Related references
Note: Only part of the references are listed.
Article
Multidisciplinary Sciences
Qinghe Cao et al.
Summary: The authors propose a gradient design for zinc anodes that prevents side reactions and dendrite growth. This design allows for long-term stable zinc anodes at high currents/capacities, which is a significant challenge for practical rechargeable zinc-ion batteries.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Buke Wu et al.
Summary: This study improves the reversibility and utilization of zinc anodes by using three-dimensional printed graphene arrays, overcoming the limitations of current two-dimensional geometric design of zinc anodes. The graphene array structures can accommodate the volume change during zinc deposition/dissolution process and protect the battery from short circuits.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Haoyu Li et al.
Summary: Aqueous Zn ion batteries are promising candidates for electrochemical energy storage due to their safety, affordability, and performance. However, the instability of the Zn anode in aqueous electrolytes hinders the development of Zn-based energy storage devices. This review focuses on electrolyte manipulation strategies, which have shown potential in improving the stability of Zn anodes and enhancing overall battery performance. The challenges, fundamental studies, optimizing methods, and future research perspectives in Zn deposition are discussed, providing insights for the further development of advanced rechargeable AZIBs.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jinrong Luo et al.
Summary: In this study, the effect of a new high donor number (DN) additive pyridine on the performance of aqueous Zn ion batteries (AZIBs) was investigated. The results showed that the incorporation of pyridine could regulate the molecule distribution inside the inner Helmholtz plane (IHP), leading to improved stability and deep discharge performance of the battery.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Mengke Peng et al.
Summary: In this study, a polycation additive, polydiallyl dimethylammonium chloride (PDD), is introduced to achieve long-term and highly reversible Zn plating/stripping. The PDD can regulate the electric fields of electrolyte and Zn/electrolyte interface to improve Zn2+ migration behaviors and guide dominant Zn (002) deposition. Moreover, PDD creates a positive charge-rich protective outer layer and a N-rich hybrid inner layer to enhance the Zn2+ desolvation and prevent direct water contact with the Zn anode, resulting in improved reversibility and long-term stability of Zn anodes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Yuhang Dai et al.
Summary: Routine electrolyte additives are not effective enough for uniform zinc (Zn) deposition. Based on underpotential deposition (UPD), an escort effect of electrolyte additives for uniform Zn deposition at the atomic level is proposed. With nickel ion (Ni2+) additives, metallic Ni deposits preferentially and triggers the UPD of Zn on Ni, facilitating firm nucleation and uniform growth of Zn while suppressing side reactions. The optimized cell operates for over 900 h at 1 mA cm(-2), more than 4 times longer than the blank one, indicating the significance of this work.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Meng Fu et al.
Summary: A strategy of using saturated fatty acid-zinc interfacial layer to modulate the interfacial redox process of zinc for ultrastable Zn metal anodes is proposed. The in situ complexing of saturated fatty acid-zinc interphases can construct a thin zinc compound layer with zincophilic sites that regulate Zn nucleation and deposition behaviors. The multifunctional interfacial layer with internal hydrophobic carbon chains as a protective layer efficiently excludes active water molecules and inhibits the surface corrosion of zinc. The modified anode shows a long cycle life of over 4000 h at 5 mA cm-2.
Article
Chemistry, Physical
Huaming Yu et al.
Summary: The addition of trace hexamethylenetetramine (HMTA) additive improves the reversibility and performance of zinc batteries.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Fan Li et al.
Summary: Driven by theory calculations, a dual-interface strategy of surface texture engineering and passivation layer protection is developed to regulate the undesirable side reactions and deposition behavior of Zn metal anodes. This dual-interface enables the inhibition of side reactions, acceleration of de-solvation, homogenization of ion flux, and guided deposition orientation, resulting in significantly extended stability and improved reversibility of Zn electrodes. It can operate steadily for over 6600 hours and retain high reversibility even at higher current densities. Furthermore, it enhances the rate capability and cyclic stability in both aqueous and solid-state Zn metal batteries.
ADVANCED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Ruwei Chen et al.
Summary: This study demonstrates a new strategy for stabilizing zinc anodes in aqueous zinc-ion batteries by adding trace amounts of ammonium hydroxide. The additive helps protect the zinc anodes by lowering the hydrogen evolution reaction potential, promoting the formation of a uniform solid electrolyte interphase, and homogenizing the electric field. This comprehensive protection enables dendrite-free zinc deposition and improved electrochemical performance in zinc//MnO2 full cells.
NANO-MICRO LETTERS
(2023)
Article
Chemistry, Physical
Leilei Zheng et al.
