4.3 Review

Achieving High Energy Efficiency: Recent Advances in Zn-Air-Based Hybrid Battery Systems

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Engineering Self-Supported Hydrophobic-Aerophilic Air Cathode with CoS/Fe3S4 Nanoparticles Embedded in S, N Co-Doped Carbon Plate Arrays for Long-Life Rechargeable Zn-Air Batteries

Lei Yan et al.

Summary: A hydrophobic-aerophilic strategy is developed to engineer the reaction kinetics at air cathodes by fabricating a self-supported air cathode based on CoS/Fe3S4 nanoparticles encapsulated in S, N co-doped carbon plate arrays (CoS/Fe3S4@SNCP). The in situ growth of bimetallic sulfides nanoparticles on the carbon plate arrays improves the intrinsic electrocatalytic activity and electron conduction of the air cathode. The hydrophobic-aerophilic surface repels water molecules and creates abundant solid-liquid-gas three-phase reaction interfaces, promoting the diffusion of reactive molecules/ions and oxygen adsorption.

ADVANCED ENERGY MATERIALS (2023)

Article Chemistry, Physical

2D Metal-organic framework derived Co/CoSe2 heterojunctions with interfacial electron redistribution as bifunctional electrocatalysts for urea-assisted rechargeable Zn-air batteries

Huanhuan Li et al.

Summary: A superb bifunctional electrocatalyst Co/CoSe2@CNx was synthesized, which consists of Co/CoSe2 nanoparticles encapsulated in a nitrogen-doped porous graphitized carbon structure. The interface engineering strategy effectively tunes charge redistribution and the porous graphitized carbon shells provide an optimized environment for charge and mass transport. The Co/CoSe2@CNx catalyst exhibits a narrow potential gap between the UOR potential and the half-wave potential for ORR, and it enables long-term rechargeability of urea-assisted ZABs with improved energy conversion efficiency.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Multidisciplinary

Enhancing Energy Conversion Efficiency and Durability of Alkaline Nickel-Zinc Batteries with Air-Breathing Cathode

Weili Xie et al.

Summary: In this study, an air breathing cathode was constructed by coupling electrocatalysts for the oxygen reduction reaction in the cathode of nickel-zinc batteries, which improved the performance of Ni-Zn batteries. The novel battery (Ni-ZnAB) exhibited outstanding energy efficiency and long cycle life under lean electrolyte conditions, surpassing traditional Ni-Zn batteries. Furthermore, a mold cell with rich electrolyte achieved an ultrahigh stability, demonstrating the strong application potential of Ni-ZnAB.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Article Chemistry, Multidisciplinary

I3-/I- Redox Reaction-mediated Organic Zinc-Air Batteries with Accelerated Kinetics and Long Shelf Lives

Mangwei Cui et al.

Summary: A long-storable Zn-air battery with accelerated kinetics mediated by I-3(-)/I- redox is reported. The use of I-3(-) chemical oxidation accelerates the electrooxidation of Zn-5(OH)(8)Cl-2 center dot H2O in the charge process. In the discharge process, I- adsorption on the electrocatalyst changes the energy level of oxygen reduction reaction (ORR). The prepared ZAB exhibits significantly improved round-trip efficiency and long-term cycling time, making it a promising candidate for industrial applications.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Review Chemistry, Physical

Rechargeable metal-metal alkaline batteries: Recent advances, current issues and future research strategies

Jahidul Islam et al.

Summary: Remarkable advancements have been made in the field of rechargeable metal-metal alkaline batteries (RABs) in terms of safety, energy density, charge-discharge capacity, and long-term storage capability. Metal-metal RABs, such as Ni-Zn, Ni-Fe, Ni-Bi, Ni-MH, Ag-Zn, Co-Zn, Cu-Zn, and Bi-Zn systems, are considered as promising energy storage devices for electric vehicles, hybrid EVs, grid-scale energy storage, and implantable and wearable electronic devices. Ni-MH batteries have become competitive with Li-ion batteries in EVs and hybrid EVs applications due to their high tolerance against mechanical abuse, stability under wide temperature ranges, and considerable charge/discharge capacity.

JOURNAL OF POWER SOURCES (2023)

Article Chemistry, Multidisciplinary

Boosting Urea Electrooxidation Activity of Ni5P4 by Vanadium Doping for Urea-Assisted Renewable Energy Conversion Devices

Qiuhan Cao et al.

Summary: In this study, the UOR activity of Ni5P4 was improved by V incorporation, resulting in the formation of a novel amorphous V-doped Ni5P4 (V10%-Ni5P4) microflower structure. The V10%-Ni5P4 microflowers exhibited higher UOR activity, with more active sites, enhanced mass transfer, conductivity, and better wettability compared to Ni5P4. Additionally, urea-assisted electrolytic cells and rechargeable Zn-Air batteries (uZABs) using V10%-Ni5P4 as the catalyst demonstrated improved performance. This study provides insights into the role of vanadium in crystallization and structure optimization for the development of new UOR electrocatalysts.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

Article Chemistry, Physical

Pt/C as a bifunctional ORR/iodide oxidation reaction (IOR) catalyst for Zn-air batteries with unprecedentedly high energy efficiency of 76.5%

Siyuan Zhao et al.

Summary: Introducing potassium iodide (KI) to Zn-air batteries can change the oxidation pathway and improve the energy efficiency and cycle life. The study shows that a carbon-based catalyst Pt/C with poor OER activity exhibits remarkable IOR activity, leading to a low charging voltage and high energy efficiency in the fabricated batteries.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Article Chemistry, Physical

High-performance aqueous rechargeable Zn-Ag and Zn-Ag/air hybrid batteries based on Ag nanobelts as highly stable bifunctional electrode

Lufa Yang et al.

Summary: By optimizing and tuning the surface electronic structure of silver nanomaterials, the conductivity and electrochemical performance of silver electrode materials can be improved. The Zn-Ag battery and Zn-Ag/air battery prepared using silver nanobelts exhibit favorable electrochemical performance and energy-saving features.

APPLIED SURFACE SCIENCE (2023)

Review Nanoscience & Nanotechnology

Organo-Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

Hongfei Wang et al.

Summary: With the increasing demand for portable electronics, flexible aqueous energy storage devices have gained significant interest. Organo-hydrogels, crosslinked amphiphilic polymers filled with organic solvents and water, are considered as ideal electrolyte candidates due to their environmental adaptation. This review discusses the composition, preparation methods, and properties of organo-hydrogel electrolytes, highlighting their application in supercapacitors and Zn-based batteries under harsh conditions. The current challenges and future development directions of organo-hydrogel electrolytes for flexible energy storage are also discussed.

