A facile synthesis of a MoS2/soluble g-C3N4/CdS ternary composite for high efficiency photocatalytic hydrogen production

In the present work, a ternary composite MoS2/soluble g-C3N4/CdS was synthesized using a facile one-pot hydrothermal reaction and conventional reflux reaction method. The composition, morphology, and properties of the ternary composite were characterized. The photocatalytic performance of the ternary composite was evaluated for hydrogen generation under LED lamp irradiation (450 nm < lambda < 465 nm) with lactic acid (LA) used as a sacrificial reagent. The results demonstrated that the maximum hydrogen production reached 4869.6 mmol under the optimal hydrogen production conditions, including a composition of 20% soluble g-C3N4, 9% MoS2, a solution pH of 1, and an irradiation time of 6 hours. The corresponding hydrogen production rate for the ternary composite was calculated to be 8116 mmol g(-1) h(-1). Furthermore, a possible electron transfer mechanism of the ternary composite system was briefly explored. The interaction and synergistic effects between MoS2, soluble g-C3N4, and CdS in the ternary composite likely facilitate efficient electron transfer, resulting in enhanced photocatalytic activity for hydrogen production. Mechanistic research showed that the electron transfer pathway represented either a double or single type II heterojunction photocatalytic system.

Automated summary

A ternary composite MoS2/soluble g-C3N4/CdS was synthesized and characterized. The composite exhibited high photocatalytic activity for hydrogen production under optimal conditions.