Novel organically linked ZnII hydrogenselenite coordination polymers: synthesis, characterization, and efficient TiO2 photosensitization for enhanced photocatalytic hydrogen production

This study focused on the solvothermal synthesis, characterization, and photocatalytic activities of two novel coordination polymers, namely [Zn(mu-HSeO3)(2)(bipy)](n) (1) and [Zn(mu-HSeO3)(2)(phen)](n) (2). These compounds represent the first organically linked Zn-II hydrogenselenite coordination polymers. The synthesis of compounds 1 and 2 involved the addition of 2,2 '-bipyridine and 1,10-phenanthroline, respectively, to SeO2 and ZnO in methanol as the solvent. The novel hydrogenselenite compounds were thoroughly characterized using spectroscopic and crystallographic methods. The photocatalytic solids (TiO2-1A and TiO2-2A) were prepared by immobilizing compounds 1-2 onto TiO2 through the sol-gel approach. These photocatalysts were then evaluated for hydrogen evolution via water splitting using a 300 W Hg/Xe lamp as the irradiation source. Among the newly synthesized photocatalytic materials, TiO2-1A demonstrated auspicious photocatalytic performance for hydrogen gas production. Its catalytic activity overcame the observed for the pure solid support TiO2 and Degussa P25 (commercial titania), making compound 1 a particularly attractive TiO2 photosensitizer. Additionally, TiO2-1A exhibited superior photocatalytic activity compared to TiO2-2A. The latter performed better than freshly prepared TiO2, approaching that of Degussa P25. These findings highlight the potential of compound 1 as an effective photosensitizer for TiO2-based photocatalysis, making it a promising candidate for applications in clean energy generation, specifically in hydrogen production by water splitting.

Automated summary

This study synthesized two novel coordination polymers and immobilized them onto TiO2 for photocatalytic hydrogen production. Among them, compound 1 exhibited promising catalytic activity and was considered as a promising TiO2 photosensitizer.