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Progress of p-block element-regulated catalysts for acetylene hydrochlorination

COORDINATION CHEMISTRY REVIEWS (2024)

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Summary: In order to address the limitations of Cu-based catalysts, 15% Cu-Lx/AC catalysts were synthesized by creating strong interactions between a ligand and CuCl2 precursors. The introduction of the MDPO ligand effectively modulated the electronic properties of the metal centers, resulting in a highly dispersed Cu-P/Cl local structure with Cu1+/Cu2+ as the active center. The sintering of active components in the catalyst and enhanced adsorption and activation of C2H2 and HCl molecules contributed to improved catalytic performance and coking resistance.

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Metal-Organic Frameworks Encaged Ru Single Atoms for Rapid Acetylene Harvest and Activation in Hydrochlorination

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Nitrogen and phosphorus co-doped activated carbon induces high density Cu' active center for acetylene hydrochlorination

Fei Li et al.

Summary: This study aimed to solve the problems of low reaction activity of Cu-based catalysts and agglomeration of active centers in acetylene hydrochlorination. Cu-based catalysts supported by NAP co-doped activated carbon (AC) were manufactured and applied in the reaction. It was found that the doping of N and P improved the dispersion of Cu in carbon and significantly enhanced the catalytic activity. The conclusion provides a reference for the development of acetylene hydrochlorination Cu catalyst.

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High-density pyridine-FeN4 active sites for acetylene hydrochlorination

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Summary: The high price of precious metal catalysts hinders their industrial implementation. Therefore, it is crucial to develop single-atom Fe-N4 catalysts with high site density. We synthesized Fe-N-C microporous catalysts (Cs-Fe-600) using pyridine-N confinement effect, which showed higher acetylene conversion compared to carbon-nitrogen material without Fe addition. The Cs-Fe-600 catalyst deactivated due to agglomeration of Fe metal and loss of pyridine-FeN4 active site, but recovered through high temperature treatment in ammonia gas.

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Excess Copper Chloride Induces Active Sites over Cu-Ligand Catalysts for Acetylene Hydrochlorination

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Summary: In this study, the active sites on Cu-based catalysts for acetylene hydrochlorination were investigated. It was found that the indirect ligand-coordinated sites induced by excess copper chloride exhibited superior performance. Molecular dynamics simulation and density functional theory calculations revealed that excess copper chloride molecules spontaneously formed chain structures, leading to the formation of indirect ligand-coordinated sites and electron transfer along the copper chloride chain, which were crucial for the high catalytic activity. These findings provide fundamental insights into the origin of activity and the identification of active sites in Cu-ligand catalysts for acetylene hydrochlorination.

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Phthalimide Ligand Coordination as a Critical Key for Constructing Chlorine-Platinum-Nitrogen Single-Site Catalysts for Effective Acetylene Hydrochlorination

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Summary: A low dispersion and deficiency of active Pt-L1/SAC-IPA catalyst was synthesized using 2-propanol (IPA) solvent and ligand coordination strategy. IPA, with its low boiling point and weak polarity, helps in the dispersion of Pt species. The introduction of phthalimide ligand (L1) modulates the electronic properties of active metals, resulting in the construction of a single-site-dispersed Cl-Pt-N local structure bearing Pt(II) as the active center. The Pt-L1/SAC-IPA catalyst shows enhanced adsorption and activation performances towards HCl, improving its anticoking performance and reducing the reaction energy barrier.

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Noble Metals Dissolution Catalyzed by [AlCl4-]-Based Ionic Liquids

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Self-oxidation of Au-[Bmim][Cl3] catalyst with enhanced activity and stability for acetylene hydrochlorination

Feng Feng et al.

Summary: There is great potential for carbon-supported gold catalysts to replace toxic mercuric chloride-based catalysts in the acetylene hydrochlorination. We report a strategy for the self-oxidation of Au3+ by the Au-SILP system with [Bmim][Cl3] ILs, which stabilizes all gold species in highly oxidized Au3+ state, resulting in excellent catalytic activity. High coordination numbers Au-Cl entities reduce electron transfer and weaken C2H2 adsorption, while [Bmim][Cl3] ILs self-oxidize gold nanoparticles into Au3+. This study provides a new method for improving gold-based acetylene hydrochlorination catalysts' stability and activity.

