4.6 Article

Modulating Zn(OH)2 Rods by Marine Alginate for Templates of Hybrid Tubes with Catalytic and Antimicrobial Properties

Journal

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 5, Issue 1, Pages 862-868

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.6b02192

Keywords

Zn(OH)(2) nanorods; Alginate; Polydopamine coating Ag nanoparticles; Catalyst; Antibiosis

Funding

  1. Chinese 1000 youth Talent Program
  2. National Natural Science Foundation of China [21474125]
  3. National Key Technology R&D Program of the Ministry of Science and Technology [2015BADI4B06]
  4. Shandong Collaborative Innovation Center for marine biomass fiber materials and textiles

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With the help of marine alginate, Zn(OH)(2) nanorods were synthesized under mild conditions (e.g., room temperature and atmospheric pressure) through a one-step, green, and scalable method, in which both the morphologies (e.g., nanorods and nanoflakes) and nanoscale sizes of Zn(OH)(2) could be precisely controlled by alginate. Considering the high reactive activity as well as the adhesion property of dopamine, polydopamine nanotubes were produced by the template of Zn(OH)(2) rods and following a mussel-biomimetic strategy of dopamine coating. The enhanced activities of polydopamine surfaces further offered the possibility of embedding Ag nanoparticles to produce Ag nanotubes with super-catalytic and-antibacterial properties. The combination of inexpensive starting materials, simple synthesis procedure, and exceptional properties gives Zn(OH)(2) rods/nanoflakes great potential as templates and for multiple applications in catalysis, sensing, etc.

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