4.6 Article

Numerical evaluations of curcumin organic molecule and an experimental study on hybrid photodetector performance in visible and UV regions

Journal

ORGANIC ELECTRONICS
Volume 124, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.orgel.2023.106946

Keywords

Global Reactivity; NLO; Absorption; HUMO-LUMO; Hybrid photodetector; Curcumin and Heterojunction

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In this study, efficient self-powered visible and UV photodetectors based on hybrid organic-inorganic materials were demonstrated. The photodetectors showed excellent UV detecting capability and good photoresponsivity.
In this work, we demonstrate efficient self-powered visible and UV photodetectors with hybrid organic-inorganic materials based on organic curcumin pigment (CU), having C21H20O6 as a molecular formula, and inorganic silicon semiconductor in CU/n-Si architecture. The optical absorption spectrum of the CU film is investigated by UV-Visible absorption features with a broad emission band. The self-powered behavior of the CU/n-Si photo-detector has been attributed to the built-in electric field formed between the CU and n-Si heterojunction inter-face. The optical performance of the hybrid photodetector, both under different light intensities of visible light and under 365 and 395 nm UV light, is investigated in detail by current-voltage measurements. CU/n-Si heterojunction photodetector exhibits excellent UV detecting capability and good photoresponsivity. The photo-response of the CU/n-Si device is slightly higher under 395 nm UV light than 365 nm one. The R and D* values obtained at 395 nm are 13.19 AW-1(at-2 V) and 1.22 x 1011 Jones (zero bias), respectively. Furthermore, under 365 and 395 nm light, the ON/OFF values are obtained as about 105. According to the simulated result, the curcumin molecule has great physical properties such as antibacterial activity and nonlinear optical response which makes it a potential candidate for biomedical and optoelectronic applications.

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