Effect of CO2-mixing dose and prolonged mixing time on fresh and hardened properties of cement pastes

This study aims to investigate the influence of CO2-mixing dose (mass fractions of 0.3%, 0.6%, and 0.9%) and prolonged mixing time on the fresh and hardened properties of cement pastes. The CO2-mixing can act as coagulant in fresh cement mixtures, resulting in a significant reduction in workability associated with the formation of a rich calcium carbonate network on the surface of cement particles. The CO2-mixing cement pastes were found to be much stiffer and more difficult to handle, place, and compact than the control mixture, which had a negative effect on the mechanical strength performance of the hardened pastes. However, prolonging the mixing time for 1 min (immediately after CO2-mixing) can effectively improve the workability (by similar to 53%-85%) by breaking up the flocculation network of deposited calcium carbonates. As a result, the presence of detached calcium carbonate accelerated early cement hydration and densified the microstructure; this improved early-age compressive strength by similar to 6%-32%, depending on the CO2-mixing dose used. Therefore, it seems that the CO2-mixing dose should be controlled at <= 0.6% with the mixing time prolonged in order to attain satisfactory workability and mechanical strength.

Automated summary

This study investigates the influence of CO2-mixing dose and prolonged mixing time on the properties of cement pastes. It is found that CO2-mixing can make the pastes stiffer and more difficult to handle, leading to a negative effect on mechanical strength. However, prolonging the mixing time can improve workability and increase early-age compressive strength.