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Tailoring Asymmetric Cu-O-P Coupling Site by Carbothermal Shock Method for Efficient Vinyl Chloride Synthesis over Carbon Supported Cu Catalysts

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Summary: A precise and versatile approach was developed to synthesize carbon-supported Cu/Cu3P nanoparticles and Cu single atoms with uniform size and dispersion. The catalytic structure-activity relationships of these catalysts were explored in the acetylene hydrochlorination reaction, and quantitative activity and stability descriptors were derived. This work provides insights for designing well-defined carbon-supported metal nanocatalysts and regulating their catalytic performance.

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Effect of R-SO2-R' ligands on the gold-based catalysts for acetylene hydrochlorination: A DFT study

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Summary: Gold-based mercury-free catalysts show great potential in the industrial production of vinyl chloride. In this study, the catalytic reaction mechanisms of five sulfur-containing ligand gold-based catalysts were investigated using DFT calculation and DFT-D3 correction. The results revealed that the rate-controlling step in the reaction path is the transfer of proton hydrogen. Valuable theoretical guidance for the preparation of efficient sulfur-containing ligand gold-based catalysts in the future was provided.

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Regulating the coordination environment of Ru single-atom catalysts and unravelling the reaction path of acetylene hydrochlorination

Yang Yang et al.

Summary: DFT calculations were used to predict the catalytic activities of metal single-atom catalysts with nitrogen coordination in acetylene hydrochlorination. The results showed that Ru-Nx SACs had the best catalytic performance. Ru-Nx SACs were fabricated by pyrolyzing MOFs with in-situ spatially confined metal precursors, and the N coordination environment was controlled by changing the pyrolysis temperature. Catalytic performance tests indicated that low N coordination number (Ru-N2, Ru-N3) showed excellent activity and stability. DFT calculations further revealed the preference of Ru-N2 and Ru-N3 for activating HCl and Ru-N4 for activating C2H2. These findings provide a reference for the design and control of metal active sites.

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Redispersion strategy for high-loading carbon-supported metal catalysts with controlled nuclearity

Vera Giulimondi et al.

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Interactions between atomically dispersed copper and phosphorous species are key for the hydrochlorination of acetylene

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Process monitoring of the Au-S bond conversion in acetylene hydrochlorination

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Performance descriptors of nanostructured metal catalysts for acetylene hydrochlorination

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Construction of a Thermally Stable Low-HgCl2 Catalyst via Chalcogen Bonding and Its Enhanced Activity in Acetylene Hydrochlorination

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Effect of Different Heteroatoms Anchoring a Cu Single-Atom Catalyst on Acetylene Hydrochlorination

Yiming Jia et al.

Summary: By using spin-polarized density functional theory to construct single Cu atoms anchored by different heteroatoms, it was found that N-doped substrate increased the charge of Cu atom, B and P-doped substrates provided multiple active sites, while O-doped substrate couldn't stably anchor the single Cu atom. Different catalysts had different dominant mechanisms, and it was discovered that charge transfer between single metal atoms and substrates could serve as a descriptor for catalytic performance.

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Non-metallic carbon-based catalysts for acetylene hydrochlorination: The effect of graphitization degree of carbonaceous material

Qi Tang et al.

Summary: The graphitization degree of activated carbon fiber (ACF) affects its catalytic performance, but the relationship is not monotonic. The interface between the graphite layer and the support acts as the catalytic active site, and the difference in the degree of exposure of the active interface results in the difference in catalytic activity.

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Tunable Redox Cycle and Enhanced π-Complexation in Acetylene Hydrochlorination over RuCu Catalysts

Yurui Fan et al.

Summary: This study demonstrates the synergistic effect of Cu(X) on the catalytic activity and selectivity of the acetylene hydrochlorination reaction. The findings provide guidance for designing efficient Ru-based catalysts and solutions for replacing mercury-contained catalysts in engineering applications.

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Sustainable Nanoporous Carbon Catalysts Derived from Melamine Assisted Cross-Linking of Poly(vinyl chloride) Waste for Acetylene Hydrochlorination

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Lowering the Operating Temperature of Gold Acetylene Hydrochlorination Catalysts Using Oxidized Carbon Supports

Samuel Pattisson et al.

