A simple dual responsive chemosensor for selective sensing of Cs plus for environmental monitoring and mimicking molecular logic gates

Detection of toxic metals is of vital importance to safeguard both public health and the ecosystem. Herein, we investigate the newly designed and synthesised isoxazole-based azo dye, (E)-cyclopentyl(5-((5-(4-fluorophenyl) isoxazole-3-yl) diazenyl)-2-hydroxyphenyl) methanone (FPAZ), as a dual chromogenic and fluorogenic sensor. FPAZ demonstrates high selectivity, reusability and ultra-sensitivity towards Cs+ ions manifested through naked eye detection in aqueous medium by employing simple and economic optical spectroscopy techniques. The color change from colourless to dark yellow and enhancement of fluorescence intensity reveal about FPAZ-Cs+ complexation by UV-Vis and fluorescence spectroscopy respectively. The complexation is also supported by DFT calculations. The LOD is estimated to be 0.476 mu M, which by far, is the lowest LOD obtained for Cs+ detection. Further, FPAZ is fabricated with various flexible materials (paper, cotton, non-woven fabric) which provide information about on-site Cs+ ion contamination by means of change in relative RGB values using a handy smartphone camera. Besides this, the logic gate as IMPLICATION and INHIBIT is designed employing Cs thorn and Cl- ions as inputs and absorbance maxima as output. Overall, the developed chemosensor is simple, quick, and more promising than previously reported systems, as it does not need any chemical modification, expensive instruments, or expertise.

Automated summary

Detection of toxic metals is vital for protecting public health and the ecosystem. This study investigates a newly designed and synthesized sensor called FPAZ, which demonstrates high selectivity, reusability, and ultra-sensitivity in detecting Cs+ ions. FPAZ can be used for naked-eye detection in aqueous medium using simple and economical spectroscopy techniques. Additionally, FPAZ can be applied to detect Cs+ ion contamination using a smartphone camera. Overall, this chemosensor is simple, quick, and more promising than previously reported systems.