SMALL SCIENCE (2023)

Article Electrochemistry

Hybrid working mechanism enables highly reversible Zn electrodes

Libei Yuan et al.

Summary: In this study, a boron nitride (BN)/Nafion layer is reported on the surface of zinc, which efficiently addresses the issues of zinc dendrite growth and water-related side reactions by combining the working mechanisms of solid/electrolyte interphase (SEI) and nucleation layers. The protective layer provides a dendrite-free and side-reaction-free zinc electrode with a preferred deposition orientation. The zinc electrode with the protective layer exhibits high reversibility and excellent performance in full cells.

ESCIENCE (2023)

Article Chemistry, Physical

Enhanced oxygen reduction reaction for Zn-air battery at defective carbon fibers derived from seaweed polysaccharide

Xiaoliang Zhao et al.

Summary: Carbon fibers with intrinsic defects (D-CFs) synthesized from seaweed polysaccharide show excellent ORR catalytic activity, making them a promising alternative to Pt/C catalyst for large-scale application in zinc-air batteries.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Environmental

S, N co-doped carbon nanotubes coupled with CoFe nanoparticles as an efficient bifunctional ORR/OER electrocatalyst for rechargeable Zn-air batteries

Guijun Li et al.

Summary: The study successfully synthesized a high-performance bifunctional electrocatalyst CoFe/S-N-C, which exhibited excellent performance in both ORR and OER. The fabricated zinc-air battery showed good performance and stability, indicating the durability of the CoFe/S-N-C catalyst.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

All-in-one and bipolar-membrane-free acid-alkaline hydrogel electrolytes for flexible high-voltage Zn-air batteries

Siyuan Zhao et al.

Summary: A novel strategy using Pluronic (R) F127 hydrogels has been proposed to design all-in-one and membrane-free acid-alkaline flexible electrolytes for high-voltage ZABs. By implementing this strategy, a ZAB with an unprecedentedly high voltage of 2V has been achieved, surpassing all existing flexible ZABs.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Energy & Fuels

Free-Standing Electrode of Core-Shell-Structured NiO@Co3S4 for High-Performance Hybrid Zn-Co/Air Batteries

Wenxu Shang et al.

Summary: In this work, a free-standing NiO@Co3S4 electrode with a core-shell structure is successfully fabricated and used in a hybrid Zn battery for the first time. This electrode exhibits improved performance in both pseudocapacitance and oxygen electrocatalysis compared to the pristine Co3S4 electrode. The hybrid Zn-Co/air battery with this electrode delivers high discharge and charge voltage plateaus, and has a long cycling life.

ENERGY & FUELS (2022)

Article Chemistry, Multidisciplinary

Self-Activated Formation of Hierarchical Co3O4 Nanoflakes with High Valence-State Conversion Capability for Ultrahigh-Capacity Zn-Co Batteries

Wenxu Shang et al.

Summary: Cobalt-based materials are of interest for alkaline Zn batteries due to their high theoretical capacity, but face challenges in cyclic stability and capacity retention. By designing hierarchical Co3O4 nanoflakes with high valence-state conversion capability, the electrode demonstrated improved capacity and energy density, enhancing battery performance and durability.

SMALL (2022)

Article Chemistry, Multidisciplinary

Chemical Passivation Stabilizes Zn Anode

Pan He et al.

Summary: This study proposes a simple and rapid surface passivation strategy to significantly improve the cycling stability and corrosion resistance of aqueous zinc ion batteries.

ADVANCED MATERIALS (2022)

Article Chemistry, Physical

Triple-phase oxygen electrocatalysis of hollow spherical structures for rechargeable Zn-Air batteries

Chen-Chen Weng et al.

Summary: The study focuses on the regulation of the reaction interface microenvironment by structural engineering of a hollow spherical bimetallic electrocatalyst. The well-constructed triple-phase contact points enhance the catalytic efficiency and introduce sulfur dopant to improve catalytic activity. The CoFe-SNC with such a designed microenvironment shows outstanding performance in oxygen reduction reaction and rechargeable Zn-air batteries.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Environmental

Heterostructured hollow fibers stitched together from nickel sulfides capped S, N-codoped carbon nanotubes as a trifunctional electrode for flexible hybrid Zn batteries

Mingxue Xie et al.

Summary: A hollow fiber electrode composed of S, N-doped carbon nanotubes confined nickel sulfide nanoparticles was designed for hybrid Zn batteries, exhibiting high electrocatalytic performance. The electrode provides fast electron/ion pathways, abundant active sites, and superior OER/ORR catalytic activities, promoting the development of high-performance power sources for electronics.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Rechargeable alkaline Zn-Cu batteries enabled by carbon coated Cu/Bi particles

David J. Arnot et al.

Summary: This work demonstrates the utilization of Cu as the cathode active material in alkaline Zn batteries through the formation of nanoscale carbon-coated Cu/Bi particles. The carbon coating provides consistent cycling performance and prevents the formation of detrimental Cu2O structures. Various characterization techniques were used to analyze the properties of the resulting particles. This study provides further insight into methods for realizing a Cu-based cathode for rechargeable alkaline Zn batteries.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Applied

Boron modulating electronic structure of FeN4C to initiate high-efficiency oxygen reduction reaction and high-performance zinc-air battery

Xue Zhao et al.

Summary: This study successfully developed a low-cost and efficient catalyst FeN4CB for efficient electrochemical oxygen reduction reaction (ORR), with comparable activity to commercial Pt/C and high stability in both acidic and alkaline media. FeN4CB as an air cathode in zinc-air batteries showed high voltage and power density, maintaining stability after long-term charge-discharge tests.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Applied

Co3O4/Mn3O4 hybrid catalysts with heterointerfaces as bifunctional catalysts for Zn-air batteries

Qikai Huang et al.

Summary: A Co3O4/Mn3O4 nanohybrid with heterointerfaces is designed as an advanced cathode catalyst for Zinc-air batteries (ZABs), which shows high activity and durability in oxygen reduction reaction and oxygen evolution reaction. The improved catalytic activity is attributed to the heterointerfaces between Co3O4 and Mn3O4 as well as the improved conductivity and contact area of the three-phase interface. The home-made ZAB based on Co3O4/Mn3O4/rGO exhibits high open circuit voltage, large power density, and good long-term cycling stability, making it a promising bifunctional oxygen catalyst for rechargeable ZABs.

JOURNAL OF ENERGY CHEMISTRY (2022)

Review Chemistry, Physical

Effects of Porous Structure on Oxygen Mass Transfer in Air Cathodes of Nonaqueous Metal-Air Batteries: A Mini-review

Fangzhou Wang et al.

