4.8 Review

Laser-Carbonization - A Powerful Tool for Micro-Fabrication of Patterned Electronic Carbons

Journal

ADVANCED MATERIALS
Volume 35, Issue 38, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202211054

Keywords

antennas; electrocatalysis; laser-carbonization; microelectronics; sensors; supercapacitors

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This article introduces laser-assisted carbonization as a tool for fabricating functional carbon-based materials for flexible device applications. By using laser carbonization, carbon materials with specific properties can be synthesized with precision and selectivity, and the preparation time is relatively short. The article also discusses the fundamentals of laser carbonization and its applications in fields such as sensor electrodes, electrocatalysts, energy storage, and antennas.
Fabricating electronic devices from natural, renewable resources is a common goal in engineering and materials science. In this regard, carbon is of special significance due to its biocompatibility combined with electrical conductivity and electrochemical stability. In microelectronics, however, carbon's device application is often inhibited by tedious and expensive preparation processes and a lack of control over processing and material parameters. Laser-assisted carbonization is emerging as a tool for the precise and selective synthesis of functional carbon-based materials for flexible device applications. In contrast to conventional carbonization via in-furnace pyrolysis, laser-carbonization is induced photo-thermally and occurs on the time-scale of milliseconds. By careful selection of the precursors and process parameters, the properties of this so-called laser-patterned carbon (LP-C) such as porosity, surface polarity, functional groups, degree of graphitization, charge-carrier structure, etc. can be tuned. In this critical review, a common perspective is generated on laser-carbonization in the context of general carbonization strategies, fundamentals of laser-induced materials processing, and flexible electronic applications, like electrodes for sensors, electrocatalysts, energy storage, or antennas. An attempt is made to have equal emphasis on material processing and application aspects such that this emerging technology can be optimally positioned in the broader context of carbon-based microfabrication.

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