Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 22, Issue 1, Pages 37-54Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ob01679j
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This review summarizes the recent advances in chemo-, regio- and stereodivergent reactions catalyzed by palladium complexes. Various reaction types and probable mechanisms are discussed.
Developing efficient and straightforward strategies to rapidly construct structurally distinct and diverse organic molecules is one of the most fundamental tasks in organic synthesis, drug discovery and materials science. In recent years, divergent synthesis of organic functional molecules from the same starting materials has attracted significant attention and has been recognized as an efficient and powerful strategy. To achieve this objective, the proper adjustment of reaction conditions, such as catalysts, solvents, ligands, etc., is required. In this review, we summarized the recent efforts in chemo-, regio- and stereodivergent reactions involving acyclic and cyclic systems catalyzed by palladium complexes. Meanwhile, the reaction types, including carbonylative reactions, coupling reactions and cycloaddition reactions, as well as the probable mechanism have also been highlighted in detail. In this review, recent advances in ligand-enabled palladium-catalyzed divergent synthesis are reported.
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