Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 4, Issue 9, Pages 4997-5004Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.6b01369
Keywords
Lignin; Antioxidant; Toughness; Polypropylene; Freeze-drying; Sheet-like
Categories
Funding
- Science and Engineering Research Council of the Agency for Science, Technology and Research (A*Star)
- Ministry of National Development, Singapore [132 176 0011]
- Nanyang Technological University, Singapore
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Lignin is an attractive renewable reinforcing agent for polyolefins and also a promising low-cost antioxidant for polymers. It, however, exhibits poor compatibility with nonpolar polymers. In this work, alkali lignin was freeze-dried to achieve sheet-like morphology and then incorporated into polypropylene (PP) by melt compounding. Owing to the significantly increased interfacial area and improved dispersion, with the addition of only 2 wt % freeze-dried lignin, the PP/lignin composites show much enhanced tensile mechanical properties, including a moderately improved Young's modulus and almost doubled elongation at break compared with those of neat PP. The enhancements brought by the sheet-like lignin are far more impressive than those achieved with the same amount of as-received lignin. The composites with the freeze-dried lignin also have rough fractured surfaces with fiber pull-out near the interface, revealing a significant toughening effect of the lignin, which can be attributed to the crazing near the interface, and enhanced relaxation in PP-lignin interphase as evidenced by the reduced T-g. Furthermore, the large interfacial area also drastically improves the antioxidant effect of lignin, greatly slowing the UV-induced and thermo-oxidative degradation of PP. After 2 weeks of intense UV exposure, neat PP becomes very brittle with its yield strain reduced to about 37% of its original value, whereas the yield strain of the composite with 2 wt % sheet-like lignin is almost unchanged, demonstrating the excellent free-radical scavenger effect of the lignin.
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