Summary: Metal-air batteries have gained attention for their high energy density, but their low rate capacity, poor circularity, and instability need to be addressed. This review investigates the effects of surface area, pore volume, and pore size on mass transfer in air cathodes, reviews studies on electrode materials and porous structures, and discusses the relationship between electrocatalysts and porous structures. Advancing materials and designing porous structures with electrocatalysts are important for enhancing mass transfer and promoting metal-air batteries. Personal views on advanced cathode design are proposed.

ACS APPLIED ENERGY MATERIALS (2022)

Review Materials Science, Multidisciplinary

Defective/Doped Graphene-Based Materials as Cathodes for Metal-Air Batteries

Qinming Zhang et al.

Summary: This article summarizes the latest research progress on graphene and its derivatives as catalytic materials in metal-air batteries. The defects and doping of graphene play an important role in improving the electrochemical performance. The relationship between graphene defects/doping and electrocatalytic mechanisms is discussed, and future directions for the development of graphene-based metal-air battery cathodes are prospected.

ENERGY & ENVIRONMENTAL MATERIALS (2022)

Article Chemistry, Physical

Ni single atoms anchored on N-doped carbon nanosheets as bifunctional electrocatalysts for Urea-assisted rechargeable Zn-air batteries

Hao Jiang et al.

Summary: In this study, a bifunctional electrocatalyst composed of individually dispersed Ni single atoms on N-doped carbon nanosheets (Ni SAs-NC) was synthesized and demonstrated to exhibit outstanding performance for both oxygen reduction reaction (ORR) and urea oxidation reaction (UOR). By coupling ORR with UOR of low thermodynamic potential, a urea-assisted rechargeable Zn-air battery (ZAB) with significantly decreased charging voltage and high urea elimination rate was achieved. The high bifunctional electrocatalytic activities of Ni SAs-NC resulted in a dramatically increased energy conversion efficiency of 71.8%, improving conventional ZABs by 17.1%. This successful implementation of Ni SAs-based urea-assisted ZABs with improved energy conversion efficiency may advance practical applications of ZAB technology.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

Achieving high energy efficiency of alkaline hybrid zinc battery by using the optimized Co-Mn spinel cathode

Jiaqun Zou et al.

Summary: Zinc-air batteries (ZABs) face the challenges of insufficient discharge voltages and low charge-discharge efficiencies. A viable strategy to solve these problems is to build alkaline hybrid zinc batteries (AHZBs) by combining ZAB and alkaline zinc/cobalt batteries (ZCB) at the battery level.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Multidisciplinary Sciences

Metal-air batteries: progress and perspective

Yuhui Chen et al.

Summary: Metal-air batteries have received much attention due to their high theoretical energy densities. However, they face scientific challenges such as metal dendrite formation/deformation and kinetics of redox mediators. Addressing these issues is crucial for improving battery performance.

SCIENCE BULLETIN (2022)

Article Chemistry, Physical

Microenvironment Alters the Oxygen Reduction Activity of Metal/N/C Catalysts at the Triple-Phase Boundary

Jia-Qiang Zhong et al.

Summary: This study investigates the effect of microenvironment on the ORR kinetics of Fe/N/C catalysts by comparing the performance at RDE and GDE. The results demonstrate the importance of factors such as accessible active sites and water activity in tuning the ORR activity, and suggest strategies for improving proton transport for future catalyst and ionomer design.

ACS CATALYSIS (2022)

Article Chemistry, Multidisciplinary

Copper Collector Generated Cu+/Cu2+ Redox Pair for Enhanced Efficiency and Lifetime of Zn-Ni/Air Hybrid Battery

Guangying Zhang et al.

Summary: This study introduces the Cu+/Cu2+ redox pair into the hybrid battery system of Zn-air and Zn-Cu/Zn-Ni, improving the efficiency and lifetime by providing a multichannel structure for better electrode-electrolyte contact.

ACS NANO (2022)

Article Chemistry, Multidisciplinary

Dual-Network Structured Hydrogel Electrolytes Engaged Solid-State Rechargeable Zn-Air/Iodide Hybrid Batteries

Qingqing Liu et al.

Summary: A dual-network structured hydrogel electrolyte composed of PAM, SA, and KI has been developed for solid-state zinc-air/iodide hybrid batteries, showing improved mechanical strength, increased ionic conductivity, excellent renewability, and a long cycling life of 110 hours with high energy efficiency of 80%. The introduction of iodine species not only enhances cathodic kinetics but also regulates the solvation structure of zinc ions for better interface stability, providing significant concepts for developing high-performance energy devices and technologies.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Chemistry, Physical

Mechanistic study on electro-oxidation of 5-hydroxymethylfurfural and water molecules via operando surface-enhanced Raman spectroscopy coupled with an Fe3+ probe

Yongfang Zhou et al.

Summary: This study investigated the mechanism of HMF electro-oxidation using operando surface-enhanced Raman spectroscopy (SERS) coupled with an Fe3+ probe. The presence of Fe3+ suppressed the catalytic activity of nickel nanoparticles, but enhanced the activity towards water oxidation. Copper nanoparticles integrated electrodes showed excellent HMF oxidation performance. This study provides a feasible route to explore mechanisms of electrocatalytic processes.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Engineering, Environmental

Integrating trifunctional Co@NC-CNTs@NiFe-LDH electrocatalysts with arrays of porous triangle carbon plates for high-power-density rechargeable Zn-air batteries and self-powered water splitting

Lei Yan et al.

Summary: A structural engineering strategy has been proposed to fabricate trifunctional electrocatalysts for flexible Zn-air batteries and self-powered water splitting. The unique 3D hierarchical structure and strong interfacial coupling between different functional components enable excellent performance and durability, demonstrating great potential for practical renewable energy applications.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Multidisciplinary Sciences

Identification of the active triple-phase boundary of a non-Pt catalyst layer in fuel cells

Yu-Cheng Wang et al.

Summary: Through studying TPBs, we found that micropores play a key role in the action of non-Pt catalysts in fuel cells, while acid-alkaline interactions lead to deactivation of active sites in mesopores and macropores.

SCIENCE ADVANCES (2022)

Article Chemistry, Physical

Sustainable aqueous metal-air batteries: An insight into electrolyte system

Linqian Wang et al.

Summary: To meet the increasing demand for sustainable energy sources, aqueous metal-air batteries have gained significant attention. However, their practical discharge performance falls short of expectations. This work presents an in-depth understanding of the working mechanism of aqueous metal-air batteries and recent advances in electrolyte development. The critical issues faced by conventional aqueous zinc-air, aluminum-air, and magnesium-air batteries are thoroughly discussed, along with potential solutions through electrolyte modification. Future research directions for electrolyte systems in aqueous metal-air batteries are also proposed.

