4.7 Article

Electro-oxidation and UV irradiation coupled method for in-site removing pollutants from human body fluids in swimming pool

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 464, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2023.132963

Keywords

Human body fluids; Swimming pool water; Electrochemical; Ultraviolet

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A comprehensive study was conducted to investigate the efficient removal of human body fluids (HBFs) related pollutants from swimming pool water using UV irradiation combined with electrochemistry. The results showed that the EC/UV treatment exhibited the highest removal rates for these pollutants compared to other treatments. The EC/UV process was resilient to changes in water parameters and could lessen the generation of disinfection by-products. This green technology has the advantages of no chlorine-based chemical additive, easy operation, continuous disinfection efficiency, and fewer byproducts production.
A comprehensive study was conducted to investigate how ultraviolet (UV) irradiation combined with electrochemistry (EC) can efficiently remove human body fluids (HBFs) related pollutants, such as urea/creatinine/ hippuric acid, from swimming pool water (SPW). In comparison with the chlorination, UV, EC, and UV/chlorine treatments, the EC/UV treatment exhibited the highest removal rates for these typical pollutants (TPs) from HBFs in synthetic SPW. Specifically, increasing the operating current of the EC/UV process from 20 to 60 mA, as well as NaCl content from 0.5 to 3.0 g/L, improved urea and creatinine degradation while having no influence on hippuric acid. In contrast, EC/UV process was resilient to changes in water parameters (pH, HCO3- , and actual water matrix). Urea removal was primarily attributable to reactive chlorine species (RCS), whereas creatinine and hippuric acid removal were primarily related to hydroxyl radical, UV photolysis, and RCS. In addition, the EC/UV procedure can lessen the propensity for creatinine and hippuric acid to generate disinfection by-products. We can therefore draw the conclusion that the EC/UV process is a green and efficient in-situ technology for removing HBFs related TPs from SPW with the benefits of needless chlorine-based chemical additive, easy operation, continuous disinfection efficiency, and fewer byproducts production.

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