☆ 4.8 Review

Electrode Protection and Electrolyte Optimization via Surface Modification Strategy for High-Performance Lithium Batteries

ADVANCED FUNCTIONAL MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Liquid-Phase Integrated Surface Modification to Construct Stable Interfaces and Superior Performance of High-Voltage LiNi0.5Mn1.5O4 Cathode Materials

Xiang Ji et al.

Summary: Spinel LiNi0.5Mn1.5O4 (LNMO) with CeF3 coating and Ce doping on the surface shows improved interfacial stability and electrochemical properties. CeF3 coating alleviates the dissolution of transition-metal ions and the side reaction between LNMO and electrolyte, resulting in better structural stability and improved electronic conductivity. CeF3 modification also improves the electrochemical kinetic behavior and leads to optimal performance for LNMO electrode.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Chemistry, Applied

Enhancing structure and cycling stability of Ni-rich layered oxide cathodes at elevated temperatures via dual-function surface modification

Ying-De Huang et al.

Summary: This study presents a simple strategy to construct a dual-function protective layer on the surface of high-nickel single-crystal cathode material, which effectively stabilizes the structure and interface of the material. The obtained material demonstrates improved cycling stability and high capacity retention even at high temperatures and voltages.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Rational design of air-stable and intact anode-electrolyte interface for garnet-type solid-state batteries

Jiaxu Zhang et al.

Summary: Garnet-type solid-state electrolytes are considered as promising fast lithium-ion conductors due to their high room temperature ion conductivity and stability against lithium metal. However, the presence of lithiophobic Li2CO3 at the garnet/Li interface poses challenges for ionic contact. In this study, researchers chemically upcycled the Li2CO3 on the garnet surface through a double replacement reaction with SiO2, forming a stable and lithiophilic LixSiOy (LSO) layer that improved interfacial ion transport efficiency.

NANO ENERGY (2022)

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Article Chemistry, Multidisciplinary

In Situ-Formed LiF-Rich Multifunctional Interfaces toward Stable Li10GeP2S12-Based All-Solid-State Lithium Batteries

Lin Shen et al.

Summary: In this study, a simple and effective strategy to improve the stability of the Li/LGPS interface in all-solid-state lithium batteries was developed by constructing LiF-rich multifunctional interfaces on the Li metal surface. The LGPS-based lithium cells with the Li@LiF anode exhibited excellent cycling stability and rate capability, achieving a high capacity retention of 80.9% over 300 cycles at 0.1 C under 25 degrees C.

ADVANCED MATERIALS INTERFACES (2022)

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Article Engineering, Environmental

Minimizing the interfacial resistance for a solid-state lithium battery running at room temperature

Qianchen Wang et al.

Summary: Developed a high ionic conductivity and low activation energy LAGP ceramic solid electrolyte, modified its interface properties to stabilize the cycling life of lithium symmetric cells, and achieved superior electrochemical performance for solid-state lithium batteries with a LiFePO4 cathode.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Composite solid electrolytes containing single-ion lithium polymer grafted garnet for dendrite-free, long-life all-solid-state lithium metal batteries

Mian Liu et al.

Summary: Compared with traditional liquid electrolytes, composite solid electrolytes composed of polymer and inorganic particle fillers exhibit better electrochemical stability and safety in lithium-ion batteries. This study focuses on the development of a flexible anion-immobilized modified ceramic-polymer composite solid electrolyte that significantly increases lithium ion transference number and shows promising performance in all-solid-state batteries. The synthesized garnet-lithium single-ion polymer composite particles have great potential in the next generation of all-solid-state lithium metal batteries.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Cellulose-reinforced poly(cyclocarbonate-ether)-based composite polymer electrolyte and facile gel interfacial modification for solid-state lithium-ion batteries

Xiaojiao Zheng et al.

Summary: Synthesizing high-performance solid electrolytes with simple methods and common materials has always been a desire for lithium-ion batteries. This study successfully prepared composite polymer electrolytes via UV curing of a new matrix and ionic liquid, which showed improved electrochemical performance and safety. Additionally, a gel transition layer was added at the electrolyte/cathode interface to optimize their interfacial contact and enhance the rate and cycle performance of the solid-state battery.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Electrochemistry

Functionalized nano-SiO2 for improving the cycling stability of 4.6V high voltage LiCoO2 cathodes

Pan He et al.

Summary: The functionalization of nano SiO2 was achieved by using dopamine self polymerization coating, and it was uniformly coated onto LiCoO2 cathode through rotary steaming. The functional nanocoating showed a homogeneous distribution on the surface of LiCoO2 particles. The interaction between nano SiO2 coating and LiCoO2 particles enhanced the function of solid superacid formed by fumed SiO2, leading to improved interface stability and ionic conductivity of LiCoO2 cathodes at high voltage. The modified LiCoO2 cathode with functionalized nano-SiO2 exhibited a reversible capacity of around 190 mAh g(-1) with good capacity retention after cycles at room temperature and elevated temperature.

ELECTROCHIMICA ACTA (2022)

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Article Electrochemistry

A surface modification layer with cobalt aluminate inhibits 4.6 V high-voltage phase transition of LiCoO2

Zhi-Wei Li et al.

Summary: This study successfully achieved ultra-long cycling of lithium cobaltate at high voltage by using a surface modification layer. The strategy protects the electrode, reduces cobalt loss, and provides extra electrons for the lithium ion reactions.

ELECTROCHIMICA ACTA (2022)

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Article Chemistry, Physical

Enhanced 4.7 V Electrochemical Performance of the LiCoO2 Cathode via a Fluoride and LiCo1-xAlxO2 Composite Coating

Yunchao Liao et al.

Summary: Coating LiCoO2 with KAlF4 is an effective way to suppress structural collapse and surface side reactions at high voltage. The composite coating layer stabilizes the surface and improves lithium ion transport, resulting in improved electrochemical performance.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

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Article Materials Science, Multidisciplinary

LATP-coated NCM-811 for high-temperature operation of all-solid lithium battery

Min -Young Kim et al.

Summary: Coating the high-nickel cathode material surface with LATP using evaporation-induced self-assembly improves the high-temperature operation of all-solid lithium batteries. The LATP coating, which can improve lattice constant and structure through cation mixing, enhances the cycle capacity retention of the battery.

MATERIALS CHEMISTRY AND PHYSICS (2022)

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Article Materials Science, Multidisciplinary

Novel NiO surface coating on LiCoO2 cathode for Li-ion batteries

L.A. Benavides et al.

Materials Science and Engineering B-Advanced Functional Solid-State Materials (2022)

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Article Chemistry, Physical

Stabilizing High-Voltage LiNi0.5Mn1.5O4 Cathodes for High Energy Rechargeable Li Batteries by Coating With Organic Aromatic Acids and Their Li Salts

Sandipan Maiti et al.

