Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 5, Issue 9, Pages 1124-1127Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201600279
Keywords
aliphatic nitro compounds; continuous flow; heterogeneous catalysts; hydrogenation; palladium
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Global COE Program
- University of Tokyo, MEXT, Japan
- Japan Science and Technology Agency (JST)
- NEDO
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Hydrogenation of aromatic nitro compounds has been widely studied, however, the catalytic hydrogenation of aliphatic nitro compounds remains a challenging topic. Herein, a polysilane/bone charcoal-supported Pd catalyst with excellent catalyst activity for the hydrogenation of aliphatic nitro compounds under continuous-flow conditions is described. The catalyst was synthesized by a simple procedure and analyzed by STEM and energy dispersive X-ray spectroscopy (EDX) measurements. This polysilane/bone charcoal-supported Pd catalyst demonstrated higher catalyst activity than conventional Pd/C, and a wide substrate scope including secondary and tertiary nitro compounds was achieved. Furthermore, no catalyst deactivation was observed during 120h of continuous-flow reaction without leaching of Pd.
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