Summary: The commercialization of gold for acetylene hydrochlorination is a significant achievement in the field. The development of second-generation gold catalysts aims to enhance their activity and stability. This study demonstrates that the surface oxygen content of carbon-based gold catalysts affects their activity. By modifying the Hummers chemical oxidation method before gold deposition, the oxygen content of carbon can be adjusted. The oxidized carbon-based catalysts exhibit higher activity at lower temperatures compared to untreated carbon, with an optimum oxygen content of around 18%. Increasing the oxygen content and concentration of C-O functionality lowers the catalyst's light-off temperature, offering a potential approach to produce highly active acetylene hydrochlorination catalysts.

ACS CATALYSIS (2022)

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Unifying views on catalyst deactivation

Antonio J. Martin et al.

Summary: This article points out the overlooked issue of catalyst deactivation in catalysis research and proposes a unified classification of deactivation modes, which helps understand and mitigate catalyst deactivation.

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M/C3N4/AC (M = Au, Pt, Ru)-catalyzed acetylene coupling with ethylene dichloride: How effective are the bifunctionalities?

Qing Yu et al.

Summary: Highly active and stable carbon nitride-based catalysts were developed for the acetylene coupling with ethylene dichloride reaction, aiming at sustainable PVC manufacturing. Modifying the best-performing system with different precious metals intensified the reaction activity but weakened the dechlorination ability. Superior coupling performance was achieved with C3N4/AC and single-atom Au/C3N4/AC catalysts in cascade reactors. The study suggests that dechlorination is a crucial step in the coupling reaction and different active sites should be engineered for the activation of acetylene and ethylene dichloride molecules in future work.

CHINESE JOURNAL OF CATALYSIS (2022)

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High nitrogen carbon material with rich defects as a highly efficient metal-free catalyst for excellent catalytic performance of acetylene hydrochlorination

Fangjie Lu et al.

Summary: The study developed a simple strategy to synthesize high nitrogen and rich carbon defect carbon material through polymerizing DAP and APS. The catalytic performance of N-doped carbon material was enhanced with an increment in carbon defects. NC-800 catalyst exhibited outstanding catalytic activity and stability in acetylene hydrochlorination, reflecting its unlimited potential as a carbon material.

CHINESE JOURNAL OF CHEMICAL ENGINEERING (2021)

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Effects of N-, P-, or O-containing ligands on gold-based complex catalysts for acetylene hydrochlorination

Yanqin Li et al.

Summary: The study demonstrated that the interaction between ligands and gold species played a crucial role in enhancing catalytic activity, with different ligands exhibiting distinct effects in the catalytic reaction. All prepared catalysts showed improved adsorption and activation capacity of hydrogen chloride, with nitrogen-containing ligands enhancing the dispersion of gold species and phosphorus-containing ligands increasing the content of active Aun+ species. Additionally, the stability of all the prepared Au-Lx/AC catalysts was ensured by inhibiting the agglomeration of gold components or coking deposition.

APPLIED CATALYSIS A-GENERAL (2021)

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Solvent-assisted synthesis of N-doped activated carbon-based catalysts for acetylene hydrochlorination

Yawen Liu et al.

Summary: In this study, N-doped carbon-based catalysts were synthesized using a unique method and showed high activity in acetylene conversion. The excellent performance of the N-doped catalyst was mainly attributed to its unique nitrogen intercalation pathway and mesoporous structure.

APPLIED CATALYSIS A-GENERAL (2021)

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Sulfur Promotion in Au/C Catalyzed Acetylene Hydrochlorination

Simon R. Dawson et al.

Summary: The study investigates the use of sulfur-containing compounds as promoters for producing highly active Au/C catalysts. Through careful consideration of pre- or post-treatments, concentration of dopants used, and modification of washing steps, the observed enhancement in catalytic activity can be optimized. Pre-treatment of the carbon support with sulfuric acid resulted in the most active Au/C catalyst with an acetylene conversion of around 70% at 200 degrees C.

SMALL (2021)

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Constructing the single-site of pyridine-based organic compounds for acetylene hydrochlorination: From theory to experiment

Chaoyue Zhao et al.

Summary: A pure pyridine-based organic polymer catalyst with high catalytic activity in acetylene hydrochlorination reaction has been successfully designed and assembled. It demonstrates a high acetylene conversion rate of 88% and a vinyl chloride selectivity of over 99%. The active site of the catalyst is identified as the pyridinic N atom in the pyridine ring, with acetylene insertion to HCl potentially being the rate-determining step.