Summary: In this study, three types of surface coatings based on adsorption of organic aromatic acids or their Li salts were applied to engineer the surface properties of high voltage LiNi0.5Mn1.5O4 (LNMO) spinel cathodes. The coatings significantly improved the capacity retention, rate performance, and cycling performance of the batteries, while reducing detrimental cation dissolution and ensuring structural stability at elevated temperatures.

SMALL METHODS (2022)

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Article Chemistry, Physical

A new surface phase of Al2Ti7O15 to enhance the electronic conductivity and interfacial stability of LiCoO2 cathode materials

Zhitao E et al.

Summary: In this study, the stability of LiCoO2 (LCO) under high cutoff voltages was improved by modifying it with Al-Mg-Ti co-doping and Al2O3 coating. The modified LCO showed enhanced electrochemical and kinetic performances. A new phase, Al2Ti7O15 (ATO), was discovered near the surface of the modified LCO, which improved electron conductivity and transmission property of lithium ions. This work provides new insights into the effect of Al-Mg-Ti co-doping on LCO materials.

APPLIED SURFACE SCIENCE (2022)

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Article Electrochemistry

Enable High-Energy LiNi0.5Co0.2Mn0.3O2 by Ultra-Thin Coating through Wet Impregnation

Xin Su et al.

Summary: To solve the instability issue between nickel-rich layered oxide LiNixCoyMnzO2 (NCM) and liquid electrolytes, researchers have developed a wet impregnation method to apply an ultra-thin Al2O3 coating layer on the surface of NCM particles. This coating layer interacts strongly with the particles and results in surface Al-doped NCM, reducing the surface resistance of lithium diffusion and stabilizing the solid electrolyte interface. Compared to other methods, wet impregnation coating provides a low-cost, ultra-thin and uniform coating with surface doping on NCM particles.

BATTERIES-BASEL (2022)

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Article Chemistry, Physical

Stable 4.5 V LiCoO2 cathode material enabled by surface manganese oxides nanoshell

Jun Wang et al.

Summary: Coating LiCoO2 (LCO) cathode with manganese oxides (MOs) nanoshell effectively alleviates organic electrolyte decomposition, ensures a stable cathode-electrolyte interface, lowers interfacial resistance, and improves structural stability, resulting in excellent rate performance, high discharge capacity retention, and enhanced thermal stability and cyclability at elevated temperature compared to untreated LCO.

NANO RESEARCH (2022)

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Review Materials Science, Multidisciplinary

Prussian-blue materials: Revealing new opportunities for rechargeable batteries

Qianchen Wang et al.

Summary: This paper reviews the recent progress in the application of Prussian blue cathode materials for rechargeable batteries, including charge-storage mechanisms, factors influencing electrochemical performances, and possible approaches to overcome their intrinsic limitations.

INFOMAT (2022)

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Article Chemistry, Physical

Highly stable and high-performance MgHPO4 surface-modified Ni-rich cathode materials for advanced lithium ion batteries

Do-Young Hwang et al.

Summary: In this paper, a novel strategy to improve the cathode material of NCM for lithium-ion batteries (LIBs) is proposed. The Mg-doped and Li3PO4-coated NCM cathode material shows advanced discharge capacity, rate capability, and cycling performance. The dual-modification of MgHPO4 on the NCM particle effectively prevents the phase transition, providing potential for commercialization acceleration.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Electrochemistry

Modification of LiCoO2through rough coating with lithium lanthanum zirconium tantalum oxide for high-voltage performance in lithium ion batteries

Han-Lin Guo et al.

Summary: The study demonstrated that rough coating an adequate quantity of Li(6.75)La(3)Zr(1.75)Ta(0.25)O(12) powder on a LiCoO(2) cathode can significantly enhance the discharge capacity, capacity retention, and thermal stability of the material. The modified cathodes showed more than double the discharge capacity compared to bare cathodes at high discharge current density. Overall, the surface modification improved the electrochemical performance and stability of the LiCoO(2) cathode material.

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Achieving Stable Cycling of LiCoO2 at 4.6 V by Multilayer Surface Modification

Cheng Tao et al.

Summary: LiCoO2, first proposed as a cathode material by Prof. John B. Goodenough in 1980, remains one of the most popular commercial cathodes for lithium-ion batteries. Efforts have been made to increase its capacity by charging to high voltage, but issues such as structural instability and side reactions with electrolytes can occur. A surface modification strategy with a multilayer structure involving Zn-rich coating, rock-salt buffer layer, and Al doping layer has been proposed to enhance stability and achieve stable cycling of LiCoO2 at 4.6 V, with a capacity retention of 65.7% after 500 cycles.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

A Morphologically Stable Li/Electrolyte Interface for All-Solid-State Batteries Enabled by 3D-Micropatterned Garnet

Rong Xu et al.

Summary: The use of a novel 3D-micropatterned solid-state electrolyte can stabilize the morphology of the Li/SSE interface even under high current density and limited stack pressure, preventing interface degradation.

ADVANCED MATERIALS (2021)

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Article Electrochemistry

Enhanced interfacial reaction interface stability of Ni-rich cathode materials by fabricating dual-modified layer coating for lithium-ion batteries

Hongqiang Wang et al.

Summary: This study presents a coating modification strategy to synthesize LiAlO2/LiF&AlF3 hybrid coating layer on the surface of LiNi0.6Co0.2Mn0.2O2 materials, which effectively mitigates structural degradation and intergranular cracks, demonstrating good performance during long-term cycling.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

Improving electrochemical performances of LiNi0.5Mn1.5O4 by Fe2O3 coating with Prussian blue as precursor

Xuan Li et al.

Summary: Coating a uniform Fe2O3 layer on the surface of LNMO can increase the specific capacity and capacity retention, suppress side reactions and the dissolution of Mn and Ni, making it a promising candidate for high-energy lithium-ion batteries.

IONICS (2021)

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Article Chemistry, Physical

Effects of MoO3 coating on the structure and electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4

Ni Bai et al.

Summary: Coating the high-voltage spinel LiNi0.5Mn1.5O4 cathode material with MoO3 oxides significantly improves its electrochemical cycling performance at both room and elevated temperatures, with capacity retention increasing to 90-93% after 100 cycles at 55 degrees C. This improvement is attributed to the stabilized structure of LiNi0.5Mn1.5O4 and reduced electrolyte decomposition and metal dissolution with MoO3 coating.

IONICS (2021)

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Article Chemistry, Physical

Dually modified cathode-electrolyte interphases layers by calcium phosphate on the surface of nickel-rich layered oxide cathode for lithium-ion batteries

Hye Ji Song et al.

Summary: Using calcium phosphate as a coating precursor for surface modification improves the stability and cycling retention of layered nickel-rich cathode materials, while preventing electrolyte decomposition at high temperatures. The artificial cathode-electrolyte interphases formed during surface modification play a key role in inhibiting undesired surface reactions and enhancing electrochemical performances.

