Related references
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Article
Multidisciplinary Sciences
James T. T. Frith et al.
Summary: This article discusses the significant gap between academic research and industrial market needs in the field of lithium-based batteries, which is partly due to the lack of peer-reviewed publications from industry. The authors present a non-academic perspective to bridge the divide, focusing on key metrics and challenges for developing practical batteries. They emphasize the need to consider various performance aspects together when developing new technologies and also examine the suitability of supply chains, sustainability of materials, and the impact on system-level cost as important factors.
NATURE COMMUNICATIONS
(2023)
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Chemistry, Physical
Wuxing Hua et al.
Summary: Understanding sulfur conversion chemistry is crucial for the development of sulfur-based high-energy-density batteries. The relationship between the electronic structure of the catalyst and its activity remains unclear. In this study, we establish a direct correlation between the p electron gain of S in p-block metal sulfides and the apparent activation energies (E-a) for the SRR, specifically the Li2Sn to Li2S conversion. The highest p charge is observed in bismuth sulfide, resulting in the lowest E-a and a high SRR rate.
Article
Chemistry, Multidisciplinary
Zhuo Zhu et al.
Summary: A novel type of ZnCo-based metal-organic framework nanoboxes (ZnCo-MOF NBs) were designed and prepared as a functional sulfur host for Li-S batteries. The hollow architecture of ZnCo-MOF NBs ensures fast charge transfer, improved sulfur utilization, and effective confinement of lithium polysulfides (LiPSs). The atomically dispersed Co-O-4 sites in ZnCo-MOF NBs capture LiPSs and accelerate their conversion kinetics electrocatalytically.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Xiang Li et al.
Summary: A catalytic two-dimensional heterostructure composite (OMC-g-MXene) with evenly grafted mesoporous carbon on MXene nanosheets is prepared as interfacial kinetic accelerators in Li-S batteries. The grafted mesoporous carbon prevents nanosheet stacking and accelerates ion diffusion, while the exposed defect-rich OMC-g-MXene inhibits polysulfide shuttling and enhances electrochemical conversion kinetics and efficiency. The cells with OMC-g-MXene exhibit high capacity, superior rate performance, and low decay rate, demonstrating promising practical applications.
Article
Chemistry, Multidisciplinary
Longtao Ren et al.
Summary: Constructing high performance electrocatalysts, such as the single atomic catalyst of Fe-N-4 moiety doping periphery with S (Fe-NSC), can effectively enhance lithium polysulfides (LiPSs) adsorption and facilitate sulfur conversion, improving the energy density and cycle life of rechargeable lithium-sulfur (Li-S) batteries. By modifying the graphene oxide supported Fe-NSC catalyst (Fe-NSC@GO) to the commercial separator, Li-S cells exhibit high discharge capacity and excellent cyclability, with 1156 mAh g(-1) at 1 C rate and a low capacity decay of only 0.022% per cycle over 1000 cycles. This work provides new insights into structural tuning of electrocatalysts to improve the electrochemical performance of Li-S batteries.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Inorganic & Nuclear
Xuanhe Hu et al.
Summary: Lithium-sulfur batteries are highly promising successors to lithium-ion batteries due to their high energy density, low cost, and environmental friendliness. However, their practical applications are hindered by slow sulfur redox kinetics and the polysulfide shuttle effect. The use of metal-organic frameworks (MOFs) as catalysts to improve the electrochemical performance of lithium-sulfur batteries has attracted significant research interest.
COORDINATION CHEMISTRY REVIEWS
(2023)
Article
Chemistry, Applied
Xiaolong Leng et al.
Summary: A bimetallic Ni-Co metal-organic framework (MOF) was synthesized and incorporated into an electrospinning separator for Lithium-sulfur (Li-S) batteries. This improved the cycle stability and sulfur utilization, resulting in excellent rate performance and outstanding long-term cycling performance.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Energy & Fuels
Jie Zeng et al.
Summary: In this study, a novel three-dimensional hollow microsphere hierarchical structure of nickel-zinc MOFs (NZMF/CF) was successfully fabricated on carbon fabric as a binder-free electrode for supercapacitor applications. The NZMF/CF electrode showed higher rate capacity and specific capacitance compared to NZMF, leading to a superior energy density and cyclic stability in a split cell asymmetric supercapacitor device (SC-ASD). This research provides a versatile scheme for efficiently preparing MOF-based binder-free energy storage materials for future hybrid and flexible electronic devices.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Materials Science, Multidisciplinary
Jie Zeng et al.