ENERGY STORAGE MATERIALS (2022)

Review Electrochemistry

Engineering Gas-Solid-Liquid Triple-Phase Interfaces for Electrochemical Energy Conversion Reactions

Chen-Chen Weng et al.

Summary: This article provides a systematic summary of the recent progress in energy-related electrocatalysts based on gas-liquid-solid triple-phase interface engineering, including active-site-enriched surface, decent gas wettability, and electrolyte infiltration and favorable electronic conductivity. The corresponding insightful understanding, architecture design/constituent regulation of electrocatalytic materials and admirable electrocatalytic activity are discussed to establish universal theory-structure-function relationships based on triple-phase interface engineering. Practical energy-related applications in water electrolyzers, metal-based batteries, and fuel cells are also revealed.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

Article Energy & Fuels

Innovating Rechargeable Zn-Air Batteries for Low Charging Voltage and High Energy Efficiency

Siyuan Zhao et al.

Summary: In this study, soluble KI was used as a reaction modifier in rechargeable zinc-air batteries (ZABs) to change the oxidation pathway during charging. The addition of KI resulted in lower charging voltage, improved energy efficiency, and longer cycle life. The use of the commercially available XC72R carbon further enhanced the performance of the batteries. This work is significant for advancing the use of rechargeable ZABs in energy storage applications.

ENERGY & FUELS (2022)

Review Materials Science, Multidisciplinary

A review of Ni based powder catalyst for urea oxidation in assisting water splitting reaction

Jiaxin Li et al.

Summary: This article reviews the recent advances in the application of Ni-based powder catalysts for urea oxidation in assisting water splitting. The fundamentals of urea oxidation and evaluation indicators are presented, and the design principles and fabrication approaches of the catalysts are discussed. The advances, problems, and challenges of various Ni-based powder catalysts are summarized. The article emphasizes the importance of understanding the structure-property relationship and developing multi-functional Ni-based powder catalysts for real device applications.

ADVANCED POWDER MATERIALS (2022)

Article Chemistry, Multidisciplinary

In situ electrochemical activation of Co(OH)2@Ni(OH)2 heterostructures for efficient ethanol electrooxidation reforming and innovative zinc-ethanol-air batteries

Zilong Li et al.

Summary: In this study, Co(OH)(2)@Ni(OH)(2) heterostructures were synthesized using a metal-organic framework precursor in a one-pot hydrothermal method. The catalyst exhibited excellent catalytic activity and stability in the ethanol oxidation reaction (EOR), converting ethanol into acetate with a high faradaic efficiency of 97.9%. The high performance was attributed to the double hydroxide heterostructure further processed by electrochemical activation. The active sites for EOR were identified as Ni (NiOOH) through in situ Raman spectra and DFT calculations.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

A zinc-air battery capable of working in anaerobic conditions and fast environmental energy harvesting

Wenxu Shang et al.

Summary: This paper reports a zinc-air battery using CuO as the positive electrode material, which can switch between aerobic and anaerobic modes and breaks the limitations of traditional zinc-air batteries.

CELL REPORTS PHYSICAL SCIENCE (2022)

Article Electrochemistry

Advanced polymer-based electrolytes in zinc-air batteries

Qingqing Liu et al.

Summary: Polymer-based electrolytes play a critical role in zinc-air batteries, improving their performance. This article reviews the recent progress in polymer-based electrolytes for zinc-air batteries and proposes future challenges and viable strategies.

ESCIENCE (2022)

Review Chemistry, Physical

Defect engineering of electrode materials towards superior reaction kinetics for high-performance supercapacitors

Wen Lu et al.

Summary: This paper provides a comprehensive overview of recent progress in defect engineering for superior reaction kinetics of electrode materials in high-performance supercapacitors. It summarizes the types of defects, strategies for engineering defects, and advanced characterization techniques. The specific roles of defects in enhancing electrochemical performances are proposed. The existing challenges and opportunities in defect engineering for electrode materials are discussed, aiming to support the effective utilization of defects in high-performance supercapacitor electrode materials.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Review Chemistry, Multidisciplinary

Material design and surface chemistry for advanced rechargeable zinc-air batteries

Soobeom Lee et al.

Summary: This article reviews the reaction mechanism of zinc-air batteries and the research progress of bifunctional electrocatalysts. It also highlights advanced ZAB systems and discusses the remaining challenges and requirements for future research directions.

CHEMICAL SCIENCE (2022)

Article Chemistry, Physical

Ag/AgCl clusters derived from AgCu alloy nanoparticles as electrocatalysts for the oxygen reduction reaction

Timucin Balkan et al.

Summary: The activity of bimetallic AgCu alloy nanoparticles towards the oxygen reduction reaction can be enhanced by dealloying Cu. The composition and formation of AgCl on Ag surfaces play a significant role in the activity of the catalyst, and Ag+ stabilized in the presence of sub-stoichiometric Cl- contributes to its superior performance.

SUSTAINABLE ENERGY & FUELS (2022)

Review Materials Science, Multidisciplinary

Aqueous Zn-based rechargeable batteries: Recent progress and future perspectives

Mingjie Wu et al.

Summary: Due to their high safety, abundant reserves, low cost, and high energy density, aqueous Zn-based rechargeable batteries (AZBs) have attracted extensive attention. To improve the performance of AZBs, efforts are focused on modifying electrode materials and electrolytes, as well as exploring different redox mechanisms based on various cathode materials and aqueous electrolytes.

INFOMAT (2022)

Article Engineering, Environmental

Engineering the defects of Co3O4-x bubbles in lotus root-like multichannel nanofibers to realize superior performance and high durability for fiber-shaped hybrid Zn battery

Hongmei Wang et al.

Summary: The lotus root-like nanofibers composed of Co3O4-x bubbles with engineered defects serve as a novel cathode for hybrid Zn batteries, providing fast electron/ion transport, highly reversible redox reactions, and abundant active sites for oxygen evolution/reduction reactions. This unique structure enables high energy/power density, superior durability and efficient kinetics, resulting in a fiber-shaped HZB with high energy density, superior high-rate capability, and long-term cycling stability under various conditions.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Nanoscience & Nanotechnology

Interface Engineering of CoS/CoO@N-Doped Graphene Nanocomposite for High-Performance Rechargeable Zn-Air Batteries

Yuhui Tian et al.