JOURNAL OF POWER SOURCES (2021)

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Article Chemistry, Physical

Surface modification with oxygen vacancy in LiNi0.5Co0.2Mn0.3O2 for lithium-ion batteries

Liwei Feng et al.

Summary: Well-distributed smaller sized Graphene-Oxide-treated LiNi0.5Co0.2Mn0.3O2 (GO-treated NCM) layered cathodes were synthesized successfully using a hydrothermal method, exhibiting excellent capacity retention and energy density during cycling.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

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Article Electrochemistry

Surface Engineered Li Metal Anode for All-Solid-State Lithium Metal Batteries with High Capacity

Yanan Shi et al.

Summary: The study introduces a surface modification strategy to reconstruct the Li/Li10GeP2S12 interface in order to address issues in all-solid-state batteries. By forming amorphous Li3PO4 on Li, parasitic side reactions are suppressed, leading to stable cycling performance and improved reversible discharge capacity.

CHEMELECTROCHEM (2021)

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Article Energy & Fuels

A Low Temperature Self-Assembled ZrO2 Layer as a Surface Modification for High Energy Density Ni-Rich Cathode Materials in a Lithium-Ion Battery

Van-Chuong Ho et al.

Summary: Research shows that surface coating of Ni-rich layered oxide cathodes can improve electrochemical performance, with the self-assembled ZrO2 coating enhancing surface stability and promoting high lithium ion diffusion.

ENERGY TECHNOLOGY (2021)

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Article Chemistry, Analytical

Achieving superior high-rate cyclability of LiNi0.5Mn1.5O4 cathode material via constructing stable CuO modification interface

Shan Wang et al.

Summary: The CuO coating is successfully constructed to stabilize the surface structure of LNMO, leading to excellent rate performance and cyclability of the material. The enhancement of structural stability and lithium ion diffusion rate by the CuO coating contribute to the outstanding electrochemical performances of the LNMO cathode material.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Nanoscience & Nanotechnology

Tailoring Electrode-Electrolyte Interfaces in Lithium-Ion Batteries Using Molecularly Engineered Functional Polymers

Laisuo Su et al.

Summary: Tailoring electrode-electrolyte interfaces (EEIs) using nanoscale polymer thin films deposited via chemical vapor deposition (CVD) can enhance the rate of Li+ transport and improve the charging speed of LiCoO2 in lithium-ion batteries (LIBs). PEDOT coatings form chemical bonds with LiCoO2, reducing Co dissolution and inhibiting electrolyte decomposition, leading to a significant increase in the cycle life of LiCoO2.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Elevated Lithium Ion Regulation by a Natural Silk Modified Separator for High-Performance Lithium Metal Anode

Xiang Li et al.

Summary: This research developed a functional modification layer from a derivant of natural silk to protect the lithium anode, offering abundant functional group sites for efficient uniform Li-ion flux and in situ formation of a Li3N-rich solid electrolyte interphase film. The high-performance lithium metal anode achieved dendrite-free morphology and significantly enhanced cycle stability, showing long-term cycling stability of 3000 cycles when paired with LiFePO4 cathodes and over 400 cycles with sulfur cathodes. This study provides a facile and practical approach for interface modification of the high-performance lithium anode and explores the application of biomass-based materials in advanced batteries.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Lithium Metal Electrode with Increased Air Stability and Robust Solid Electrolyte Interphase Realized by Silane Coupling Agent Modification

Yanyan Wang et al.

Summary: This study utilizes a silane coupling agent to improve the solid electrolyte interphase (SEI) layer of Li metal electrodes, enhancing their electrochemical performance and oxidation resistance. The silane coupling agent can bridge Li metal and the SEI layer through chemical bonding and physical intertwining effects, leading to excellent electrode performance.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

Covalent grafting interface engineering to prepare highly efficient and stable polypropylene/mesoporous SiO2 separator for Li-ion batteries

Xingtao Qi et al.

Summary: The covalent grafting interface engineering strategy improves the interfacial stability of the PP-g-mSiO(2) separator, while the mSiO(2) NPs assist in increasing the storage of electrolyte, resulting in high thermal stability, high electrolyte affinity, and fast lithium-ion diffusion. When used in LIBs, the PP-g-mSiO(2) separator demonstrates excellent rate capability and high capacity retention, showcasing stable covalent grafting ceramic surface and enhanced electrolyte affinity.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Inorganic & Nuclear

被撤回的出版物: Hydrothermal MgF2 surface treatment of LiNi0.5Mn1.5O4 high voltage cathode materials for lithium-ion batteries (Retracted article. See vol. 320, 2023)

Artur Tron et al.

Summary: The research demonstrates the surface modification of LiNi0.5Mn1.5O4 cathode material with MgF2 through a facile hydrothermal method and additional heat treatment, showing that 1 wt% MgF2-coated LNMO exhibits the best electrochemical performance with higher specific capacities and lower surface resistance after 150 cycles.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Cooperative Shielding of Bi-Electrodes via In Situ Amorphous Electrode-Electrolyte Interphases for Practical High-Energy Lithium-Metal Batteries

Jia-Yan Liang et al.

Summary: The study proposes a dual-interface protection strategy which effectively combines solid-state and liquid-state batteries, addressing main challenges while maintaining energy density.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Electrochemistry

Enhanced electrochemical performance of Ni-rich cathode material by N-doped LiAlO2 surface modification for lithium-ion batteries

Qingyu Li et al.

Summary: The study demonstrates that surface modification with N-doped LiAlO2 greatly enhances the electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathodes, leading to improved cycling performance and capacity retention. This modification effectively suppresses surface side reactions, structural degradation, and intergranular cracks, showing potential for higher rate operations.

ELECTROCHIMICA ACTA (2021)

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Article Engineering, Chemical

Bio-mimicking organic-inorganic hybrid ladder-like polysilsesquioxanes as a surface modifier for polyethylene separator in lithium-ion batteries

Su Cheol Shin et al.

Summary: The ladder-like polysilsesquioxanes were utilized as a surface modifier for polyethylene separators in high performing lithium ion batteries, significantly improving capacity retention and cycle stability. The LIBs fabricated using this modified separator demonstrated excellent performance under 0.5C rate.

JOURNAL OF MEMBRANE SCIENCE (2021)

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Article Chemistry, Physical

Facile interface functionalization of Ni-rich layered LiNi0.8Co0.1Mn0.1O2 cathode material by dually-modified phosphate and aluminum precursor for Li-ion batteries

Seong Ho Oh et al.

Summary: Dually-functionalized Ni-rich NCM cathode materials are developed using aluminum phosphate for surface modification, which effectively suppress undesired reactions and improve cycling retention.

SOLID STATE IONICS (2021)

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Article Chemistry, Physical

A mechanically robust self-healing binder for silicon anode in lithium ion batteries

Hao Chen et al.

Summary: Silicon is considered the most promising anode material for next-generation lithium ion batteries, but silicon particles undergo volume changes and pulverization during charge/discharge processes, damaging the longevity of silicon anodes. This study synthesized a novel self-healing binder to repair the damage to silicon anodes, achieving excellent electrochemical performance.