APPLIED ORGANOMETALLIC CHEMISTRY (2021)

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A DFT study of graphene-FeNx (x=4, 3, 2, 1) catalysts for acetylene hydrochlorination

Xuening Zhou et al.

Summary: This paper systematically studied the mechanism and activity of graphene-FeNx series of non-noble metal catalysts for acetylene hydrochlorination using density functional theory. The results showed that the activity of the reaction decreased with a decrease in doped nitrogen atoms in the catalyst, and graphene-FeN4 exhibited excellent catalytic performance.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

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Single-Atom Ruthenium Catalytic Sites for Acetylene Hydrochlorination

Hongyu Zhang et al.

Summary: A single-atom ruthenium catalyst was designed and prepared using a cascade anchoring strategy to maximize the efficiency of Ru atoms in acetylene hydrochlorination. Experimental results showed that the catalyst exhibited excellent activity and stability, with potential to be an important technological tool for improving the efficiency of acetylene hydrochlorination reactions in the future.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

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Design of carbon supports for metal-catalyzed acetylene hydrochlorination

Selina K. Kaiser et al.

Summary: This study identifies the crucial roles of carbon in determining the activity and stability of hydrochlorination catalysts, with acetylene adsorption capacity and density of acidic oxygen sites being central descriptors for optimal performance.

NATURE COMMUNICATIONS (2021)

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Palladium-halloysite nanocomposites as an efficient heterogeneous catalyst for acetylene hydrochlorination

Meng Zhang et al.

Summary: Halloysite nanotubes (HNTs) were utilized to design and synthesize palladium-based catalysts for acetylene hydrochlorination, with urea modification proving to be effective in enhancing catalytic performance by immobilizing Pd species and inhibiting carbon deposition on the catalyst surface.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2021)

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Waste cigarette butt-derived nitrogen-doped porous carbon as a non-mercury catalyst for acetylene hydrochlorination

Xin Jin et al.

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Stabilizing supported gold catalysts in acetylene hydrochlorination by constructing an acetylene-deficient reaction phase

Bolin Wang et al.

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Constructing green mercury-free catalysts with single pyridinic N species for acetylene hydrochlorination and mechanism investigation

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Synthesis of a vinyl chloride monomer via acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

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Constructing a fragmentary g-C3N4 framework with rich nitrogen defects as a highly efficient metal-free catalyst for acetylene hydrochlorination

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MOF-derived various morphologies of N-doped carbon composites for acetylene hydrochlorination

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A novel S, N dual doped carbon catalyst for acetylene hydrochlorination

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APPLIED CATALYSIS A-GENERAL (2018)

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Effect of carbon defects on the nitrogen-doped carbon catalytic performance for acetylene hydrochlorination

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APPLIED CATALYSIS A-GENERAL (2018)

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The curious relationship of sintering to activity in supported gold catalysts for the hydrochlorination of acetylene

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APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Wheat flour-derived N-doped mesoporous carbon extrudate as superior metal-free catalysts for acetylene hydrochlorination

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CHEMICAL COMMUNICATIONS (2018)

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Heterogeneous non-mercury catalysts for acetylene hydrochlorination: progress, challenges, and opportunities

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GREEN CHEMISTRY (2018)

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Sulfur and nitrogen co-doped mesoporous carbon with enhanced performance for acetylene hydrochlorination

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JOURNAL OF CATALYSIS (2018)

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Green production of PVC from laboratory to industrialization: State-of-the-art review of heterogeneous non-mercury catalysts for acetylene hydrochlorination

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JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2018)

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Direct synthesis of mesoporous nitrogen doped Ru-carbon catalysts with semi-embedded Ru nanoparticles for acetylene hydrochlorination

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MICROPOROUS AND MESOPOROUS MATERIALS (2018)

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The activity and stability of PdCl2/C-N catalyst for acetylene hydrochlorination

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Descriptors for High-Performance Nitrogen-Doped Carbon Catalysts in Acetylene Hydrochlorination

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ACS CATALYSIS (2018)

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Ionic liquids-coordinated Au catalysts for acetylene hydrochlorination: DFT approach towards reaction mechanism and adsorption energy

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CATALYSIS SCIENCE & TECHNOLOGY (2018)