Summary: The interface engineering of heterogeneous CoS/CoO nanocrystals and N-doped graphene composite results in enhanced electrocatalytic performances for oxygen reduction reaction and oxygen evolution reaction. Optimizing the composition, interface structure, and conductivity of the electrocatalyst leads to bifunctional catalytic activity with outstanding efficiency and stability for both ORR and OER. The aqueous ZAB with the bifunctional electrocatalyst displays high power density, specific capacity, and cycling stability, making it promising for flexible and wearable electronic devices.

NANO-MICRO LETTERS (2021)

Article Nanoscience & Nanotechnology

Root Reason for the Failure of a Practical Zn-Ni Battery: Shape Changing Caused by Uneven Current Distribution and Zn Dissolution

Yuanhao Shen et al.

Summary: Despite the excellent rate performance and environmental friendliness, poor cycling life of aqueous Zn-Ni batteries is mainly attributed to the shape changing of the Zn anode resulting from uneven current distribution and the dissolution of Zn.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

Recent Progress on Flexible Zn-Air Batteries

Yongguang Zhang et al.

Summary: Flexible zinc-air battery technology is considered as one of the most promising energy storage systems, but its practical application is still at the preliminary stage. This review discusses the basic battery configurations, design principles, challenges, and recent progress in developing each battery component, aiming to present a clear picture of current research directions.

ENERGY STORAGE MATERIALS (2021)

Article Engineering, Environmental

Formation of mesoporous Co/CoS/Metal-N-C@S, N-codoped hairy carbon polyhedrons as an efficient trifunctional electrocatalyst for Zn-air batteries and water splitting

Lei Yan et al.

Summary: This study introduces a hierarchical trifunctional electrocatalyst, Co/CoS/Fe-HSNC, synthesized using a metal-organic framework-induced strategy, which shows superior performance in ORR, OER and HER due to its rationally designed nanostructures. The catalyst exhibits high power density and low charge/discharge voltage gap in a Zn-air battery, offering new insights for constructing multifunctional catalysts for zinc-air batteries and water electrolysis.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Designed preparation of CoS/Co/MoC nanoparticles incorporated in N and S dual-doped porous carbon nanofibers for high-performance Zn-air batteries

Yanrong Ren et al.

Summary: The study successfully designed and synthesized a high-efficiency bifunctional electrocatalyst CoS/Co/MoC-N, S-PCNFs, which exhibited excellent performance in oxygen reduction reaction and oxygen evolution reaction, as well as demonstrated outstanding battery performance and durability in Zn-air batteries.

CHINESE CHEMICAL LETTERS (2021)

Article Engineering, Environmental

Mott-Schottky heterojunction of Co/Co2P with built-in electric fields for bifunctional oxygen electrocatalysis and zinc-air battery

Haoqi Yang et al.

Summary: A high-performance bifunctional electrocatalyst composed of Co/Co2P nanoparticles encapsulated in nitrogen and phosphorus co-doped carbon nanotubes (NPCNTs) has been successfully synthesized via a mechanochemistry-pyrolysis approach. The catalyst exhibits outstanding ORR/OER activities, high power density, and cycling life, making it a promising cathode material for rechargeable ZABs. Theoretical calculations support the enhanced electron transport and improved intermediate adsorption in the electrocatalytic process.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Electrochemistry

A printed paper-based Zn-air/Ag hybrid battery with switchable working modes

Yifei Wang et al.

Summary: The paper-based Zn-air/Ag hybrid battery is an efficient and flexible battery technology with dual-mode operation capability and high energy efficiency.

ELECTROCHIMICA ACTA (2021)

Article Chemistry, Physical

Cobalt (II) oxide nanosheets with rich oxygen vacancies as highly efficient bifunctional catalysts for ultra-stable rechargeable Zn-air flow battery

Mingjie Wu et al.

Summary: The development of highly efficient bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is crucial for rechargeable Zn-air batteries. Cobalt (II) oxide (L-CoO) nanosheets with hierarchical nanostructures were grown on stainless steel (SS) substrate via a simple heat treatment, showing superior ORR/OER activity and stability in the rechargeable Zn-air flow battery for over 1000 hours. X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) were used to uncover the reasons behind the excellent bifunctional catalytic performance of this catalyst, with operando XAS revealing the atomic-scale structures as support for the stability of L-CoO during electrocatalytic operation.

NANO ENERGY (2021)

Article Energy & Fuels

High performance secondary zinc-air/silver hybrid battery

Aroa R. Mainar et al.

Summary: Electrically rechargeable zinc-air batteries have low cost, high security and energy density, but low power density, which requires improvement for commercial potential. The development of a new technology, ZASH battery, integrates the advantages of zinc-air and silver-zinc technologies, showing potential for practical applications in the market. Further research on material development beyond conventional approaches could lead to progress in technology for future market applications.

JOURNAL OF ENERGY STORAGE (2021)

Article Chemistry, Physical

Electrochemically induced NiCoSe2@NiOOH/CoOOH heterostructures as multifunctional cathode materials for flexible hybrid zn batteries

Mangwei Cui et al.

Summary: Hybrid Zn batteries utilizing multifunctional electrode materials derived from NiCoSe2 nanosheets show high energy density, superior cycling life, and great environmental adaptability. The in-situ electrochemical phase transformation process ensures the maintenance of the conductive NCS scaffold's porous nanosheet structure and formation of plenty electroactive sites, beneficial for both faradaic reactions and oxygen reduction/evolution reactions.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Understanding the ORR Electrocatalysis on Co-Mn Oxides

Wang Wang et al.

Summary: This study investigates the nature of the active sites in a CoMn2O4 catalyst, revealing the superior activity of Co-Mn spinel oxides is related to the Mn2+/Mn3+ redox transition, which is significantly affected by the operating potential window. This irreversible activity decay is proposed to be caused by the irreversible change of the Jahn-Teller distortion during the Mn2+/Mn3+ transition.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Review Chemistry, Physical

Utilizing Oxygen Redox in Layered Cathode Materials from Multiscale Perspective

Gi-Hyeok Lee et al.

Summary: This review summarizes recent advances in investigating oxygen redox reactions in cathode materials, discussing mechanistic aspects, consequences on electrode degradation pathways, and recent developments for improving reversibility or mitigating harmful processes arising from oxygen oxidation.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

In situ coupling of NiFe nanoparticles with N-doped carbon nanofibers for Zn-air batteries driven water splitting

Chenglong Lai et al.

Summary: A flexible 3D free-standing bifunctional electrode, NiFe/NCNF/CC, was successfully constructed by in-situ coupling of NiFe nanoparticles and N-doped carbon nanofibers on carbon cloth. This electrode exhibits efficient and stable ORR and OER performance, and showed high power density and excellent charge/discharge stability in Zinc-air battery assembly. Additionally, two liquid Zinc-air batteries were used for stable power supply in a self-assembled water-splitting device.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Physical

Recent advances in rechargeable Zn-based batteries

Xinxin Zhang et al.