NANO ENERGY (2021)

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Article Energy & Fuels

Rejuvenating dead lithium supply in lithium metal anodes by iodine redox

Chengbin Jin et al.

Summary: The researchers use an iodic species to react with inactive lithium, bringing it back to life and thus making batteries last longer.

NATURE ENERGY (2021)

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Article Chemistry, Physical

Bulk and surface degradation in layered Ni-rich cathode for Li ions batteries: Defect proliferation via chain reaction mechanism

Chengkai Yang et al.

Summary: Ni-rich cathode materials face bulk and surface degradation issues, with rock-salt phase structure observed deteriorating. First-principle calculation simulations reveal a triggered phase transition by defect chain reaction (DCR) mechanism.

ENERGY STORAGE MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Atomic Layer Deposition of a Nanometer-Thick Li3PO4 Protective Layer on LiNi0.5Mn1.5O4 Films: Dream or Reality for Long-Term Cycling?

Maxime Hallot et al.

Summary: LNMO is a promising electrode for high voltage batteries, but faces issues with manganese dissolution and electrolyte decomposition. A surface protective layer made by atomic layer deposition method can improve stability, however, long-term cycling may cause mechanical failure within the films.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

10 μm-Thick High-Strength Solid Polymer Electrolytes with Excellent Interface Compatibility for Flexible All-Solid-State Lithium-Metal Batteries

Zhiyan Wang et al.

Summary: This study presents an ultrathin solid polymer electrolyte with high ionic conductance and excellent mechanical properties, showing promising stability in various battery systems, particularly in all-solid-state lithium-metal batteries.

ADVANCED MATERIALS (2021)

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Article Materials Science, Ceramics

Enhanced high-voltage performance of LiCoO2 cathode by directly coating of the electrode with Li2CO3 via a wet chemical method

Qianchang Tang et al.

Summary: Surface modification with Li2CO3 significantly improves the cycling stability and initial coulombic efficiency of LiCoO2 electrodes, with the electrode coated for 2 minutes showing the best electrochemical performance.

CERAMICS INTERNATIONAL (2021)

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Article Engineering, Chemical

Fabrication of polymer electrolyte via lithium salt-induced surface-initiated radical polymerization for lithium metal batteries

Yong Zhang et al.

Summary: The cellulose-based polymer electrolyte fabricated through Li salt-induced surface-initiated polymerization shows high ionic conductivity, good thermal stability, and wide electrochemical stability window, demonstrating promising performance in high-performance Li metal batteries.

JOURNAL OF MEMBRANE SCIENCE (2021)

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Article Chemistry, Physical

LiNbO3-coated LiNi0.7Co0.1Mn0.2O2 and chlorine-rich argyrodite enabling high-performance solid-state batteries under different temperatures

Linfeng Peng et al.

Summary: The study investigates the enhancement of solid-state battery performance by surface modification of high-voltage cathodes using LiNbO3 coating. The LNO@NCM712 electrode shows improved cyclic performance and lower resistance changes at different rates and temperatures, providing insight into the influence of modification layers on SSB performance and guidance for cathode modification design strategy.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Stable all-solid-state lithium metal batteries with Li3N-LiF-enriched interface induced by lithium nitrate addition

Zhao Zhang et al.

Summary: This research introduces stable Li3N-LiF enriched interface in-situ induced by lithium nitrate (LiNO3) between poly (ethylene oxide) (PEO)-based solid electrolyte and Li anode, to improve the interface contact between solid electrolyte and Li anode, leading to homogeneous Li deposition. When paired with LiFePO4 cathode, the all-solid-state LMBs demonstrate superior cycling stability and Coulombic efficiency, showing promising prospects for potential applications.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Confining invasion directions of Li+ to achieve efficient Si anode material for lithium-ion batteries

Ziqi Zhang et al.

Summary: A novel silicon nano-ribbon (SiNR) with (110) crystal plane was proposed as an anode for Lithium-ion batteries, showing stability and high capacity retention during cycling. SiNR, without the need for surface coating treatment, exhibited high ionic conductivity and long cycling stability.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Realizing an Excellent Cycle and Rate Performance of LiCoO2 at 4.55 V by Li Ionic Conductor Surface Modification

Bin Shen et al.

Summary: Surface modification of LiCoO2 with the lithium ionic conductor LiAlSiO4 enhances its electrochemical performance at a high cutoff voltage of 4.55 V, resulting in higher reversible specific capacity and excellent rate capability. This improvement is attributed to the effective stabilization of the surface and bulk structure by LiAlSiO4 coating, making it a promising strategy to enhance the electrochemical performance of high-voltage LiCoO2.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Surface-Modified Lithium Cobalt Oxide (LiCoO2) with Enhanced Performance at Higher Rates through Li-Vacancy Ordering in the Monoclinic Phase

Govind Kumar Mishra et al.

Summary: A targeted strategy of coating LCO cathode with LCMO has been adopted to improve its structural stability and battery safety. The coating also enables faster cycling rate and longer periods of time for charging and discharging.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Improving Electrochemical Performance of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathodes by Silicon Oxide Surface Modification

Chunze Ma et al.

Summary: The SiO2 modification of the LNMO cathode material improved the cycling performance and rate capability of the battery.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Applied

Constructing a uniform lithium iodide layer for stabilizing lithium metal anode

Yingxin Lin et al.

Summary: A uniform LiI protective layer is constructed on the Li metal anode via a simple solid-gas reaction, enhancing the cycling lifetime and capacity retention of the battery. This method provides a practical approach for the commercialization of high-energy Li metal batteries.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Editorial Material Energy & Fuels

Layered lithium cobalt oxide cathodes

Arumugam Manthiram et al.

Summary: Lithium cobalt oxide was the pioneering cathode material for lithium-ion batteries, paving the way for the development of layered-oxide compositions that are now prevalent in the automotive battery industry.

NATURE ENERGY (2021)

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Article Chemistry, Physical

Lithium-Aluminum-Phosphate coating enables stable 4.6 V cycling performance of LiCoO2 at room temperature and beyond

Xiao Wang et al.

Summary: By using a surface engineering strategy with lithium-aluminum-phosphate composite coating materials, stable cycling of LCO at 4.6 V (vs. Li/Li+) was achieved, preventing direct contact between the cathode and electrolyte, reducing active material loss without hindering lithium ion migration. The doping layer formed after calcination includes phosphorus and aluminum, helping maintain surface structure and stabilize oxygen atoms around the particle surface, showing high ion mobility when operated at 4.6 V (vs. Li/Li+).

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Instantaneous Surface Li3PO4 Coating and Al-Ti Doping and Their Effect on the Performance of LiNi0.5Mn1.5O4 Cathode Materials

Valeriu Mereacre et al.

