Engineering bifunctional Pd/CeNbTiOx catalyst for the simultaneous removal of NO and CO under oxygen-rich conditions at low temperature

The simultaneous elimination of CO and NO has practical significance for the control of air pollutants in the flue gas operating temperature range of 240-320 degrees C. CeNbTiOx catalyst was prepared by evaporation-induced self-assembly method (EISA), and the 0.3 % Pd/CeNbTiOx catalyst was obtained by appropriate Pd anchoring at the defects of CeNbTiOx. CO and NO removal efficiency were above 90 % from 240 to 320 degrees C, which exhibited satisfactory N-2 selectivity. The CO and NO removal efficiency of the 0.3 % Pd/CeNbTiOx catalyst exceeded 92 % during stability and water resistance. O-alpha and O-beta were involved in the oxidation of NO and CO, respectively, promoting the fast SCR and CO oxidation reaction within the ordered mesoporous of the 0.3 % Pd/CeNbTiOx catalyst. In addition, the efficiency of CO and NO elimination had been further improved due to the enhancement of defects after resistance of H2O. Therefore, this work provided a new and efficient way to control CO and NO by the efficient using of oxygen species.

Automated summary

The simultaneous elimination of CO and NO was achieved using CeNbTiOx catalyst and 0.3% Pd/CeNbTiOx catalyst, showing high removal efficiency and stability within the temperature range of 240-320 degrees C.