Summary: Considering the increasing global demand for sustainable energy storage, finding advanced environmentally-friendly energy storage systems with low cost and excellent performance is essential. Rechargeable Zn-based batteries (RZBs) have attracted attention due to their safety, reversibility, high theoretical capacity, and potential applications in various electrical systems. This review outlines differences and connections between Zn-ion batteries (ZIBs) and Zn-air batteries (ZABs), summarizing reaction mechanisms, performance, and composition, while also addressing challenges and suggesting solutions for improving battery stability and efficiency.

JOURNAL OF POWER SOURCES (2021)

Review Chemistry, Physical

Rechargeable aqueous Zn-based energy storage devices

Yiyang Liu et al.

Summary: This work reviews the development and advantages of various types of aqueous Zn-based EES devices since 1799, discussing the electrochemical charge storage mechanisms, key components, challenges, and future directions of AZDs.

JOULE (2021)

Article Chemistry, Physical

Reaction modifier system enable double-network hydrogel electrolyte for flexible zinc-air batteries with tolerance to extreme cold conditions

Yanan Zhang et al.

Summary: This study explores the use of zinc-air batteries for powering wearable electronic devices, and improves the anti-dehydration and anti-freezing properties of hydrogel electrolytes, enabling them to operate in extreme cold temperatures and provide power for electronic devices.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Iron-doped nanoflakes of layered double hydroxide of nickel for high-performance hybrid zinc batteries

Sadegh Askari et al.

Summary: The hybrid Zn-air and Zn-M battery with Fe-doped Ni double hydroxide nanoflakes and activated carbon cathode material shows superior performance, high energy density, exceptional energy conversion efficiency, and outstanding power density. It also enables high-rate charging due to rapid redox reaction kinetics and excellent cathode materials catalytic activity.

MATERIALS TODAY ENERGY (2021)

Article Chemistry, Physical

Formation of sandwiched leaf-like CNTs-Co/ZnCo2O4@NC-CNTs nanohybrids for high-power-density rechargeable Zn-air batteries

Lei Yan et al.

Summary: The study introduces a bifunctional oxygen electrocatalyst, Co/ZnCo2O4@NC-CNTs, with high efficiency in oxygen reduction and evolution reactions for Zn-air batteries. This catalyst shows excellent performance in Zn-air batteries, providing a small potential gap, high power density, and long cycle life. Additionally, it can be used in flexible solid-state Zn-air batteries and exhibits competitive performance.

NANO ENERGY (2021)

Article Engineering, Environmental

Metal-semiconductor oxide (WO3@W) induces an efficient electro-photo synergistic catalysis for MOR and ORR

Zhongshui Li et al.

Summary: The study focuses on utilizing the metal-semiconductor contact mode to construct efficient electro-photo catalysts under irradiation. The findings demonstrate that oxide-derived metal nanostructures can significantly enhance the bifunctional electrocatalytic activity, providing a new approach for the application of direct methanol fuel cells.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Multidisciplinary

Ultrathin Co(OH)2 Nanosheets@Nitrogen-Doped Carbon Nanoflake Arrays as Efficient Air Cathodes for Rechargeable Zn-Air Batteries

Yijie Wang et al.

Summary: The study reports an efficient bifunctional oxygen electrocatalyst Co(OH)(2)@NC, showing excellent bifunctional activity, and exhibiting outstanding performance in rechargeable Zn-air batteries.

SMALL (2021)

Article Multidisciplinary Sciences

Construction of Pd-Zn dual sites to enhance the performance for ethanol electro-oxidation reaction

Yajun Qiu et al.

Summary: The construction of Pd-Zn dual sites significantly improves the efficiency of ethanol electro-oxidation, exceeding commercial Pd/C by approximately 24 times. Further computational studies reveal that Pd-Zn dual sites promote the adsorption of ethanol and hydroxide ion, optimizing the electro-oxidation pathway.

NATURE COMMUNICATIONS (2021)

Article Multidisciplinary Sciences

Modifying redox properties and local bonding of Co3O4 by CeO2 enhances oxygen evolution catalysis in acid

Jinzhen Huang et al.

Summary: Developing efficient and stable earth-abundant electrocatalysts for acidic oxygen evolution reaction is challenging. Here, the authors modify the local bonding environment of Co3O4 by CeO2 nanocrystallites to regulate the redox properties, thus enhance the catalytic activity.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Optimizing the Spin States of Mesoporous Co3O4 Nanorods through Vanadium Doping for Long-Lasting and Flexible Rechargeable Zn-Air Batteries

Yuan Rao et al.

Summary: The vanadium-doped Co3O4 (V-Co3O4) electrocatalyst shows enhanced oxygen electrocatalysis efficiency by optimizing the spin states, demonstrating superior bifunctional properties. Zinc-air batteries fabricated with V-Co3O4 electrocatalysts offer a promising power source for next-generation electronics.

ACS CATALYSIS (2021)

Article Chemistry, Applied

Self-standing 3D nanoporous Ag2Al with abundant surface oxygen species facilitating oxygen electroreduction for efficient hybrid Zn battery

Ming Peng et al.

Summary: A scalable strategy to fabricate nanoporous Ag2Al intermetallic compound as a self-standing cathode for the hybrid Zn battery is reported in this study, showing efficient catalytic oxygen reduction activity and regulated redox activity. The assembled hybrid Zn-Ag2Al/air battery delivers a high capacity, demonstrating its potential value in practical applications.

JOURNAL OF ENERGY CHEMISTRY (2021)

Review Chemistry, Physical

Zn-ion hybrid supercapacitors: Achievements, challenges and future perspectives

Haiyan Wang et al.

Summary: The newly-emerging Zn-ion hybrid supercapacitors (ZHSCs) integrate the high-capacity of Zn-ion batteries and high-power of supercapacitors (SCs), facing challenges in achieving satisfactory energy density and developing suitable cathode materials and electrolytes. This review comprehensively discusses the fundamentals of ZHSCs, advanced engineering of nanostructured cathode materials, electrochemical characteristics, and energy storage mechanisms, as well as the recent development of electrolytes and Zn anode.

NANO ENERGY (2021)

Article Chemistry, Multidisciplinary

Surface Phosphorus-Induced CoO Coupling to Monolithic Carbon for Efficient Air Electrode of Quasi-Solid-State Zn-Air Batteries

Huan Liu et al.

