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Chemical Chartographisis: a contemporary perspective in molecular design and synthesis

Journal

DALTON TRANSACTIONS
Volume 52, Issue 48, Pages 18118-18132

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3dt02459h

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This article introduces a contemporary approach in molecular design and synthesis, called Chemical Chartographisis, which enhances the potential of flexible molecular systems by taking a holistic view of the reaction processes. The article discusses three projects in detail, involving catalytic and biologically related examples.
The use of flexible molecular systems in solution, without strictly controlling their behaviour, has frequently been productive. Their potential could increase by a more holistic view of the reaction(s) process(es) in which they are involved. In this perspective, we introduce a broader approach - Chemical Chartographisis - and discuss three projects in detail to illustrate its potential. The topics involve bimetallic 3d/4f species and coordination compounds built from benzotriazole-based and (a)symmetric salan ligands and focus on catalytic and, in less detail, biological-related examples. We introduce a contemporary perspective in molecular design and synthesis, named Chemical Chartographisis.

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