Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue 4, Pages 410-413Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201600547
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Funding
- MEXT
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [15K13699, 26248031] Funding Source: KAKEN
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Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztschester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of Pd-II to Pd-0 that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.
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