Summary: The use of H2O2 activated the surface of LNMO, facilitating the uniform deposition of Li, Al, Ti, and phosphate ions, leading to improved cycling performance and Coulombic efficiency of the battery cathode material.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Facile Fabrication of Functionalized Separators for Lithium-Ion Batteries with Ionic Conduction Path Modifications via the γ-Ray Co-irradiation Grafting Process

Haoshen Ma et al.

Summary: Improving the porous structure of separators in lithium-ion batteries can optimize battery performance, especially by enhancing the ionic conduction path with the introduction of functional groups, resulting in improved cycle stability and capacity retention.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Modification of the LiFePO4 (010) Surface Due to Exposure to Atmospheric Gases

Karol Jarolimek et al.

Summary: The research investigates the surface chemistry of LFP under different temperature and gas partial pressure conditions, as well as the impact of adsorbates such as molecular oxygen and water on surface properties.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Reclaiming Inactive Lithium with a Triiodide/Iodide Redox Couple for Practical Lithium Metal Batteries

Cheng-Bin Jin et al.

Summary: This study demonstrates that the triiodide/iodide redox couple can significantly reclaim inactive Li, improving the cyclability of lithium metal batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Flame retardant vermiculite coated on polypropylene separator for lithium-ion batteries

Maria Carter et al.

Summary: Lithium-ion batteries are widely used in various applications due to their desirable energy storage characteristics, but they are prone to thermal runaway. By using vermiculite as a separator lining, the battery demonstrated enhanced safety by releasing less exothermic energy during thermal runaway and having a higher separator melting temperature.

APPLIED CLAY SCIENCE (2021)

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Article Engineering, Environmental

Nanoscale operation of Ni-Rich cathode surface by polycrystalline solid electrolytes Li3.2Zr0.4Si0.6O3.6 coating

Jianying Li et al.

Summary: A facile one-step chemical approach using nanoscale polycrystalline of solid electrolyte Li3.2Zr0.4Si0.6O3.6 (NP-LZSO) is reported for building a conductive protective coating on Ni-rich cathode LiNi0.8Co0.15Mn0.05O2 (NCM), which significantly improves cycling stability with a capacity retention rate of 79.9% over 400 cycles at 0.2C. This effective strategy provides a new insight using nanoscale polycrystalline of solid electrolyte to modify surface of nickel-rich cathodes to improve its cyclic performance.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Poly(ethylene glycol) brush on Li6.4La3Zr1.4Ta0.6O12 towards intimate interfacial compatibility in composite polymer electrolyte for flexible all-solid-state lithium metal batteries

Qingya Guo et al.

Summary: By modifying LLZTO nanoparticles with surface functionalization, the interfacial compatibility with PEO was enhanced. This resulted in significantly improved ionic conductivity and cycling stability of the LLZTO/PEO composite polymer electrolyte.

JOURNAL OF POWER SOURCES (2021)

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Article Chemistry, Physical

Bidirectionally Compatible Buffering Layer Enables Highly Stable and Conductive Interface for 4.5 V Sulfide-Based All-Solid-State Lithium Batteries

Longlong Wang et al.

Summary: A bidirectionally compatible buffering layer design scheme is proposed to overcome the interfacial challenges of sulfide-based HVASSLBs, leading to significantly enhanced performance in terms of initial discharge capacity, capacity retention, and rate performance.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Lattice Oxygen Instability in Oxide-Based Intercalation Cathodes: A Case Study of Layered LiNi1/3Co1/3Mn1/3O2

Xueyan Hou et al.

Summary: The lattice oxygen stability of oxide-based cathode materials is crucial for the performance of secondary batteries. This study investigates the oxygen release behavior in layered rock-salt LiNi1/3Co1/3Mn1/3O2-δ, revealing that factors such as high valent Ni and Li''TM aggravate oxygen release, leading to structural deterioration. The findings provide new research directions and guidelines for stabilizing lattice oxygen in oxide-based intercalation cathodes.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Highly Stable Quasi-Solid-State Lithium Metal Batteries: Reinforced Li1.3Al0.3Ti1.7(PO4)3/Li Interface by a Protection Interlayer

Zhen Chen et al.

Summary: A multi-layer electrolyte structure comprising LATP, PVDF-TrFE, and ILE, along with an additional protective layer of PTNB coated on Li, has successfully addressed the brittleness and instability issues of solid electrolytes; Significant improvement in lithium battery performance is achieved by reducing interfacial resistances, preventing dendritic lithium growth, mitigating cathode material phase changes, and preventing internal microcrack formation.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

A Perspective on the Sustainability of Cathode Materials used in Lithium-Ion Batteries

Beth E. Murdock et al.

Summary: The rise of electric vehicles has highlighted the importance of lithium-ion batteries as a vital green technology, but the large-scale mining for battery materials raises concerns regarding resource depletion and environmental, social, and governance issues. Insufficient research has been conducted on the socioenvironmental impacts of lithium-ion battery technology in the past, and the potential implications of increased nickel use in material management and development disciplines also lack attention.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Surface Modification of Nanocrystalline LiMn2O4 Using Graphene Oxide Flakes

Monika Michalska et al.

Summary: The electrochemical performance of lithium manganese oxide composites with graphene oxide in Li-ion batteries was studied, showing that the composite with 5%wt. graphene oxide exhibited better capacity retention after cycling.

MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Alleviating the Storage Instability of LiNi0.8Co0.1Mn0.1O2 Cathode Materials by Surface Modification with Poly(acrylic acid)

Shiyun Peng et al.

Summary: This study successfully alleviated the negative impact of higher nickel content on the storage stability of cathode materials by developing a surface modification method. The modified materials showed improved performance under high temperature and humidity conditions.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Physical

In situ constructing a stable interface film on high-voltage LiCoO2 cathode via a novel electrolyte additive

Digen Ruan et al.

Summary: The novel electrolyte additive ATCN is proposed to enhance the stability of LiCoO2 cathode under high-voltage conditions, significantly improving cycling performance. Experimental and theoretical analyses show that ATCN preferentially oxidizes on the cathode, converting detrimental components in the electrolyte into a unique film texture that enhances cathode/electrolyte interface stability and overall cell cycling stability.

NANO ENERGY (2021)

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Article Chemistry, Multidisciplinary

Sowing Silver Seeds within Patterned Ditches for Dendrite-Free Lithium Metal Batteries

Hua Wang et al.

Summary: The Li anode with silver nanowires sowed in patterned ditches shows improved stability and cycling performance, with excellent cyclability achieved under specific current and capacity conditions. Pairing this anode with specific cathodes also demonstrates long cycle life and minimal gas generation in full cells over extended cycling, showcasing the effectiveness of the authors' strategy for LMBs.

ADVANCED SCIENCE (2021)

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Article Materials Science, Multidisciplinary

Graphene wrapped Y2O3 coated LiNi0.5Mn1.5O4 quasi-spheres as novel cathode materials for lithium-ion batteries

Hanan Abdurehman Tariq et al.

