4.7 Article

Spatio-temporal dynamics of a microsecond pulsed Grimm-type glow discharge

Journal

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
Volume 39, Issue 1, Pages 153-168

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ja00280b

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This paper presents the spatio-temporal dynamics of a Grimm-type microsecond pulsed glow discharge (mu PGD) in argon at 6 mbar. The occurrence of a high current peak during the discharge ignition is analyzed and the importance of displacement current is emphasized. The development of electron excitation temperature for argon atoms and ions at various distances from the cathode is measured. The spatio-temporal evolution of selected spectral lines of argon and copper atoms and ions is analyzed during different phases of the discharge. The results suggest that the behavior of spectral line emissions differs between the pre-peak and afterglow periods, with different lines reaching maximum intensity during these phases. The appearance time and decay time of the afterpeak are shorter for ions than for atoms. These findings are explained in terms of three-body recombination processes and ion mobilities.
Spatio-temporal dynamics of a Grimm-type microsecond pulsed glow discharge (mu PGD), that operates in abnormal glow regime in argon at 6 mbar, is presented. The occurrence of a high current peak during the ignition of the discharge was analyzed and the importance of taking into account the displacement current was pointed out. A development of the electron excitation temperature of argon atoms and argon ions was measured at several distances from the cathode. Spatio-temporal evolution of the intensity of selected spectral lines of atoms and ions of argon and copper were measured and analyzed during the three phases of the discharge development: pre-peak, steady-state and afterglow. The spectral line emissions have different behavior during the pre-peak and the afterglow of the discharge - the lines with low upper-level energies get the maximum intensity in the pre-peak period, while the lines with high upper-level energies get the maximal intensity in the afterglow period. The time of the appearance of the afterpeak maxima and the afterpeak decay time are shorter for the ions than for the atoms. The results are explained primarily in terms of three-body recombination processes and ion mobilities. Carefully arranged and conducted experiment with a large amount of experimental data, together with analysis of excitation and deexcitation processes, could be useful for more precise modeling of mu PGD, as well as a note for selection of adequate spectral lines and discharge conditions for more accurate analytical measurements. Spatio-temporal dynamics of a PGD, in Ar6.0 at 6 mbar for some of Ar I, Ar II, Cu I, Cu II lines. Analysis of a high current peak during ignition of discharge, excitation and deexcitation processes, development of electron excitation temperature of Ar.

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