Summary: The study suggests that bimetallic MOFs with good electrical conductivity can be used to design electrodes with Ni-Zn MOF yolk-shell structures, showing high energy and power densities in a 6M gel electrolyte.
Article
Chemistry, Multidisciplinary
Xiongwei Zhong et al.
Summary: This paper reports a method of preparing large-area MXene film through drop-casting, and using this film to improve the adhesion and capacity retention of lithium-sulfur batteries. At the same time, titanium oxide anchored on MXene was prepared by oxidation treatment, which further promotes lithium ion transport and prevents the shuttle effect of lithium polysulfides.
Review
Chemistry, Multidisciplinary
Anukul K. Thakur et al.
Summary: This review summarizes the synthesis strategies, charge conduction mechanism, and applications of B, N co-doped carbon in electrocatalysis, energy storage, and sensors. It also discusses the challenges and future directions in this field.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Xiaodong Meng et al.
Summary: The study demonstrates that aggregated cobalt single-atom catalysts (SACs) attached to graphene via porphyrins can overcome challenges associated with catalyst/reactant size mismatch, enabling efficient electrocatalysis for improved performance of sulfur cathodes. This approach achieves a high atomic utilization efficiency, enhances the electrocatalytic effect, and results in outstanding capacity retention and rate capability in Li-S cells.
Article
Energy & Fuels
Guangmin Zhou et al.
Summary: The authors analyze key Li-S cell parameters, propose an energy density calculation, and discuss the design targets for practical high-performance Li-S batteries.
Article
Chemistry, Physical
Yusen He et al.
Summary: In this study, a porous carbon nanofiber with an oxygen-dominated Ti3C2 MXene nanosheet (O-Ti3C2@CNF) was designed and synthesized as an all-purpose interlayer for lithium-sulfur (Li-S) batteries. By controllable surface modifications and oxygen regulation, the O-Ti3C2@CNF exhibited strong physical/chemical affinity and fast reaction kinetics towards sulfur species. The interlayer enabled high-flux lithium diffusion and dendrite-free lithium anode. A practical, flexible Li-S pouch battery with excellent areal capacity was assembled using the symmetric interlayer design.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Ting Huang et al.
Summary: A new type of single-atomic iron mediator with a designed FeN3P1 coordination structure is reported to boost bidirectional polysulfide conversion. The substitution by one P atom at the first-coordination shell of Fe center is found to strengthen adsorption toward sulfur species and reduce energy barrier for Li2S decomposition. The bidirectional electrocatalytic behavior for polysulfide conversion via FeN3P1 mediator is confirmed by electrokinetic analysis. This strategy offers an example in probing the correlation between the definitive structure of single atoms and their catalytic performance in Li-S chemistry.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Chemistry, Multidisciplinary
Zhenkang Wang et al.
Summary: This article discusses the influence of the morphology of lithium polysulfides (LPSs) on the performance of lithium-sulfur batteries and summarizes the earlier studies on inhibiting LPS dissolution as well as the recent viewpoint of promoting LPS dissolution. The article provides an overview of the historical background, strategies, advantages, and disadvantages of the two views, and predicts the future morphology of LPSs in lithium-sulfur batteries based on existing research.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Minghui Sun et al.
Summary: This study investigates a catalyst for high-performance lithium-sulfur batteries. By designing a cobalt-decorated N-doped hollow carbon nanofiber catalyst, the electron redistribution resulting from long-range interactions enhances the generation of oxygen radicals and the dissociation of hydrogen sulfide, enabling selective oxidation of hydrogen sulfide. Furthermore, the hollow structure of the catalyst provides ample storage space for rapid gas diffusion and allows for the in-situ fabrication of high sulfur-loading carbon-based cathodes during the oxidation of hydrogen sulfide. This chemical reaction-induced deposition results in a more uniform distribution of solid sulfur upon carbon than traditional methods, leading to superior electrochemical performance in lithium-sulfur batteries.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Engineering, Environmental
Zongke He et al.
