☆ 4.8 Article

A helicene-based semiconducting polymer for stable and efficient perovskite solar cells

MATTER (2023)

Related references

Note: Only part of the references are listed.

Review Biochemistry & Molecular Biology

Recent Progress of Helicene Type Hole-Transporting Materials for Perovskite Solar Cells

Jijitha Vailassery et al.

Summary: Helicene-based hole-transporting materials have gained attention for their unique properties and ability to enhance the performance and stability of perovskite solar cells. This review summarizes the optical, electrochemical, thermal, and photovoltaic properties of helicene-based small molecules as hole-transporting materials or interfacial layer materials in different types of perovskite solar cells. Future perspectives for the development of helicene-based hole-transporting materials are also provided.

MOLECULES (2023)

Add to Collection

Article Chemistry, Physical

Tunable Molecular Packing of Dopant-Free Hole-Transport Polymers for Perovskite Solar Cells

Qiang Fu et al.

Summary: Optimizing the molecular packing and orientation of dopant-free hole-transport materials (HTMs) is an effective strategy for achieving high-performance perovskite solar cells (PSCs). By regulating the donor building blocks and using a large core unit, we successfully demonstrated tunable molecular packing and orientation of polymers. The developed PC-DPP conjugated polymer with a preferred face-on orientation showed enlarged hole mobility and improved efficiency in PSCs compared to the control PBDT-DPP polymer with a preferred edge-on orientation. This work opens up possibilities for developing dopant-free HTMs.

ACS ENERGY LETTERS (2023)

Add to Collection

Article Chemistry, Physical

Helical Polycyclic Heteroaromatic as Hole Transport Material for Perovskite Solar Cell: Remarkable Impact of Alkyl Substitution Position

Lingyi Fang et al.

Summary: This study demonstrates the influence of alkyl substitution position on the properties of a polycyclic heteroaromatic, TBPC. Internal hexyl substitution improves thin film morphology, reduces energy disorder, and enhances hole mobility. The organic semiconductor with internal hexyl substitution shows a higher glass transition temperature and slower diffusion rate of external species, leading to the successful fabrication of high-efficiency perovskite solar cells.

ADVANCED ENERGY MATERIALS (2023)

Add to Collection

Article Chemistry, Multidisciplinary

A Perylene-Based Conjugated Polymer Endows Perovskite Solar Cells with 85 °C Durability: The Control of Gas Permeation

Yuyan Zhang et al.

Summary: This study reports a hole-transporting conjugated copolymer, p-NP-E, which can achieve thermally stable perovskite solar cells by controlling gas permeation to reduce degradation, enhancing the efficiency of solar cells compared to conventional materials. The p-NP-E based hole transport layer exhibits higher heat resistance and lower solubility and diffusion coefficients for environmental water molecules and gaseous products, enabling the fabrication of highly efficient and durable solar cells at elevated temperatures.

ADVANCED FUNCTIONAL MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

A Phenanthrocarbazole-Based Dopant-Free Hole-Transport Polymer with Noncovalent Conformational Locking for Efficient Perovskite Solar Cells

Yaxiao Guo et al.

Summary: Utilizing S-O secondary interaction for noncovalent conformational locking is crucial in enhancing the conductivity of polymeric HTMs.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Physical

Donor-Acceptor Type Polymer Bearing Carbazole Side Chain for Efficient Dopant-Free Perovskite Solar Cells

Guofeng You et al.

Summary: A new copolymer PBDB-Cz with carbazole as the conjugated side chain of BDT has been developed for perovskite solar cells, showing excellent hole transport properties and a promising power conversion efficiency of 22.06%. The incorporation of carbazole improves the coplanarity and interaction of the polymer chains, as well as the hole mobility of the polymeric HTM, leading to enhanced device stability with over 90% of initial PCE retention after 100 days of ambient storage.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Pyrene-Based Dopant-Free Hole-Transport Polymers with Fluorine-Induced Favorable Molecular Stacking Enable Efficient Perovskite Solar Cells

Zhaoyang Yao et al.

