Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 5, Issue 7, Pages 886-890Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201600149
Keywords
aromatic substitution; furoxans; nitrogen oxides; photochemistry; synthetic methods
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Funding
- Naito Foundation
- Inoue Science Research Award
- NOVARTIS Foundation (Japan) for the Promotion of Science
- TOBE MAKI Scholarship Foundation
- Kawanishi Memorial ShinMaywa Education Foundation
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The synthesis of 3- and 4-fluorofuroxans is reported for the first time. Under photoirradiation and physiological conditions, 4-fluorofuroxans with weaker nitric oxide-releasing ability are converted into 3-fluorofuroxans, which show remarkable thiol-mediated nitric oxide-releasing properties, thereby suggesting that 4-fluorofuroxans are potent photoinduced nitric oxide donors.
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