Journal
JOURNAL OF ENERGY STORAGE
Volume 74, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.est.2023.109393
Keywords
Li-ion batteries; Anode materials; Layered structure; Germanium selenide; Thermally-reduced graphene oxide
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Layered GeSe/thermally-reduced graphene oxide (TRG) composites show improved electrochemical performance and cycling stability in Li-ion batteries, due to the role of the TRG matrix.
Due to their layered structure and greater electrical conductivity compared to traditional metal oxides, layered metal selenides have been extensively explored as promising electrode materials for Li-ion batteries. The greatest obstacles to their continued growth, however, are the substantial volume change and particle agglomeration during cycling. In this work, layered GeSe/ thermally-reduced graphene oxide (TRG) composites were successfully synthesized by using a facile shear-force exfoliation approach. When a highly conductive TRG matrix was incorporated with GeSe particles, the resultant GeSe/TRG composite electrode achieved an impressive reversible capacity (>840.1 mAh g(-1) at 0.1C), improved rate capability as well as excellent cycling stability. The remarkable improvement in electrochemical performance of the GeSe/TRG composite electrode corresponds to the TRG matrix, which potentially constructs an efficient conductive channel and serves as a flexible mechanical buffer for the restriction of volume expansion and particle aggregation.
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