Summary: The study introduces a surface phosphorization-monolithic strategy to embed CoO nanoparticles into paulownia carbon plate as monolithic electrodes for Zn-air batteries. The resulting electrode shows remarkable catalytic activity and long-term cycling stability in quasi-solid-state or aqueous ZABs.

ADVANCED SCIENCE (2021)

Article Chemistry, Physical

Unlocking the Potential of Oxygen-Deficient Copper-Doped Co3O4 Nanocrystals Confined in Carbon as an Advanced Electrode for Flexible Solid-State Supercapacitors

Shude Liu et al.

Summary: Incorporating Cu dopants and O vacancies into Co3O4 nanocrystals confined in a carbon matrix, termed as O-v-Cu-Co3O4@C, helps improve the specific capacity and rate performance of the material. The heterostructured architecture with multifunctional nanogeometries enables high intercomponent synergy, leading to enhanced electrical conductivity and enriched redox chemistry, ultimately resulting in a significantly improved energy density of 64.1 W h kg(-1) at 800 W kg(-1) for asymmetric supercapacitors.

ACS ENERGY LETTERS (2021)

Article Electrochemistry

High-performance Zn battery with transition metal ions co-regulated electrolytic MnO2

Mingyan Chuai et al.

Summary: Electrolytic MnO2/Zn batteries co-regulated with transition metal ions show improved electrochemical performance in terms of deposition and stripping chemistries, with the incorporation of Co and Ni leading to more active electron states, faster charge-transfer kinetics, and better electrical conductivity. This approach offers a versatile strategy for enhancing the performance of aqueous electrolytic MnO2/Zn batteries in large-scale energy storage applications.

ESCIENCE (2021)

Article Electrochemistry

Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production

Tongzhou Wang et al.

Summary: An effective approach is introduced in this study to replace the anodic oxygen evolution reaction with a urea oxidation reaction, significantly decreasing the cell voltage for hydrogen production. The Ni2P/NiMoP catalyst shows impressive activity for both hydrogen evolution and oxygen evolution during hydrogen production. The introduction of urea results in a significant reduction in oxidation voltage, and the two-electrode electrolyzer with Ni2P/NiMoP catalyst exhibits excellent long-term durability.

ESCIENCE (2021)

Article Chemistry, Multidisciplinary

In situ coupling of Ag nanoparticles with high-entropy oxides as highly stable bifunctional catalysts for wearable Zn-Ag/Zn-air hybrid batteries

Yanyi Zhang et al.

Summary: A scalable chemical dealloying procedure was introduced to synthesize stable bifunctional catalysts for hybrid Zn-Ag/Zn-air batteries, consisting of Ag nanoparticles for ORR and multicomponent HEOs for OER. By precisely controlling the content of Ag nanoparticles, both ORR performance and Zn-Ag battery capacity can be optimized, achieving high energy density. Stabilized noble metals in HEO nanocomposites show potential as multifunctional electrocatalysts in various energy conversion devices.

NANOSCALE (2021)

Review Nanoscience & Nanotechnology

Recent Advances in Electrode Design for Rechargeable Zinc-Air Batteries

Jinfa Chang et al.

Summary: This paper introduces the fundamental principles of rechargeable zinc-air batteries (ZABs) and focuses on the electrochemical aspects of the metal anode and air cathode. It also identifies the main problems hindering the large-scale application of ZABs and offers brief perspectives on their further development.

SMALL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Rechargeable zinc-air batteries with neutral electrolytes: Recent advances, challenges, and prospects

Cheng Wang et al.

Summary: This review summarizes the latest research progress of neutral electrolytes used in R-ZABs and efforts in improving the stability of Zn anodes in neutral electrolytes. Comparison of oxygen reduction and evolution reactions in alkaline and neutral electrolytes, potential oxygen electrocatalysts applicable in neutral conditions, and perspectives on future research directions of R-ZABs with neutral electrolytes are provided.

ENERGYCHEM (2021)

Review Nanoscience & Nanotechnology

Recent Advances on Electrospun Nanomaterials for Zinc-Air Batteries

Chenfeng Xia et al.

Summary: Zinc-air batteries are gaining attention in energy storage and conversion technologies, with electrospun materials showing promise in high-performance applications. This review explores the recent progress of electrospun technologies in zinc-air batteries, discussing their fundamental principles and application potential. Challenges and opportunities for electrospun nanomaterials in zinc-air batteries are also highlighted, aiming to inspire further innovation in energy conversion and storage technologies.

SMALL SCIENCE (2021)

Review Nanoscience & Nanotechnology

Metal Chalcogenides with Heterostructures for High-Performance Rechargeable Batteries

Yu Li et al.

Summary: Heterostructures have shown significant potential for improving the electrochemical performance of batteries, with metal chalcogenides being a promising material species due to their high theoretical capacity. The concept of constructing heterostructures for electrode materials is considered a promising design approach for next-generation rechargeable batteries.

SMALL SCIENCE (2021)

Article Chemistry, Physical

Precise regulation of pyrrole-type single-atom Mn-N4 sites for superior pH-universal oxygen reduction

Lei Yan et al.

Summary: The study designed and fabricated ultrathin carbon nanosheet-supported Mn single-atom catalysts with a precise configuration, displaying outstanding ORR activity and high stability.

CARBON ENERGY (2021)

Review Nanoscience & Nanotechnology

High-Voltage Rechargeable Aqueous Zinc-Based Batteries: Latest Progress and Future Perspectives

Yanxia Yu et al.

Summary: Rechargeable aqueous zinc-based batteries are considered desirable energy storage devices for their high theoretical capacity, low cost, and safety, but their energy density needs improvement due to limitations in the narrow electrochemically stable window of aqueous electrolytes. Efforts are being made to increase output voltage to enhance energy density.

SMALL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Single-atom alloy catalysts: structural analysis, electronic properties and catalytic activities

Tianjun Zhang et al.

Summary: This review discusses the development and application of single-atom alloy catalysts, highlighting structural analysis at the atomic scale using microscopy and spectroscopy tools, electronic properties research through X-ray spectroscopy techniques and quantum calculations, and catalytic activity in representative reactions. It also proposes future perspectives for single-atom alloy catalysts from structural, electronic, and reactivity aspects.

CHEMICAL SOCIETY REVIEWS (2021)

Review Chemistry, Multidisciplinary

Toward Critical Electrode/Electrolyte Interfaces in Rechargeable Batteries

Chong Yan et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Review Engineering, Environmental

Two-dimensional Spinel Structured Co-based Materials for High Performance Supercapacitors: A Critical Review

Xun Zhao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Electrochemistry

Microstructure-tuned cobalt oxide electrodes for high-performance Zn-Co batteries

Wenxu Shang et al.