Summary: A new class of polymeric hole-transport materials (HTMs) have been explored, which involve the insertion of a two-dimensionally conjugated fluoro-substituted pyrene into thiophene and selenophene polymeric chains. These materials exhibit enhanced pi-pi stacking and strong interaction with the perovskite surface, resulting in efficient charge transport in both the HTM layer and the perovskite/HTM interface. The fluorine substitution adjacent to pyrene further improves the stacking and facilitates efficient charge transport, leading to high-performance perovskite solar cells (PSCs) with an efficiency of 22.3%.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Ionic Dopant-Free Polymer Alloy Hole Transport Materials for High-Performance Perovskite Solar Cells

Qiang Fu et al.

Summary: An alloy strategy using two conjugated polymers has been demonstrated for dopant-free hole transport material in high-performance perovskite solar cells, improving efficiency and stability significantly.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Multidisciplinary Sciences

Inactive (PbI2)2RbCl stabilizes perovskite films for efficient solar cells

Yang Zhao et al.

Summary: In halide perovskite solar cells, introducing RbCl doping effectively stabilizes the perovskite phase by converting excess PbI2 into an inactive compound. This strategy achieved a certified PCE of 25.6% for FAPbI(3) perovskite solar cells, with high device stability and minimal hysteresis effects.

SCIENCE (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Dopant-Free Bithiophene-Imide-Based Polymeric Hole-Transporting Materials for Efficient and Stable Perovskite Solar Cells

Yuanqing Bai et al.

Summary: The development of high-performance hole-transport materials (HTMs) is crucial for improving the efficiency and stability of perovskite solar cells. In this study, two conjugated polymers, PBTI and PFBTI, were successfully synthesized and demonstrated as promising HTMs. The introduction of fluorine atoms and optimization of the polymer structure significantly enhanced the hole mobility and stability of the devices. The PVSCs incorporating PFBTI as the HTM achieved a record power conversion efficiency of 23.1%, making it one of the best HTMs reported to date. Moreover, PFBTI showed great potential for applications in inorganic PVSCs and perovskite/organic tandem solar cells, with high conversion efficiencies of 17.4% and 22.2%, respectively.

ADVANCED MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Management of Donor and Acceptor Building Blocks in Dopant-Free Polymer Hole Transport Materials for High-Performance Perovskite Solar Cells

Qiang Fu et al.

Summary: This study proposes a molecular design strategy to construct dopant-free polymer hole transport materials (HTMs) by selecting structurally related polymers. The optimized device utilizing dopant-free polymer HTM shows high efficiency and improved operational stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Multidisciplinary Sciences

Transporting holes stably under iodide invasion in efficient perovskite solar cells

Tao Wang et al.

Summary: This study presents a solution strategy to stabilize the hole transport in organic layers of perovskite solar cells, resulting in improved hole conductivity and well-matched band alignment. The fabricated solar cells exhibited excellent durability and maintained high conversion efficiency under extreme conditions.

SCIENCE (2022)

Add to Collection

Article Materials Science, Multidisciplinary

Oligo(Ethylene Glycol) Functionalization of a Dopant-Free Hole Transport Material for Perovskite Photovoltaics

Henry Opoku et al.

Summary: The research shows that the performance of PPVs can be improved by controlling the amount and length of OEG side groups in polymeric HTMs. The polymeric HTM with the longest OEG side groups demonstrated efficient transport and extraction of photogenerated charge carriers resulting in high efficiency and device stability in PPVs.

ACS MATERIALS LETTERS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Chiroptical Properties of Symmetric Double, Triple, and Multiple Helicenes

Tadashi Mori

Summary: This review focuses on the chiroptical properties of multiple helicenes, with an emphasis on the impact of the arrangement of multiple helices on the chiroptical responses. Although the number of multiple helicenes reported is limited, insights into the design principle for advanced chiroptical materials through the proper arrangement of multiple helices are provided.

CHEMICAL REVIEWS (2021)

Add to Collection

Article Chemistry, Physical

A spiro-OMeTAD based semiconductor composite with over 100 °C glass transition temperature for durable perovskite solar cells

Yutong Ren et al.