Summary: Methylammonium acetate was found to enhance the reversibility and stability of the Zn anode as an electrolyte additive. Acetate anions competitively engage the Zn2+ solvation structure, reducing water reactivity and promoting anion-enriched electrolyte structure, which effectively suppresses byproducts and dendrite formation. The formation of an anion-derived, robust solid electrolyte interphase with an inorganic/organic hybrid structure enables improved cycling performance in Zn||Na3V2(PO4)(3) batteries and Zn||activated carbon capacitors.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Yu Liu et al.
Summary: In this study, glycine is used as an additive to modulate the solvation shell structure and enhance the interfacial stability of aqueous Zn ion batteries. The results show that the cycle life of the symmetrical cells reaches over 3200 h in glycine-containing electrolytes, and the Zn//NVO full cell exhibits exceptional cycling stability for 3000 cycles at 5 A g-1. Therefore, the proposed strategy for interfacial chemistry modulation, represented by glycine, has considerable potential in promoting the commercialization progress of aqueous batteries.
Article
Chemistry, Multidisciplinary
Jiandong Wan et al.
Summary: Sodium tartrate is used as a dual-functional electrolyte additive to improve the reversibility of aqueous zinc-ion batteries. The additive preferentially adsorbs on the zinc surface, coordinates with zinc ions, and promotes uniform zinc deposition on the (002) plane, inhibiting side reactions and dendrite growth. This leads to long-term cycling stability and improved performance of zinc||MnO2 full cells.
Review
Chemistry, Multidisciplinary
Jingjing Yang et al.
Summary: This review comprehensively summarizes the recent progress of interphase modulation in zinc-ion batteries (ZIBs), aiming to achieve high-performance ZIBs with prolonged lifespan and high reversibility. It provides a systematic guideline for constructing ideal artificial layers.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Minghao Zhang et al.
Summary: A dynamically interfacial pH-buffering strategy using N-methylimidazole (NMI) additive is proposed to eliminate the accumulation of by-products by removing detrimental OH- at the zinc/electrolyte interface. An interfacial absorption layer assembled by NMI and protonated NMI (NMIH+) is found to replenish the interface with protons constantly, resulting in excellent cumulative plating capacity and ultrahigh Coulombic efficiency for zinc electrodes. Additionally, the NMI/NMIH+ buffer additive enhances the dissolution/deposition process on the cathode, leading to enhanced cycling capacity.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zeyu Shen et al.
Summary: Regulating the molecular structure of the inner Helmholtz plane can convert deposition into activation control, achieving dendrite-free zinc growth and crystallographic optimization. Electrolyte engineering and tailored solvation structure greatly improve the utilization efficiency and total charge passed of zinc metal.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Hongfei Wang et al.
Summary: By using a 100 mM xylitol additive, the plating/stripping processes in Zn-ion batteries can achieve high reversibility. The xylitol molecules not only inhibit the hydrogen evolution reaction, but also accelerate the migration of cations through the expelling of active H2O molecules and weakening of electrostatic interactions. Additionally, the preferential adsorption of xylitol molecules on the Zn surface forms a shielding buffer layer, which hinders the sedimentation and diffusion of Zn2+ ions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Engineering, Environmental
Ziwei Zhao et al.
Summary: In this study, a novel electrolyte additive (histidine) was introduced into the conventional ZnSO4 electrolyte to address the issues of dendrite growth, hydrogen evolution reaction, and by-product generation with metallic zinc-based anodes. The additive molecule exhibited strong cationic specific absorption with the zinc anode, effectively regulating Zn2+ deposition and inhibiting hydrogen evolution. The unique buffer-like functional groups of histidine further stabilized the electrolyte interphase pH value, reducing by-product generation. With this electrolyte additive, a Zn||Zn symmetric cell showed excellent stability, running for more than 3000 hours under a current density of 2 mA cm-2.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Tian Chen Li et al.
Summary: An efficient adsorptive additive strategy is proposed to reshape the electric double layer and regulate Zn interfacial chemistry, solving the problem of unstable Zn interface caused by undesired dendrites and parasitic side reactions. The self-adaptive adlayer constructed creates a horizontally aligned Zn deposition along the (002) plane and a localized environment lacking H2O and SO4 (2-), resulting in thermodynamically stable and highly reversible Zn electrochemistry. The achieved reversible plating/stripping of 3800 h and high Coulombic efficiency of 99.8% demonstrate the potential for practical application in a scalable, low-cost, rechargeable battery.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Physical
Zhaolin Na et al.
Summary: In this study, a gradient Zn anode (LLP@TreatedZn) with a passivated-layer at the top and fresh-zinc-layer at the bottom was developed using potassium permanganate solution treatment and laser lithography. The passivation layer prevents corrosion and side reactions, while promoting preferential deposition of Zn at the bottom of the microchannel. The LLP@Treated Zn anodes exhibited stable cycling performance over 700h at high current densities. Laser lithography also allowed for the fabrication of Zn anodes with different surface morphologies.