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Novel nitrogen-doped Au-embedded graphene single-atom catalysts for acetylene hydrochlorination: A density functional theory study

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COMPUTATIONAL AND THEORETICAL CHEMISTRY (2018)

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The Effect of N-Doping in Activated Carbon-Supported Au-Sr Catalysts for Acetylene Hydrochlorination to Vinyl Chloride

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CHEMISTRYSELECT (2018)

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Mercury-free nitrogen-doped activated carbon catalyst: an efficient catalyst for the catalytic coupling reaction of acetylene and ethylene dichloride to synthesize the vinyl chloride monomer

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Hydrochlorination of acetylene catalyzed by activated carbon supported highly dispersed gold nanoparticles

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APPLIED CATALYSIS A-GENERAL (2018)

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Zeolite Supported Ionic Liquid Catalysts for the Hydrochlorination of Acetylene

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Metal-organic framework-derived cobalt and nitrogen co-doped porous carbon with four-coordinated Co-N-x for efficient acetylene hydrochlorination

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APPLIED ORGANOMETALLIC CHEMISTRY (2018)

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Nitrogen doped nanoflower porous carbon as a nonmetal catalyst for acetylene hydrochlorination

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Effect of acidity and ruthenium species on catalytic performance of ruthenium catalysts for acetylene hydrochlorination

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Efficient and stable Ru(III)-choline chloride catalyst system with low Ru content for non-mercury acetylene hydrochlorination

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Boron-modified activated carbon supporting low-content Au-based catalysts for acetylene hydrochlorination

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Alternative solvent to aqua regia to activate Au/AC catalysts for the hydrochlorination of acetylene

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Effective Catalytic Performance of Plasma-Enhanced W2N/AC as Catalysts for Acetylene Hydrochlorination

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Catalytically Active Boron Nitride in Acetylene Hydrochlorination

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Bi/AC modified with phosphoric acid as catalyst in the hydrochlorination of acetylene

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Activated Carbon-Supported Tetrapropylammonium Perruthenate Catalysts for Acetylene Hydrochlorination

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The Neglected Significant Role for Graphene-Based Acetylene Hydrochlorination Catalysts - Intrinsic Graphene Defects

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CHEMISTRYSELECT (2017)

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Improvement of imidazolium-based ionic liquids on the activity of ruthenium catalyst for acetylene hydrochlorination

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Nitrogen-doped Carbon Derived from ZIF-8 as a High-performance Metal-free Catalyst for Acetylene Hydrochlorination

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Acetylene hydrochlorination using Au/carbon: a journey towards single site catalysis

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Cobalt-nitrogen-activated carbon as catalyst in acetylene hydrochlorination

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Stabilizing Au(III) in supported-ionic-liquid-phase (SILP) catalyst using CuCl2 via a redox mechanism

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Deactivation mechanism and regeneration of carbon nanocomposite catalyst for acetylene hydrochlorination

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Halogen-Mediated Conversion of Hydrocarbons to Commodities

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Ru-Co(III)-Cu(II)/SAC catalyst for acetylene hydrochlorination

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APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Enhanced stability of hydrochlorination of acetylene using polyaniline-modified Pd/HY catalysts

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CATALYSIS COMMUNICATIONS (2016)

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Effect of K promoter on the stability of Pd/NFY catalysts for acetylene hydrochlorination

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CATALYSIS COMMUNICATIONS (2016)

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One-pot synthesis of nitrogen and sulfur co-doped activated carbon supported AuCl3 as efficient catalysts for acetylene hydrochlorination

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CHINESE CHEMICAL LETTERS (2016)

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Acetylene hydrochlorination over 13X zeolite catalysts at high temperature

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GREEN CHEMISTRY (2016)

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Bimetallic Au-Sn/AC catalysts for acetylene hydrochlorination

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MOF-derived nitrogen-doped porous carbon as metal-free catalysts for acetylene hydrochlorination

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JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2016)

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Non-mercury catalytic acetylene hydrochlorination over a NH4F-urea-modified Pd/HY catalyst for vinyl chloride monomer production

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NEW JOURNAL OF CHEMISTRY (2016)

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Hydrochlorination of acetylene catalyzed by an activated carbon supported chlorotriphenylphosphine gold complex