Summary: The study focuses on improving the durability of perovskite solar cells by blending commercial polymer and organic salt with spiro-OMeTAD to create a high-performance organic composite material. This composite material can achieve high efficiency perovskite solar cells at 85 degrees Celsius and shows good control over charge transport, interfacial recombination, and hole extraction. Multiple experimental measurements and molecular dynamics modeling reveal the crucial impact of organic coatings on the thermal decomposition of hybrid perovskites from a new perspective of gas diffusion modulation.

NANO ENERGY (2021)

Add to Collection

Article Chemistry, Physical

Multifunctional Two-Dimensional Conjugated Materials for Dopant-Free Perovskite Solar Cells with Efficiency Exceeding 22%

Qiang Fu et al.

Summary: In this study, a solution-processable two-dimensional polymer HTM called 2DP-TDB with extended pi-electron delocalization was successfully developed for perovskite solar cells. The PSCs incorporating 2DP-TDB as dopant-free HTM showed a high efficiency of 22.17% after further optimization of the perovskite film, demonstrating the potential of 2D conjugated polymer HTMs for high-efficiency and stable PSCs.

ACS ENERGY LETTERS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

A Pyrrole-Bridged Bis(oxa[5]helicene)-Based Molecular Semiconductor for Efficient and Durable Perovskite Solar Cells: Microscopic Insights

Yuefang Wei et al.

Summary: The study introduces a new organic semiconductor DOP-OMeDPA, which exhibits improved hole mobility and glass transition temperature compared to its oxa[5]helicene counterpart. A doped semiconducting composite based on DOP-OMeDPA shows high efficiency and thermal stability in perovskite solar cells.

ACS MATERIALS LETTERS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Spontaneous interface engineering for dopant-free poly(3-hexylthiophene) perovskite solar cells with efficiency over 24%

Min Ju Jeong et al.

Summary: By incorporating gallium(iii) acetylacetonate into organic hole-transporting materials without additional surface treatment processes, the interface engineering strategy efficiently reduces the recombination loss and enhances the performance of perovskite solar cells. This method significantly improves the power conversion efficiency of PSCs and maintains stability without hygroscopic additives, showing a promising route for high performance and commercialization.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Add to Collection

Article Multidisciplinary Sciences

Glass transition temperature from the chemical structure of conjugated polymers

Renxuan Xie et al.

NATURE COMMUNICATIONS (2020)

Add to Collection

Article Chemistry, Physical

Dopant-Free, Donor-Acceptor-Type Polymeric Hole-Transporting Materials for the Perovskite Solar Cells with Power Conversion Efficiencies over 20%

Guofeng You et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Nonaromatic Green-Solvent-Processable, Dopant-Free, and Lead-Capturable Hole Transport Polymers in Perovskite Solar Cells with High Efficiency

Junwoo Lee et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Unraveling Doping Capability of Conjugated Polymers for Strategic Manipulation of Electric Dipole Layer toward Efficient Charge Collection in Perovskite Solar Cells

Jaehong Park et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Add to Collection

Article Multidisciplinary Sciences

Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene)

Eui Hyuk Jung et al.

NATURE (2019)

Add to Collection

Review Polymer Science

Glass Transition Phenomenon for Conjugated Polymers

Zhiyuan Qian et al.

MACROMOLECULAR CHEMISTRY AND PHYSICS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Side-Chain Engineering on Dopant-Free Hole-Transporting Polymers toward Highly Efficient Perovskite Solar Cells (20.19%)

Luozheng Zhang et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Add to Collection

Article Chemistry, Physical

Ladder-like conjugated polymers used as hole-transporting materials for high-efficiency perovskite solar cells

Liren Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Multidisciplinary Sciences

An Oxa[5]helicene-Based Racemic Semiconducting Glassy Film for Photothermally Stable Perovskite Solar Cells

Niansheng Xu et al.

ISCIENCE (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Intensive Exposure of Functional Rings of a Polymeric Hole-Transporting Material Enables Efficient Perovskite Solar Cells

Luozheng Zhang et al.

ADVANCED MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

Sequentially Fluorinated PTAA Polymers for Enhancing V-OC of High-Performance Perovskite Solar Cells

Youngwoong Kim et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Green-Solvent-Processable, Dopant-Free Hole-Transporting Materials for Robust and Efficient Perovskite Solar Cells

Junwoo Lee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Add to Collection

Article Polymer Science

Unravelling the Thermomechanical Properties of Bulk Heterojunction Blends in Polymer Solar Cells

Anirudh Sharma et al.