ACS ENERGY LETTERS
(2023)
Article
Chemistry, Physical
Guosheng Duan et al.
Summary: This study proposes a dynamic bridging strategy to enhance the reversibility of the Zn metal anode by using a chain taurine (TA) additive. TA can switch between inner Helmholtz plane (IHP) adsorption and modified solvation sheath due to salt bridge interactions. The adsorbed TA forms H2O-poor channels that facilitate the transport and desolvation of Zn2+ solvation sheaths, resulting in uniform nucleation and inhibition of H2O reduction. The Zn metal anode exhibits excellent stability and low polarization voltage at high and low current densities. This work provides a new insight into electrolyte engineering for high-performance aqueous Zn metal batteries (AZMBs).
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ruwei Chen et al.
Summary: This study proposes a hydrated deep eutectic electrolyte with reduced free water content, which can suppress water-induced side reactions and provide high Zn2+ mass transfer kinetics. This results in highly reversible Zn anodes and high capacity Zn//NVO full cells.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Peng Xiao Sun et al.
Summary: In this study, a TiOx/Zn/N-doped carbon inverse opal (TZNC IO) host is developed to regulate Zn deposition and prevent side reactions. The highly ordered IO host and three-dimensional open networks enable stable Zn deposition and cycling performance at large current densities.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Lei Zhang et al.
Summary: Aqueous Zn-ion batteries have the potential for large-scale energy storage due to their safety and cost-effectiveness. The addition of nettle extract helps to guide uniform zinc deposition on the anode, effectively suppressing dendrite growth and improving battery performance over extended cycling. This approach of engineering zincophilic sites through plant extracts opens up new possibilities for dendrite-free zinc anodes.
ENERGY STORAGE MATERIALS
(2022)
Article
Multidisciplinary Sciences
Shuo Jin et al.
Summary: Aqueous zinc batteries have potential for cost-effective and safe electricity storage. Researchers have developed an in situ formed nanometric interphase strategy to enable fast-charging of aqueous zinc cells, achieving highly reversible cycling at high current densities and capacities.
NATURE COMMUNICATIONS
(2022)
Article
Multidisciplinary Sciences
Huan Yu et al.
Summary: We developed a three-dimensional hybrid fiber host for high-performance Zn metal batteries, which enables homogeneous Zn deposition on the interior and exterior surfaces of the hollow fibers.
Article
Chemistry, Physical
Chang Li et al.
Summary: This study introduces a novel additive that effectively solves the issues in aqueous zinc-metal batteries, leading to excellent cycling performance and efficient zinc deposition.
Article
Chemistry, Physical
Tianyi Zhou et al.
Summary: The introduction of PASP as an electrolyte additive for aqueous rechargeable zinc batteries can address the issues of dendrite growth and side-reactions, leading to improved cyclic stability and high Coulombic efficiency.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Jing Xu et al.
Summary: The introduction of silk fibroin (SF) as an electrolyte additive for aqueous zinc-ion batteries can form a stable and self-healable protective film, which promotes homogeneous zinc deposition and suppresses parasitic reactions, leading to improved cycle life of the batteries.
Article
Chemistry, Multidisciplinary
Zhengqiang Hu et al.
Summary: This study proposes the use of cerium chloride (CeCl3) as an additive in aqueous Zn batteries to inhibit dendrite growth and enhance electrolyte stability, resulting in improved cycling stability and efficiency of the batteries.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Physical
Tian Wang et al.
Summary: This review provides an overview of the effective strategies and recent progress in achieving planar and dendrite-free zinc deposition in aqueous zinc metal batteries, and elucidates the influence of crystal orientation on zinc metal deposition behavior.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Hongyu Qin et al.
Summary: This study introduces a thiourea additive to improve the performance of aqueous zinc ion batteries (AZIBs) by constructing a unique metal-molecule interface, which regulates the interface chemistry of the zinc electrode and the electrolyte environment. The metal-molecule interface acts as a corrosion inhibitor to alleviate water-induced side reactions and as a regulator for promoting homogeneous zinc deposition, resulting in a corrosion-free and dendrite-free zinc anode. The zinc|zinc symmetric cell exhibits an extended lifespan and high cumulative capacity, while the zinc|V2O5 full cell shows a high capacity retention after cycles.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yang Wang et al.
