Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 43, Issue 10, Pages 3544-3557Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc202306009
Keywords
Lewis acids; silylation reaction; hydrosilylation reaction; unsaturated hydrocarbons
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Organosilicon compounds, with their unique properties, have found wide applications in various fields. The silylation of unsaturated compounds has been recognized as an important approach for synthesizing organosilicon compounds, and significant progress has been made, particularly using B(C6F5)(3) as a catalyst.
Organosilicon compounds have been widely applied in synthetic chemistry, medicinal chemistry, polymer chemistry, organic photoelectric materials and other fields due to their unique properties. The silylation of unsaturated compounds represents one of the most important approaches for the synthesis of organosilicon compounds, which has attracted the intensive attention of chemists, and a great success has been achieved. As a unique non-metallic Lewis acid, B(C6F5)(3)-catalyzed silylation of unsaturated compounds has made a significant progress in recent years. This subject and the corresponding mechanism are demonstrated.
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