Journal
JOURNAL OF ENERGY STORAGE
Volume 73, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.est.2023.109162
Keywords
Candle soot; KOH activation; Energy density; Non -aqueous electrolytes; Redox additive electrolyte
Categories
Ask authors/readers for more resources
Supercapacitors have advantages of ultra-long life cycles and high-power density, but face the challenge of low energy density. This study addresses this challenge through two approaches: one using carbon from candle soot activation, and the other increasing energy density with non-aqueous electrolytes and a redox additive.
Supercapacitors are attracting the scientific community because of their advantages, such as ultra-long-life cycles and high-power density. Nevertheless, they pose one of the critical challenges of low energy density. In the present work, this challenge is addressed by two different approaches. One strategy uses carbon from candle soot activation, which resulted in a high surface area of 1060 m2 g-1 and retained capacitance of 82 % for 10,000 cycles in the aqueous (H2SO4) electrolyte. In another approach, energy density is increased by employing non -aqueous electrolytes (tetraethylammonium tetrafluoroborate in acetonitrile (TEABF4-ACN) and 1-ethyl-3-meth-ylimidazolium (EMIMBF4)), which showed a wide electrochemical stability window and specific energy of 15 and 37.5 Wh kg -1, respectively. However, this non-aqueous liquid provides challenges like high cost, poor ionic mobility, and high viscosity. A redox additive (0.02 M hydroquinone (HQ)) electrolyte is utilized to tackle these challenges. This electrolyte enhanced the electrochemical potential window to 0-2.2 V and delivered a specific energy of 61.6 Wh kg -1.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available