ELECTROCHIMICA ACTA (2020)

Article Chemistry, Applied

Hybrid battery integrated by Zn-air and Zn-Co 3 O 4 batteries at cell level

Ning Liu et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

Review Chemistry, Physical

The Current State of Aqueous Zn-Based Rechargeable Batteries

Ya-Ping Deng et al.

ACS ENERGY LETTERS (2020)

Article Chemistry, Multidisciplinary

Phase Engineering of Iron-Cobalt Sulfides for Zn-Air and Na-Ion Batteries

Shu Lu et al.

ACS NANO (2020)

Article Chemistry, Multidisciplinary

Operando Identification of the Dynamic Behavior of Oxygen Vacancy-Rich Co3O4 for Oxygen Evolution Reaction

Zhaohui Xiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Ru Single Atoms on N-Doped Carbon by Spatial Confinement and Ionic Substitution Strategies for High-Performance Li-O2 Batteries

Xiaolin Hu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Physical

Recent progress in aqueous based flexible energy storage devices

Woo-Jin Song et al.

ENERGY STORAGE MATERIALS (2020)

Article Chemistry, Physical

Rechargeable alkaline zinc batteries: Progress and challenges

Wenxu Shang et al.

ENERGY STORAGE MATERIALS (2020)

Article Chemistry, Physical

A Function-Separated Design of Electrode for Realizing High-Performance Hybrid Zinc Battery

Yijun Zhong et al.

ADVANCED ENERGY MATERIALS (2020)

Article Electrochemistry

Status and Targets for Polymer-Based Solid-State Batteries for Electric Vehicle Applications

Hong-Keun Kim et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

Review Engineering, Environmental

Two-dimensional electrocatalysts for alcohol oxidation: A critical review

Xun Zhao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Review Chemistry, Physical

Bifunctional electrocatalysts for Zn-air batteries: recent developments and future perspectives

Shuangshuang Ren et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Multidisciplinary

A review on fundamentals for designing oxygen evolution electrocatalysts

Jiajia Song et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Multidisciplinary

MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions

Hao-Fan Wang et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Physical

Commencing mild Ag-Zn batteries with long-term stability and ultra-flat voltage platform

Guojin Liang et al.

ENERGY STORAGE MATERIALS (2020)

Review Chemistry, Multidisciplinary

Surface/interface nanoengineering for rechargeable Zn-air batteries

Tianpei Zhou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Physical

Facile in-situ growth of Ni2P/Fe2P nanohybrids on Ni foam for highly efficient urea electrolysis

Lei Yan et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

Article Chemistry, Multidisciplinary

Co3O4 Nanoparticles with Ultrasmall Size and Abundant Oxygen Vacancies for Boosting Oxygen Involved Reactions

Zhe Li et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Chemistry, Multidisciplinary

The Kirkendall Effect for Engineering Oxygen Vacancy of Hollow Co3O4 Nanoparticles toward High-Performance Portable Zinc-Air Batteries

Dongxiao Ji et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Large-Area Paper Batteries with Ag and Zn/Ag Screen-Printed Electrodes

Diogo Miguel Esperanca Garcia et al.

ACS OMEGA (2019)

Article Chemistry, Multidisciplinary

Realizing a Rechargeable High-Performance Cu-Zn Battery by Adjusting the Solubility of Cu2+

Qiancheng Zhu et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Multidisciplinary Sciences

Utilizing solar energy to improve the oxygen evolution reaction kinetics in zinc-air battery

Xiaorui Liu et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Advanced Technologies for High-Energy Aluminum-Air Batteries

Jaechan Ryu et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Flexible Hybrid Zn-Ag/Air Battery with Long Cycle Life

Chia-Che Chang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Physical

Achieving high energy density and efficiency through integration: progress in hybrid zinc batteries

Wenxu Shang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Physical

Defect engineering activating (Boosting) zinc storage capacity of MoS2

Wangwang Xu et al.

ENERGY STORAGE MATERIALS (2019)

Review Chemistry, Physical

Hybridization design of materials and devices for flexible electrochemical energy storage

Ruizuo Hou et al.

ENERGY STORAGE MATERIALS (2019)

Article Chemistry, Multidisciplinary

Ni-Mo-O nanorod-derived composite catalysts for efficient alkaline water-to-hydrogen conversion via urea electrolysis

Zi-You Yu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Multidisciplinary

Co3O4 Nanosheets as Active Material for Hybrid Zn Batteries

Peng Tan et al.

SMALL (2018)

Article Energy & Fuels

Solution-Processable Design of Fiber-Shaped Wearable Zn//Ni(OH)2 Battery

Ruyi Chen et al.

ENERGY TECHNOLOGY (2018)

Review Chemistry, Multidisciplinary

Advanced Architectures and Relatives of Air Electrodes in Zn-Air Batteries

Jing Pan et al.

ADVANCED SCIENCE (2018)

Review Energy & Fuels

Batteries and fuel cells for emerging electric vehicle markets

Zachary P. Cano et al.

NATURE ENERGY (2018)

Article Multidisciplinary Sciences

Ethanol as an electrolyte additive for alkaline zinc-air flow batteries

Soraya Hosseini et al.

SCIENTIFIC REPORTS (2018)

Article Nanoscience & Nanotechnology

Integration of Zn-Ag and Zn-Air Batteries: A Hybrid Battery with the Advantages of Both

Peng Tan et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

A Robust Hybrid Zn-Battery with Ultralong Cycle Life

Bing Li et al.

NANO LETTERS (2017)

Review Chemistry, Multidisciplinary

Flexible Zn- and Li-air batteries: recent advances, challenges, and future perspectives

Peng Tan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2017)

Review Multidisciplinary Sciences

Combining theory and experiment in electrocatalysis: Insights into materials design

Zhi Wei Seh et al.

SCIENCE (2017)

Article Chemistry, Physical

Characterization of gas diffusion electrodes for metal-air batteries

Timo Danner et al.

JOURNAL OF POWER SOURCES (2016)

Review Energy & Fuels

Advances in understanding mechanisms underpinning lithium-air batteries

Doron Aurbach et al.

NATURE ENERGY (2016)

Review Multidisciplinary Sciences

Opportunities and challenges for a sustainable energy future

Steven Chu et al.

NATURE (2012)

Review Chemistry, Physical

Metal-Air Batteries with High Energy Density: Li-Air versus Zn-Air

Jang-Soo Lee et al.

ADVANCED ENERGY MATERIALS (2011)

Review Multidisciplinary Sciences

Key challenges in future Li-battery research

J. -M. Tarascon

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES (2010)