Summary: The study successfully synthesized Y2O3-coated quasi-spheres of high-energy density LiNi0.5Mn1.5O4 cathode material covered in graphene using a microwave-assisted chemical co-precipitation technique. The graphene-assisted coating not only improves the electrical conductivity of the electrode but also effectively inhibits the production of undesirable phases, enhancing the cyclic performance of the material. Furthermore, the proposed material synthesis strategy provides a new approach for the study of other types of electrode materials.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2021)

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Article Chemistry, Physical

A Lithium-Metal Anode with Ultra-High Areal Capacity (50 mAh cm-2) by Gridding Lithium Plating/Stripping

Pan Xu et al.

Summary: By using a functionalized framework and a phosphorized copper mesh as a support skeleton, a lithium anode with excellent performance and practical application significance has been achieved, addressing the issues encountered during Li plating/stripping process in lithium metal batteries.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Physical

Bifunctional Sulfonated Graphene-Modified LiNi0.5Mn1.5O4 for Long-Life and High-Energy-Density Lithium-Ion Batteries

Huiling Chen et al.

Summary: This paper utilizes sulfonated graphene (SA-GE) to modify high-voltage LiNi0.5Mn1.5O4, achieving greatly improved cycling life and rate capability. The SA-GE layer inhibits the rapid growth of the cathode electrolyte interphase (CEI) layer, enhances Li+ diffusion kinetics, reduces polarization degree, charge transfer resistance, and structure degradation of the cathode. This demonstrates that optimized chemical decorations of graphene modifiers with sulfonic acid groups are a promising strategy for constructing lithium-ion batteries with long life and high energy density.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Improving the electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathodes using a simple Ce4+-doping and CeO2-coating technique

Yanhua Feng et al.

Summary: Ce4+ doping and CeO2 coating of NCM particles can reduce Li+/Ni2+ mixing, enhance structural stability, and improve Li+ diffusion, leading to a higher capacity retention rate during cycling.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

An artificial hybrid interphase for an ultrahigh-rate and practical lithium metal anode

Anjun Hu et al.

Summary: An artificial hybrid SEI layer composed of lithium-antimony alloy and lithium fluoride was constructed to reduce electron tunneling between the Li anode and SEI, resulting in uniform Li deposition and stable Li plating/stripping behaviors at an ultrahigh rate. This work uncovers the internal mechanism of Li+ transport within the SEI component, providing a pathway to stabilize the Li anode under practical high-rate conditions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Physical

Interplay between multiple doping elements in high-voltage LiCoO2

Sicheng Song et al.

Summary: The interplay between doping elements in Ni-Ti-Mg co-doping LCO has been clearly revealed, showing that poly-crystallization and grain boundary enrichment can enhance capacity retention and stability in high-voltage LCO batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Titanium and fluorine synergetic modification improves the electrochemical performance of Li(Ni0.8Co0.1Mn0.1)O2

Zheng Si et al.

Summary: In this study, Ti and F co-doping was employed to improve the performance of nickel-rich layered oxides (NCM) cathode materials, demonstrating enhanced cycle stability and discharge capacity, as well as reduced charge transfer resistance. The results suggest that Ti4+ and F- co-doping can effectively modulate the crystal structure of the cathode material, leading to improved electrochemical performance and providing a new strategy for enhancing lithium-ion battery performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Selective extraction of lithium from a spent lithium iron phosphate battery by mechanochemical solid-phase oxidation

Kang Liu et al.

Summary: This study presents a green process for the selective and rapid extraction of lithium from spent lithium iron phosphate (LiFePO4) batteries via mechanochemical solid-phase oxidation. The designed process is acid/base free, has an extremely short time, wastewater-free discharge, and high economic profit. The results show that mechanochemical solid-phase oxidation can selectively release lithium from LiFePO4, providing a new approach to the recovery of lithium.

GREEN CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Structure Code for Advanced Polymer Electrolyte in Lithium-Ion Batteries

Jirong Wang et al.

Summary: This review summarizes recent advances in high-performance lithium-ion batteries prepared using well-defined polymer electrolytes, discussing ion-transport mechanisms and preparation techniques. The aim of the research is to elucidate the structure code for advanced polymer electrolytes with optimized properties and to discuss existing challenges and future perspectives.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Applied

High performance columnar-like Fe2O3@carbon composite anode via yolk@shell structural design

Zhiming Zheng et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Article Engineering, Environmental

Fluorine doped carbon coating of LiFePO4 as a cathode material for lithium-ion batteries

Xufeng Wang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

High-voltage LiNi0.5Mn1.5O4 thin film cathodes stabilized by LiPON solid electrolyte coating to enhance cyclic stability and rate capability

Shasha Lv et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Chemistry, Physical

Engineering interfacial adhesion for high-performance lithium metal anode

Bingqing Xu et al.

NANO ENERGY (2020)

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Article Nanoscience & Nanotechnology

Functional Electrolyte of Fluorinated Ether and Ester for Stabilizing Both 4.5 V LiCoO2 Cathode and Lithium Metal

Shuangshuang Lin et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Physics, Applied

Decoration by dual-phase Li2ZrO3 islands with core-shell structures enhances the electrochemical performance of high-voltage LiNi0.5Mn1.5O4

R. Zhao et al.

APPLIED PHYSICS LETTERS (2020)

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Article Chemistry, Physical

Facile and efficient fabrication of Li3PO4-coated Ni-rich cathode for high-performance lithium-ion battery

Pinjuan Zou et al.

APPLIED SURFACE SCIENCE (2020)

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Article Engineering, Environmental

Design of Li2FeSiO4 cathode material for enhanced lithium-ion storage performance

Hailong Qiu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Electrical & Electronic

Improve electrochemical performance of spinel LiNi0.5Mn1.5O4 via surface modified by Li1.2Ni0.2Mn0.6O2 layered materials

Jidong Duan et al.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2020)

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Article Chemistry, Physical

A novel polymer-modified separator for high-performance lithium-ion batteries

Caihong Xue et al.

JOURNAL OF POWER SOURCES (2020)

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Article Chemistry, Physical

Constructing tri-functional modification for spinel LiNi0.5Mn1.5O4 via fast ion conductor

Li Li et al.

JOURNAL OF POWER SOURCES (2020)

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Article Chemistry, Physical

Garnet Si-Li7La3Zr2O12 electrolyte with a durable, low resistance interface layer for all-solid-state lithium metal batteries

Xiaoning Ma et al.

JOURNAL OF POWER SOURCES (2020)

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Article Chemistry, Physical

Suppressing Voltage Fading of Li-Rich Oxide Cathode via Building a Well-Protected and Partially-Protonated Surface by Polyacrylic Acid Binder for Cycle-Stable Li-Ion Batteries

Jingsong Yang et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

The Synergetic Effect of LiMg0.5Mn1.5O4 Coating and Mg2+ Doping on Improving Electrochemical Performances of High-Voltage LiNi0.5Mn1.5O4 by Sol-Gel Self-Combustion Method

Xuan Li et al.

