4.3 Article

GAMMA CONVERGENCE FOR THE DE GENNES-CAHN-HILLIARD ENERGY

Journal

COMMUNICATIONS IN MATHEMATICAL SCIENCES
Volume 21, Issue 8, Pages 2131-2144

Publisher

INT PRESS BOSTON, INC

Keywords

de Gennes-Cahn-Hilliard energy; Gamma convergence; sharp interface limit; surface diffusion

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This paper investigates the Gamma-limit of the degenerate de Gennes-Cahn-Hilliard equation, revealing that it is proportional to the interface area, determined by the de Gennes coefficient and the double well potential.
The degenerate de Gennes-Cahn-Hilliard (dGCH) equation is a model for phase separation which may more closely approximate surface diffusion than others in the limit when the thickness of the transition layer approaches zero. As a first step to understand the limiting behavior, in this paper we study the Gamma-limit of the dGCH energy. We find that its Gamma-limit is a constant multiple of the interface area, where the constant is determined by the de Gennes coefficient together with the double well potential. In contrast, the transition layer profile is solely determined by the double well potential.

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