4.6 Article

Negative differential resistance based on phase transformation

Journal

MATERIALS HORIZONS
Volume 10, Issue 11, Pages 5143-5151

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3mh00657c

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This research demonstrates a novel current controlled negative differential resistance (NDR) device based on phase transformation, providing more possibilities for material selection. The experimental demonstration of NDR induced by phase transformation has a significant impact on the development of NDR devices. This phase transformation-based NDR device is significantly different from typical devices such as tunnel diodes and memristors, and has the potential for evaluating hydrogen storage properties.
The negative differential resistance (NDR) device is attracting attention because of its broad potential application in neuromorphic computing and non-volatile memory. However, only a limited range of materials show NDR and, therefore, there is less choice in material selection for NDR devices. Considering this issue, we here demonstrate a novel current controlled NDR device based on phase transformation. To the best of our knowledge, this report is the first experimental demonstration that NDR can be induced by phase transformation. We believe that the impact of this demonstration is very large, as phase transformation is the most common phenomenon in materials and consequently most materials can be reconsidered as possible candidates for NDR devices. The prototype NDR device is constructed using hydrogen absorbing metal palladium (Pd) thin-wire and the phase transformation from metal-hydride to metal is employed for the demonstration. The observed NDR property shows a strong dependence on the current sweep speed. Also, it exhibits no current polarity dependence. Therefore, the NDR device based on phase transformation is significantly different from typical NDR devices such as tunnel diodes and memristors. The prototype NDR device has been found to be very useful for evaluating the hydrogen storage properties of metals. The advantage of this analysis method is that the storage properties can be acquired just by sweeping the applied current. This demonstration offers novel directions for both the development and utilization of NDR devices. A novel mechanism to induce negative differential resistance is proposed and experimentally demonstrated using a prototype device consisting of metal-hydride.

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