Journal
PROCESSES
Volume 11, Issue 11, Pages -Publisher
MDPI
DOI: 10.3390/pr11113224
Keywords
CO2 sequestration; deep coal seams; numerical simulation; effective stress; mechanical property
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This study investigates the effect of stress conditions on the mechanical properties of coal during CO2 sequestration. The results show that coal strength increases with increasing confining pressure, but this effect diminishes with higher confining pressures. The critical confining pressure is determined to be approximately 20 MPa, at which all samples exhibit similar failure strength. The application of high-pressure super-critical CO2 can strengthen the coal.
Deep coal seams are generally preferred for CO2 sequestration, during which the saturation fluids and high-stress condition involved can significantly alter the mechanical attributes of coal. To understand the effect of stress conditions on the mechanical properties of coal during CO2 sequestration, a finite element model was developed and subsequently validated using experimental data. The results indicate that coal strength increases from 10.35% for a 5 MPa CO2-saturated sample to 114.54% for an 8 MPa CO2 + water-saturated sample as the confining pressure rises from 0 to 30 MPa, due to reduced porosity. However, this effect diminishes with higher confining pressures as dilation decreases. The critical confining pressure determined in this study is approximately 20 MPa, at which all samples exhibit similar failure strength (around 48.50 MPa). Moreover, the strengthening effect caused by applied stress is especially pronounced in CO2-saturated samples, particularly in those saturated with super-critical CO2 and CO2 + water. This suggests that the reduction in coal strength resulting from the adsorption of saturation fluids can be counterbalanced by the strength gain resulting from applied stress. The aforementioned results highlight the effectiveness of injecting high-pressure super-critical CO2 into deep coal seams for carbon sequestration purposes.
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