4.7 Article

Microstructural and polymer film interaction mechanisms: Insights of GO-reinforced polymer-modified cement composites

Journal

JOURNAL OF BUILDING ENGINEERING
Volume 80, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jobe.2023.107962

Keywords

Graphene oxide; Polymer -modified cement composites; Cement hydration products; Polymer films; Microstructure

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This study investigates the effects of graphene oxide (GO) on cement hydration phases and polymer film formation in GO-reinforced polymer-modified cement (GOPMC) composites. The results show that GO has a significant impact on the chemical structure of cement and is directly involved in the early-age hydration kinetics. The GOPMC composite exhibits higher heat flow and tensile strength compared to the reference composite.
The effects of graphene oxide (GO) on cement hydration phases and polymer film formation in GO-reinforced polymer-modified cement (GOPMC) composites were investigated by analysing interactions of film chemical structure and cement hydration kinetics towards enhanced engi-neering performance. Chemical characterisation by FTIR and XRD analyses revealed that alter-ations of the cement matrix's chemical structure, such as slow Ethylene vinyl acetate (EVA) hydrolysis, increased calcium-silicate-hydrate (C-S-H) and portlandite Ca(OH)2, were more pronounced in GOPMC composites, indicating direct and robust involvement of GO during early -age hydration kinetics. Isothermal calorimetry displayed an increased heat flow of-7.2 % for GOPMC compared with the reference PMC composite. Notably, air voids of GOPMC composite revealed polymer film sheets intermingled with cement hydration products to promote elastic interconnections and microstructural uniformity. Accordingly, the GOPMC composite displayed-16 % higher tensile strength at 28 days versus the PMC composite, primarily attributable to GO nucleation, due to its seeding effect on cement hydration kinetics thereby inducing marginally slower EVA hydrolysis, increased C-S-H nucleation sites, and smaller-sized CH crystals while mechanically reinforcing polymer films. More significantly, GO reinforced the microstructure of the GOPMC composites with no apparent chemical interference of crucial film-forming proper-ties. This research provides a fundamental understanding of this novel material's characteristic properties and framework of engineering performance optimization for future infrastructure applications.

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