance of phenolic OH groups. Overall, this work demonstrated a biorefinery technology for the effective fractionation and valorization of lignocellulosic biomass.
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Qi Liu et al.
Summary: This study found that temperature had a more significant impact on the cellulose content in fiber, and microwave-assisted hydrolysis could significantly reduce reaction time and chemical costs compared to traditional heating hydrolysis. Extensive determination and characterization confirmed the existence of non-thermal effect of microwave assistance.
CARBOHYDRATE POLYMERS
(2021)
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Polymer Science
Yuan Zhu et al.
Summary: In this study, it was found that acidified solutions of ChCl and glycerol were more efficient at removing lignin and xylan from corn stover compared to DES. Acidified ChCl solution showed better pretreatment performance than acidified glycerol solution. Additionally, the presence of 20% water in DES reduced its capability for delignification and xylan removal. Enzymatic saccharification of pretreated CS was highly correlated to delignification and cellulose crystallinity, but less correlated to xylan removal.
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Chemistry, Applied
Xiaojun Shen et al.
Summary: Lignocellulosic biomass is considered the best candidate for producing biomaterials, biochemicals, and bioenergy due to over-consumption of fossil resources and environmental problems. Efficient and green fractionation of lignocellulose components can greatly enhance high-value utilization and biorefinery development, but the heterogeneity of lignocellulosic structure poses challenges to this process. Through strategies such as cellulose-first, hemicelluloses-first, and lignin-first fractionation, selective dissociation and transformation of components in lignocellulose can be achieved, offering both challenges and opportunities for biorefining valorization.
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Md Anwar Hossain et al.
Summary: Deep eutectic solvent treatment shows great potential in overcoming lignocellulose resistance for biofuels and bioproducts production. Research focused on four solvents, with Choline chloride-glycerol pretreatment showing good results in retaining glucan from rice straw and fractionating lignin. However, some challenges remain with solvent deposition on solids limiting cellulose accessibility to enzymes.
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Summary: Valorization of bioresources to extract valuable phenolic compounds using choline chloride-based deep eutectic solvents is essential for a sustainable and environmentally friendly economy. Recent studies have focused on optimizing extraction processes and understanding mechanisms involved in phenolic compound extraction. This paper thoroughly summarizes factors influencing extraction, kinetic models, and mechanisms, providing valuable insights for future biomass valorization.
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