CHEMISTRYSELECT (2020)

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Article Nanoscience & Nanotechnology

Lithium Fluoride Coated Silicon Nanocolumns as Anodes for Lithium Ion Batteries

Jie Lin et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Nanoscience & Nanotechnology

Delayed Phase Transition and Improved Cycling/Thermal Stability by Spinel LiNi0.5Mn1.5O4 Modification for LiCoO2 Cathode at High Voltages

Peipei Pang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Ultrastable Silicon Anode by Three-Dimensional Nanoarchitecture Design

Gang Huang et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Ti3C2Tx MXene Nanosheets as a Robust and Conductive Tight on Si Anodes Significantly Enhance Electrochemical Lithium Storage Performance

Mengting Xia et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

A Mixed Lithium-Ion Conductive Li2S/Li2Se Protection Layer for Stable Lithium Metal Anode

Fanfan Liu et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Electrochemistry

Boosted electrochemical performance of LiNi0.5Mn1.5O4 via synergistic modification of Li+-Conductive Li2ZrO3 coating layer and superficial Zr-doping

Jianning Zhang et al.

ELECTROCHIMICA ACTA (2020)

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Article Electrochemistry

Nanocomposite solid polymer electrolytes based on semi-interpenetrating hybrid polymer networks for high performance lithium metal batteries

Elisabetta Fedeli et al.

ELECTROCHIMICA ACTA (2020)

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Article Electrochemistry

Realizing Superior Cycle Stability of a Ni-Rich Layered LiNi0.83Co0.12Mn0.05O2 Cathode with a B2O3 Surface Modification

Qiang Li et al.

CHEMELECTROCHEM (2020)

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Article Chemistry, Physical

Enhance electrochemical performance of LiFePO4 cathode material by Al-doped Li7La3Zr2O12 and carbon co-coating surface modification

Yu-Xuan Bai et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Chemistry, Analytical

UV-curable PVdF-HFP-based gel electrolytes with semi-interpenetrating polymer network for dendrite-free Lithium metal batteries

Haoyu Fan et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Physical

Toward a high-voltage fast-charging pouch cell with TiO2 cathode coating and enhanced battery safety

Yan Li et al.

NANO ENERGY (2020)

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Article Chemistry, Physical

Stress-relieving defects enable ultra-stable silicon anode for Li-ion storage

Yunzhan Zhou et al.

NANO ENERGY (2020)

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Article Nanoscience & Nanotechnology

Improved Cycling Stability of LiCoO2 at 4.5 V via Surface Modification of Electrodes with Conductive Amorphous LLTO Thin Film

Shipai Song et al.

NANOSCALE RESEARCH LETTERS (2020)

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Article Energy & Fuels

Binder-Free TiO2-Coated Polypropylene Separators for Advanced Lithium-Ion Batteries

Miao Zhu et al.

ENERGY TECHNOLOGY (2020)

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Article Chemistry, Physical

An Extremely Fast Charging Li3V2(PO4)3 Cathode at a 4.8 V Cutoff Voltage for Li-Ion Batteries

Qiao Ni et al.

ACS ENERGY LETTERS (2020)

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Article Chemistry, Multidisciplinary

Enhancement of Electrochemical Performance of LiFePO4@C by Ga Coating

Dawei Yi et al.

ACS OMEGA (2020)

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Article Nanoscience & Nanotechnology

Fast Charge Transfer across the Li7La3Zr2O12 Solid Electrolyte/LiCoO2 Cathode Interface Enabled by an Interphase-Engineered All-Thin-Film Architecture

Jordi Sastre et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Materials Science, Multidisciplinary

Amino-Functionalized Al2O3 Particles Coating Separator with Excellent Lithium-Ion Transport Properties for High-Power Density Lithium-Ion Batteries

Hui Zhang et al.

ADVANCED ENGINEERING MATERIALS (2020)

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Article Materials Science, Ceramics

Enhanced cycle stability of LiCoO2 at high voltage by mixed conductive Li7.5La3Zr1.5Co0.5O12 coating

Xu Cheng et al.

CERAMICS INTERNATIONAL (2020)

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Article Chemistry, Physical

Improving electrochemical performance of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode for Li-ion batteries by dual-conductive coating layer of PPy and LiAlO2

Yu Ma et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

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Article Chemistry, Analytical

Graphene quantum dots coated LiCoO2 for improved cycling stability an thermal safety at high voltage

Yiping Sun et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Physical

Bifunctional composite separator with a solid-state-battery strategy for dendrite-free lithium metal batteries

Hanyu Huo et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Multi-scale stabilization of high-voltage LiCoO2 enabled by nanoscale solid electrolyte coating

Zeyuan Li et al.

ENERGY STORAGE MATERIALS (2020)

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Article Engineering, Electrical & Electronic

Investigations on electrochemical performance of the full cell fabricated LiCoO2wrapped with MgO and ZnO for advanced lithium ion battery applications

S. Pavithra et al.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2020)

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Article Chemistry, Multidisciplinary

Enabling Stable High-Voltage LiCoO2Operation by Using Synergetic Interfacial Modification Strategy

Xuerui Yang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Enhanced rate performance and cycle stability of LiNi 0.6 Co 0.2 Mn 0.2 O 2 at high cut-off voltage by Li 6.1 La 3 Al 0.3 Zr 2 O 12 surface modification

Zhiyan Cheng et al.

APPLIED SURFACE SCIENCE (2020)

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Article Physics, Atomic, Molecular & Chemical

Improving interfacial electrochemistry of LiNi0.5Mn1.5O4 cathode coated by Mn3O4

Miao-miao Deng et al.

CHINESE JOURNAL OF CHEMICAL PHYSICS (2020)

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Article Energy & Fuels

Ag-Modified LiMn2O4 Cathode for Lithium-Ion Batteries: Coating Functionalization

Somia M. Abbas et al.

ENERGIES (2020)

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Article Chemistry, Physical

Li2TiO3 and Li2ZrO3 co-modification LiNi0.8Co0.1Mn0.1O2 cathode material with improved high-voltage cycling performance for lithium-ion batteries

Jiwen Li et al.

SOLID STATE IONICS (2020)

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Article Chemistry, Physical

An In Situ Formed Surface Coating Layer Enabling LiCoO2with Stable 4.6 V High-Voltage Cycle Performances

Yi Wang et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

Structural and electrochemical properties of LiNiO2cathodes prepared by solid state reaction method

Ravindranadh Koutavarapu et al.

IONICS (2020)

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Article Materials Science, Ceramics

Structural and Electrochemical Studies of La2O3 Coated LiCoO2 Particles

Bhuvanagiri Nageswara Rao et al.

