Journal
CARBOHYDRATE POLYMERS
Volume 324, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2023.121473
Keywords
Starch modification; Cooperative crosslinking; Extrusion processing; Rheological properties; Citric acid; Zinc citrate
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Due to the low degree of crosslinking, the application of citric acid crosslinking modification is restricted. In this study, a novel ion-esterification cooperative crosslinking-extrusion combined (CCEC) modification approach was proposed to improve the strength and tunable gel characteristics of citric acid-crosslinked starch. The results showed that the CCEC-modified starch had a significantly higher elastic modulus and a denser porous structure. By changing the cation concentration, the rheological characteristics of the gel could be efficiently controlled.
Due to its safety and palatability, the citric acid crosslinking modification is an excellent way to modify the properties of starch gels. However, the application of this method is restricted by the low degree of crosslinking of gels produced by this method in the hydrogel system. To produce citric acid-crosslinked starch with improved strength and tunable gel characteristics, a novel ion-esterification cooperative crosslinking-extrusion combined (CCEC) modification approach is presented in this study. The linear and nonlinear rheological characteristics of the samples were measured to evaluate the effectiveness of CCEC modification. Findings disclosed that at 0.1 % strain, the elastic modulus of the CCEC-modified starch (SC-0.5Zn2+, G' = 1522.29 +/- 36.31) exhibited a significant rise of 387.27 % as compared to the elastic modulus of citric acid-crosslinked starch (SC, G' = 318.29 +/- 11.62). Furthermore, changing the cation concentration allowed for efficient control of the gel's rheological characteristics. The samples were characterized by SEM, FTIR, XRD, and XPS. The CCEC-modified gels had a smaller pore size distribution and a denser honeycomb porous structure. The CCEC modification reaction involves ester bonds and electrostatic attraction. This research is essential to elucidate how coupled physicochemical modification techniques affect the manipulation of starch gel characteristics.
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