MACROMOLECULES (2017)

Add to Collection

Article Multidisciplinary Sciences

A generic interface to reduce the efficiency-stability-cost gap of perovskite solar cells

Yi Hou et al.

SCIENCE (2017)

Add to Collection

Article Chemistry, Physical

Efficient perovskite photovoltaic devices using chemically doped PCDTBT as a hole-transport material

Michael Wong-Stringer et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Add to Collection

Article Chemistry, Physical

Severe Morphological Deformation of Spiro-OMeTAD in (CH3NH3)Pbl3 Solar Cells at High Temperature

Ajay Kumar Jena et al.

ACS ENERGY LETTERS (2017)

Add to Collection

Article Nanoscience & Nanotechnology

Enhanced Efficiency and Long-Term Stability of Perovskite Solar Cells by Synergistic Effect of Nonhygroscopic Doping in Conjugated Polymer-Based Hole-Transporting Layer

Chang Woo Koh et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Add to Collection

Article Nanoscience & Nanotechnology

Effect of Selective Contacts on the Thermal Stability of Perovskite Solar Cells

Xing Zhao et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Add to Collection

Review Nanoscience & Nanotechnology

Hybrid organic-inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties

Thomas M. Brenner et al.

NATURE REVIEWS MATERIALS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Contorted Polycyclic Aromatics

Melissa Ball et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Polyfluorene Derivatives are High-Performance Organic Hole-Transporting Materials for Inorganic-Organic Hybrid Perovskite Solar Cells

Zonglong Zhu et al.

ADVANCED FUNCTIONAL MATERIALS (2014)

Add to Collection

Article Chemistry, Multidisciplinary

A diketopyrrolopyrrole-containing hole transporting conjugated polymer for use in efficient stable organic-inorganic hybrid solar cells based on a perovskite

Young Soo Kwon et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor

Seungchan Ryu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Single-crystal Field-effect Transistors with a Furan-containing Organic Semiconductor Having a Twisted π-Electronic System

Katsumasa Nakahara et al.

CHEMISTRY LETTERS (2013)

Add to Collection

Article Optics

Circularly polarized light detection by a chiral organic semiconductor transistor

Ying Yang et al.

NATURE PHOTONICS (2013)

Add to Collection

Article Optics

Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors

Jin Hyuck Heo et al.

NATURE PHOTONICS (2013)

Add to Collection

Article Materials Science, Multidisciplinary

Role of band states and trap states in the electrical properties of organic semiconductors: Hopping versus mobility edge model

Shafigh Mehraeen et al.

PHYSICAL REVIEW B (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Helicenes: Synthesis and Applications

Yun Shen et al.

CHEMICAL REVIEWS (2012)

Add to Collection

Article Chemistry, Physical

Unification of trap-limited electron transport in semiconducting polymers

H. T. Nicolai et al.

NATURE MATERIALS (2012)

Add to Collection

Article Physics, Multidisciplinary

Ultralow Doping in Organic Semiconductors: Evidence of Trap Filling

Selina Olthof et al.

PHYSICAL REVIEW LETTERS (2012)

Add to Collection

Article Materials Science, Multidisciplinary

Trap density of states in small-molecule organic semiconductors: A quantitative comparison of thin-film transistors with single crystals

Wolfgang L. Kalb et al.

PHYSICAL REVIEW B (2010)

Add to Collection

Article Materials Science, Multidisciplinary

Synthesis, characterization, and transistor response of tetrathia-[7]-helicene precursors and derivatives

Choongik Kim et al.

ORGANIC ELECTRONICS (2009)

Add to Collection

Article Materials Science, Multidisciplinary

Trap-limited hole mobility in semiconducting poly(3-hexylthiophene)

Z Chiguvare et al.

PHYSICAL REVIEW B (2004)

Add to Collection

Article Chemistry, Multidisciplinary

Low-k insulators as the choice of dielectrics in organic field-effect transistors

J Veres et al.

ADVANCED FUNCTIONAL MATERIALS (2003)

Add to Collection

© Peeref 2019-2024. All rights reserved.