Journal
CELLULOSE
Volume -, Issue -, Pages -Publisher
SPRINGER
DOI: 10.1007/s10570-023-05640-8
Keywords
Cellulose nanocrystals; Protic ionic liquid; Proton solid conductors; Thermal properties; Conductivity; Structure organization by NMR
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This study presents new solid electrolytes based on cellulose nanocrystals and protic ionic liquid. The materials exhibit excellent thermal stability and conductivity properties. The correlation between the nanostructure and transport properties of the membranes has been investigated. The thermal and conductivity properties of these materials can compete with currently available membranes, and further research may lead to the development of materials suitable for next-generation fuel cells.
The search for solid electrolytes which have good proton conductivity in anhydrous conditions, thermal and mechanical stability, and are at the same time environmentally friendly and easy to manufacture is a big challenge which we have undertaken. This work presents new solid electrolytes based on cellulose nanocrystals with protic ionic liquid 1-methylimidazolium bis(trifluoromethylsulfonyl) imide (PIL) which have been obtained and whose thermal and conductivity properties and nanoscale organization has been determined. Two membranes were synthesized which differ as to the amount of absorbed PIL. They show excellent thermal stability up to 200 C-degrees. The maximum value of ionic conductivity is about 10(-2) S/m at 200 C-degrees in anhydrous conditions and falls in the range of 10(-3)-10(-2) S/m for temperatures from 150 to 200 C-degrees. The correlation between the transport properties of membranes and their nanostructure has been probed by solid-state nuclear magnetic resonance spectroscopy. The thermal and conductivity properties of the new materials can compete with currently available membranes. Further work on a composite with a similar chemical composition should lead to obtaining a membrane capable of operating in next-generation fuel cells (T > 120 C-degrees).
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