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Supported ionic-liquid-phase-stabilized Au(III) catalyst for acetylene hydrochlorination

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Ru/N-AC catalyst to produce vinyl chloride from acetylene and 1,2-dichloroethane

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A ligand coordination approach for high reaction stability of an Au-Cu bimetallic carbon-based catalyst in the acetylene hydrochlorination process

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CATALYSIS SCIENCE & TECHNOLOGY (2016)

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Effects of nitrogen-dopants on Ru-supported catalysts for acetylene hydrochlorination

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The Preparation of Cu-g-C3N4/AC Catalyst for Acetylene Hydrochlorination

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Vinyl chloride monomer production catalysed by gold: A review

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Direct synthesis of nitrogen-doped mesoporous carbons for acetylene hydrochlorination

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Catalytic properties of Pd/HY catalysts modified with NH4F for acetylene hydrochlorination

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Enhancement of Au/AC acetylene hydrochlorination catalyst activity and stability via nitrogen-modified activated carbon support

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A low content Au-based catalyst for hydrochlorination of C2H2 and its industrial scale-up for future PVC processes

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Discovery, Development, and Commercialization of Gold Catalysts for Acetylene Hydrochlorination

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Confining Noble Metal (Pd, Au, Pt) Nanoparticles in Surfactant Ionic Liquids: Active Non-Mercury Catalysts for Hydrochlorination of Acetylene

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Development of a Heterogeneous Non-Mercury Catalyst for Acetylene Hydrochlorination

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Boron and Nitrogen Doping in Graphene for the Catalysis of Acetylene Hydrochlorination

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Activated carbon supported ternary gold-cesium(I)-indium(III) catalyst for the hydrochlorination of acetylene

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Catalytic dehydrochlorination of 1,2-dichloroethane to produce vinyl chloride over N-doped coconut activated carbon

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Ultra-low Ru-promoted CuCl2 as highly active catalyst for the hydrochlorination of acetylene

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Nitrogen functional groups on an activated carbon surface to effect the ruthenium catalysts in acetylene hydrochlorination

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Efficient Au0/C catalyst synthesized by a new method for acetylene hydrochlorination

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Promotional effect of copper(II) on an activated carbon supported low content bimetallic gold-cesium(I) catalyst in acetylene hydrochlorination

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Activated-Carbon-Supported Gold-Cesium(I) as Highly Effective Catalysts for Hydrochlorination of Acetylene to Vinyl Chloride

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C-doped boron nitride fullerene as a novel catalyst for acetylene hydrochlorination: a DFT study

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Nitrogen-doped active carbon as a metal-free catalyst for acetylene hydrochlorination

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Active ruthenium species in acetylene hydrochlorination

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APPLIED CATALYSIS A-GENERAL (2014)

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Nitrogen-Doped Pitch-Based Spherical Active Carbon as a Nonmetal Catalyst for Acetylene Hydrochlorination

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Influence of Surface Chemistry of Activated Carbon on the Activity of Gold/Activated Carbon Catalyst in Acetylene Hydrochlorination

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2014)

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A novel, non-metallic graphitic carbon nitride catalyst for acetylene hydrochlorination

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Melamine Modification of Spherical Activated Carbon and Its Effects on Acetylene Hydrochlorination

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JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION (2014)

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Development of Au/C catalysts by the microwave-assisted method for the selective hydrochlorination of acetylene

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Phosphorus-doped carbon supports enhance gold-based catalysts for acetylene hydrochlorination

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Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride

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GLOBAL ENVIRONMENTAL POLITICS (2014)

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AuCl3 on polypyrrole-modified carbon nanotubes as acetylene hydrochlorination catalysts

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Enhanced Activity of Hydrochlorination of Acetylene Using Melamine-Modified Activated Carbon Supported Gold Catalyst

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Non-mercury catalytic acetylene hydrochlorination over bimetallic Au-Co(III)/SAC catalysts for vinyl chloride monomer production

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GREEN CHEMISTRY (2013)

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Aqua regia activated Au/C catalysts for the hydrochlorination of acetylene

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Hydrochlorination of acetylene to vinyl chloride monomer over bimetallic Au-La/SAC catalysts

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Reactivation of a carbon-supported gold catalyst for the hydrochlorination of acetylene

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Effect of KCl on CuCl2/γ-Al2O3 catalyst for oxychlorination of ethane

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