Summary: This study proposes a synergistic strategy to facilitate Zn2+ migration kinetics and regulate surface energy for dendrite-free Zn deposition and suppressing self-corrosion in aqueous Zn metal batteries (AZMBs). The use of multifunctional covalent organic frameworks with sulfonate-rich nanochannels allows for rapid extraction of Zn2+ from the electrolyte, promoting uniform nucleation and enhancing the stability of Zn anodes. The zincophilic coatings also induce preferential crystallographic growth, further improving the performance of the batteries.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Engineering, Environmental
Qi Meng et al.
Summary: This study proposes a multifunctional additive, cysteine, for stabilizing zinc anode and addressing the instability issue in aqueous zinc ion batteries. Experimental and theoretical analysis demonstrate that the multiple polar groups of cysteine can strongly interact with Zn2+ and Zn metal, enabling the reconfiguration of solvation shell and anode/electrolyte interface. The synergistic effect of this multifunctional additive effectively inhibits dendrite growth and side reactions, resulting in a more stable zinc anode.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Bin Luo et al.
Summary: Despite the high theoretical capacity, low cost, and intrinsic safety, the practical application of aqueous Zn-ion batteries has been limited by the dendrite growth and side reactions of Zn anode. This study successfully enhanced the uniform deposition of Zn nucleation and inhibited dendrite growth by modifying the Zn anode with TCNQ. The TCNQ@Zn anode exhibited remarkable cycling stability at different current densities.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yanqun Lv et al.
Summary: This study demonstrates the use of zwitterionic ionic liquids (ZIL) to construct a self-adaptive electric double layer (EDL) in zinc metal batteries, enabling dendrite-free plating/stripping and high zinc utilization. The Zn//NaV3O8 center dot 1.5H(2)O full battery exhibits superfast charging/discharging and high areal capacity.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Xiaohui Zeng et al.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Miao Zhou et al.
Summary: This study investigates a novel zinc anode with a surface-preferred (002) crystal plane, revealing its characteristics of fewer dendrites, no by-products, and weak hydrogen evolution. This leads to improved stability and reversibility of the battery system.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Dan Li et al.
Summary: A low-concentration aqueous Zn(OTF)(2)-Zn(NO3)(2) electrolyte was designed to form a robust inorganic ZnF2-Zn-5(CO3)(2)(OH)(6)-organic bilayer SEI, allowing high Coulombic efficiency and energy density. The study achieved a high CE of 99.8% for 200 h in Ti parallel to Zn cells, and a high energy density of 168 Wh kg(-1) with 96.5% retention for 700 cycles in Zn parallel to MnO2 cells with a low Zn/MnO2 capacity ratio of 2:1.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Multidisciplinary Sciences
Weidong Zhang et al.
Summary: This study presents a method utilizing anisotropic nanostructures to form dynamic interphases in battery electrolytes, achieving ordered assembly of metal electrodeposits and high anode reversibility. The research demonstrates the promotion of vertically aligned and spatially compact zinc electrodeposits with unprecedented reversibility, as well as uniform growth of compact magnesium and aluminum electrodeposits, offering a general pathway toward energy-dense metal batteries based on earth-abundant anode chemistries.
Article
Chemistry, Physical
Siyuan Li et al.
Summary: This study focuses on the design of a dual-layer solid electrolyte interface using lithium difluoro(oxalato)borate as the main salt, which has been successfully applied in phosphate ester/ether mixed electrolytes to improve the safety and reversibility of lithium metal batteries.
ENERGY STORAGE MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Longsheng Cao et al.
Summary: The study introduces an aqueous zinc battery with a solid-electrolyte interphase that enables excellent performance in various tests, demonstrating its potential for practical applications in energy storage.
NATURE NANOTECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Zehai Chen et al.
Summary: Arginine (Arg) can inhibit irregular zinc dendrite growth and induce uniform zinc deposition, significantly improving the cycle life of aqueous zinc-ion batteries. The arginine cations (Arg(+)) increase the overpotential for zinc dendrite nucleation and result in uniform zinc deposition.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Cong Huang et al.
Summary: The research shows that saccharin (Sac) as an electrolyte additive can regulate the electrical double layer (EDL) structure on the zinc anode, forming a unique solid electrolyte interphase (SEI) that effectively modulates zinc deposition behavior and prevents side reactions, thus improving battery performance.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Multidisciplinary
Ming Li et al.
Summary: This study comprehensively summarizes the role of water molecules in rechargeable aqueous zinc-ion batteries, focusing on the influencing mechanisms from various perspectives. It also proposes new insights and actionable methods for the potential future directions in the design of high-performance AZIBs.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Min Du et al.
Article
Chemistry, Physical
Xu Liu et al.
ACS ENERGY LETTERS
(2020)
Article
Chemistry, Physical
Yang Dong et al.
ACS APPLIED ENERGY MATERIALS
(2020)
Article
Electrochemistry
CH Zhen et al.
ELECTROCHIMICA ACTA
(2004)