TRANSACTIONS OF THE INDIAN CERAMIC SOCIETY (2020)

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Article Electrochemistry

Rational Design of a Piezoelectric BaTiO3Nanodot Surface-Modified LiNi0.6Co0.2Mn0.2O2Cathode Material for High-Rate Lithium-Ion Batteries

Wenzhi Wang et al.

CHEMELECTROCHEM (2020)

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Article Chemistry, Multidisciplinary

A Cation-Tethered Flowable Polymeric Interface for Enabling Stable Deposition of Metallic Lithium

Zhuojun Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

Atomistic mechanism of cracking degradation at twin boundary of LiCoO2

Yuyuan Jiang et al.

NANO ENERGY (2020)

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Article Chemistry, Physical

In Situ Tuning Residual Lithium Compounds and Constructing TiO2 Coating for Surface Modification of a Nickel-Rich Cathode toward High-Energy Lithium-Ion Batteries

Wenzhi Wang et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

A Surface Se-Substituted LiCo[O2-δSeδ] Cathode with Ultrastable High-Voltage Cycling in Pouch Full-Cells

Zhi Zhu et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Stable surface construction of the Ni-rich LiNi0.8Mn0.1Co0.1O2 cathode material for high performance lithium-ion batteries

Yu Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Improved high-temperature cyclability of AlF3 modified spinel LiNi0.5Mn1.5O4 cathode for lithium-ion batteries

Ching-Teng Chu et al.

APPLIED SURFACE SCIENCE (2020)

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Article Chemistry, Multidisciplinary

A general route of fluoride coating on the cyclability regularity of high-voltage NCM cathodes

Huixian Xie et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Inorganic & Nuclear

Building an artificial solid electrolyte interphase on spinel lithium manganate for high performance aqueous lithium-ion batteries

Wujie Dong et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Multidisciplinary

Unveiling the mechanisms of lithium dendrite suppression by cationic polymer film induced solid-electrolyte interphase modification

Seung-Yong Lee et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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Article Chemistry, Physical

Electro-chemo-mechanical evolution of sulfide solid electrolyte/Li metal interfaces: operando analysis and ALD interlayer effects

Andrew L. Davis et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Phase Transformation Behavior and Stability of LiNiO2 Cathode Material for Li-Ion Batteries Obtained from InSitu Gas Analysis and Operando X-Ray Diffraction

Lea de Biasi et al.

CHEMSUSCHEM (2019)

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Article Engineering, Chemical

Binder-less chemical grafting of SiO2 nanoparticles onto polyethylene separators for lithium-ion batteries

Wonjun Na et al.

JOURNAL OF MEMBRANE SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Collapse of LiNi1-x-yCoxMnyO2 Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries

Wangda Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Materials Science, Multidisciplinary

Improved rate performance of LiNi0.5Mn1.5O4 as cathode of lithium-ion battery by Li0.33La0.56TiO3 coating

Yan-Rong Zhu et al.

MATERIALS LETTERS (2019)

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Article Chemistry, Multidisciplinary

Enhancement of Ultrahigh Rate Chargeability by Interfacial Nanodot BaTiO3 Treatment on LiCoO2 Cathode Thin Film Batteries

Sou Yasuhara et al.

NANO LETTERS (2019)

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Article Multidisciplinary Sciences

Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes

Chuanfa Li et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Physical

New Organic Complex for Lithium Layered Oxide Modification: Ultrathin Coating, High-Voltage, and Safety Performances

Yingqiang Wu et al.

ACS ENERGY LETTERS (2019)

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Article Nanoscience & Nanotechnology

Surface Modification of Ni-Rich LiNi0.8Co0.1Mn0.1O2 Cathode Material by Tungsten Oxide Coating for Improved Electrochemical Performance in Lithium-Ion Batteries

Dina Becker et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

A Yolk-Shell Structured Silicon Anode with Superior Conductivity and High Tap Density for Full Lithium-Ion Batteries

Lei Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Materials Science, Ceramics

Surface modification of Li1.3Al0.3Ti1.7(PO4)3 ceramic electrolyte by Al2O3-doped ZnO coating to enable dendrites-free all-solid-state lithium-metal batteries

Hainan Bai et al.

CERAMICS INTERNATIONAL (2019)

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Article Chemistry, Physical

Surface Modification for Suppressing Interfacial Parasitic Reactions of a Nickel-Rich Lithium-Ion Cathode

Han Gao et al.

CHEMISTRY OF MATERIALS (2019)

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Article Electrochemistry

Enhanced High-Rate and Low-Temperature Electrochemical Properties of LiFePO4/Polypyrrole Cathode Materials for Lithium-ion Batteries

Yuan Gao et al.

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE (2019)

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Article Materials Science, Multidisciplinary

Optimized ALD-derived MgO coating layers enhancing silicon anode performance for lithium ion batteries

Xia Tai et al.

JOURNAL OF MATERIALS RESEARCH (2019)

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Article Chemistry, Multidisciplinary

Modified Chestnut-Like Structure Silicon Carbon Composite as Anode Material for Lithium-Ion Batteries

Jing Luo et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Physical

Dual-component LixTiO2@silica functional coating in one layer for performance enhanced LiNi0.6Co0.2Mn0.2O2 cathode

Shaohua Guo et al.

NANO ENERGY (2019)

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Article Nanoscience & Nanotechnology

Nitrogen Plasma-Treated Core-Bishell Si@SiOx@TiO2-delta: Nanoparticles with Significantly Improved Lithium Storage Performance

Jing Hu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

Surface modification of LiNi0.8Co0.1Mn0.1O2 by WO3 as a cathode material for LIB

Zhanggen Gan et al.

APPLIED SURFACE SCIENCE (2019)

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Article Chemistry, Physical

Stable and ultrafast lithium storage for LiFePO4/C nanocomposites enabled by instantaneously carbonized acetylenic carbon-rich polymer

Yudi Mo et al.

CARBON (2019)

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Fe2O3/C-modified Si nanoparticles as anode material for high-performance lithium-ion batteries

Qingpeng Wang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Electrochemistry

Effects of vanadium oxide coating on the performance of LiFePO4/C cathode for lithium-ion batteries

Yong Tao et al.

JOURNAL OF SOLID STATE ELECTROCHEMISTRY (2019)

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Article Nanoscience & Nanotechnology

In Situ Lithiophilic Layer from H+/Li+ Exchange on Garnet Surface for the Stable Lithium-Solid Electrolyte Interface

Mingli Cai et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Electrochemistry

CePO4 Coated LiNi0.6Co0.2Mn0.2O2 as Cathode Material and its Electrochemical Performance

Ruijia Diao et al.

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE (2019)

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Article Chemistry, Physical

LiFePO4/carbon hybrids with fast Li-ion solid transfer capability obtained by adjusting the superheat temperature

Jinming Zeng et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Chemistry, Physical

Enhanced cycling stability of high voltage LiCoO2 by surface phosphorylation

Run Gu et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

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Article Chemistry, Physical

Improving the performance of sulphur doped LiMn2O4 by carbon coating

Krystian Chudzik et al.

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