Summary: In this study, a high-performance sulfur host was developed by introducing oxygen vacancies and Nb-doping into a porous structured conductive TiO2. The host matrix was designed into a 3D ordered macroporous skeleton with N-doped carbon fillers, providing large and stable space for sulfur accommodation. The sulfur cathode based on this host exhibited low capacity fading rate and high areal capacity, making it a promising candidate for efficient and durable Li-S batteries.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Materials Science, Multidisciplinary
Pengbiao Geng et al.
Summary: This study demonstrates that incorporating Cu2+ into Al-MOF to form bimetallic Al/Cu-MOF as a sulfur host material can improve the adsorption capacity to lithium polysulfides. The melt-diffusion process to obtain sulfur-containing Al/Cu-MOF-S shows improved cyclic performance in Li-S batteries.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Junru Wang et al.
Summary: The study identified specific 2D metal-organic frameworks that can effectively suppress the dissolution and shuttling of LiPSs, showing good electrical conductivity and high sulfur loading, which are important for overcoming the challenges faced by LiSBs.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Zhifu Liang et al.
Summary: This study reports on the use of 2D layered organic material, C2N, loaded with atomically dispersed iron as an effective sulfur host in lithium-sulfur batteries (LSBs), which shows significantly improved rate performance and long-term cycling stability. The Fe/C2N-based cathodes exhibit high initial capacities and maintain remarkable specific capacity retention even after multiple cycles at high rates.
ADVANCED ENERGY MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Ning Yuan et al.
Summary: This review summarizes recent advances in the functionalization of lithium-sulfur battery (LSBs) separators based on metal-organic frameworks (MOFs), including original MOFs, MOF derivatives, and MOF composites. The mechanisms enhancing the electrochemical performance of each modified separator are explained, and the potential outlook of this field is provided.
ADVANCED MATERIALS INTERFACES
(2021)
Article
Chemistry, Physical
Jenny G. Vitillo et al.
Summary: Zeolitic imidazolate frameworks (ZIFs) undergo pressure-induced phase transitions that are peculiar to each ZIF, and the metal dependence of the ambient pressure and high pressure phases of ZIF-8(M) with Mg, Fe, and Zn has been studied. The substitution of Zn with Mg or Fe influences the gate opening energy significantly, with ZIF-8(Fe) showing a different lowest energy phase structure compared to ZIF-8(Mg) and ZIF-8(Zn), which is closer to the high pressure phase. Additionally, ZIF-8(Fe) is confirmed to have high-spin divalent iron in antiferromagnetic coupling, making it a promising material for catalysis and photocatalysis due to its band gap in the visible light range.
CHEMISTRY OF MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Lehlohonolo E. Mphuthi et al.
Summary: Incorporating iron into ZIFs through metal ion exchange significantly enhances their photocatalytic performance, resulting in a markedly higher catalytic activity for dye degradation. The Fe-exchanged ZIF-8 and ZIF-67 nanoparticles showed a dramatic improvement in photocatalysis compared to their parent ZIFs, with preserved morphology and crystal structures.
Article
Materials Science, Multidisciplinary
Li-Peng Hou et al.
Summary: This review systematically analyzes the challenges of the Li metal anode in the presence of LiPSs, and summarizes the preliminary advances in Li metal anode protection to deal with LiPSs. The insight outlook is put forward to promote the development of practical Li-S batteries through a fundamental understanding and practical exploration of the Li metal anode.
Article
Chemistry, Physical
Chaoqi Zhang et al.
Summary: A Mott-Schottky catalyst based on bimetallic phosphide CoFeP nanocrystals supported on carbon nitride tubular nanostructures is proposed to enhance the performance of lithium-sulfur batteries. The CoFeP@CN composites demonstrated superior rate performance and cycling stability, effectively addressing the issues often overlooked in LSBs.
ADVANCED ENERGY MATERIALS
(2021)
Review
Chemistry, Physical
Haeji Hong et al.
Summary: As research focuses shift towards the development of lithium-sulfur batteries, addressing key degradation of the metal anode and suppressing related side reactions are crucial steps towards commercialization. However, technical challenges surrounding the lithium metal anode must be overcome to enable practical applications and stimulate progress in parallel energy storage technologies.
JOURNAL OF MATERIALS CHEMISTRY A
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Songyan Bai et al.
Summary: The use of MOF gel separators in organic batteries can effectively address electrode dissolution and shuttle effect issues, improving cycle stability and capacity retention. This technology has great potential for various applications, as the pore size can be tailored to specific organic electrode materials.
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