4.7 Review

Advances in Hole Transport Materials for Layered Casting Solar Cells

Related references

Note: Only part of the references are listed.
Article Optics

Perovskite solar cells based on spiro-OMeTAD stabilized with an alkylthiol additive

Xu Liu et al.

Summary: This study presents a facile approach for doping spiro-OMeTAD hole-transport materials using a low-cost alkylthiol additive DDT. The incorporation of DDT allows for a more efficient and controllable doping process with reduced duration. Coordination between DDT and LiTFSI increases the dopant concentration, enhances the structural integrity of the material, and improves device performance under wetting, heat, and light stress.

NATURE PHOTONICS (2023)

Article Chemistry, Physical

Spiro-OMeTAD versus PTAA for single-walled carbon nanotubes electrode in perovskite solar cells

Bo-Wen Zhang et al.

Summary: Poly(triarylamine) (PTAA)-wrapped single-walled carbon nanotubes (SWCNTs) served as both an efficient hole-transporting layer and electrode in perovskite solar cells (PSCs). The dopant-free PTAA used in this dual-role SWCNTs electrode resulted in a well-matched energy level, increased hole-transporting mobility, and hydrophobicity, leading to improved efficiency and stability compared to reference standards using LiTFSI-doped Spiro-OMeTAD. This dopant-free PTAA-applied SWCNTs electrode not only enables efficient utilization of SWCNTs electrodes in PSCs, but also reveals the mechanism of interaction between the hole-transporting layer and SWCNTs.

CARBON (2023)

Article Materials Science, Multidisciplinary

A CuxS/GO composite hole transport layer for photovoltaic performance enhancement on CuInS2 quantum dot-sensitized solar cells

Zhuoyin Peng et al.

Summary: In this study, a CuxS/GO composite hole transport layer is used to modulate the charge transfer efficiency of quantum dot-sensitized solar cells. The introduction of the CuxS/GO composite layer significantly reduces the normalized PL intensity of TiO2/CuInS2 photo-electrodes, indicating excellent charge separation properties. The charge recombination traps are also reduced under the CuxS/GO composite layer, leading to an effective improvement in the charge transfer efficiency of the solar cells. As a result, TiO2/CuInS2 quantum dot-sensitized solar cells with the CuxS/GO composite layer exhibit higher V-oc, FF and J(sc) values, resulting in an enhancement of the photovoltaic conversion efficiency from 4.85% to 6.07%.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2023)

Article Polymer Science

Solution-processed Molybdenum Oxide Hole Transport Layer Stabilizes Organic Solar Cells

Yan-Fu Liu et al.

Summary: In this study, a stable and low-cost molybdenum oxide hole transport layer (HTL) was prepared by adjusting the state of the precursor solution using an oxidant. The MoOx HTL showed good efficiency, applicability, and stability in organic solar cells.

CHINESE JOURNAL OF POLYMER SCIENCE (2023)

Article Energy & Fuels

Controlling of Conductivity and Morphological Properties of Hole-Transport Layer Using Ionic Liquid for Vacuum-Free Planar Hybrid Solar Cells

Viet Thanh Hau Pham et al.

Summary: In this study, the effects of using a 1-butyl-3-methylimidazolium chloride (BMIM+Cl-) ionic liquid on the conductivity and morphological properties of the hole-transport layer (HTL) made of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) films were investigated. The conductivity of the acidic PEDOT:PSS film was decreased, while the conductivity of the pH-neutral PEDOT:PSS film was increased. The surface morphology of the pH-neutral PEDOT:PSS film slightly changed, while the surface morphology of the acidic PEDOT:PSS film remained relatively unchanged. Vacuum-free planar hybrid solar cells using the pH-neutral PEDOT:PSS film showed higher power conversion efficiency compared to those using the acidic PEDOT:PSS film.

ENERGIES (2023)

Review Crystallography

The Use of Crystalline Carbon-Based Nanomaterials (CBNs) in Various Biomedical Applications

Maria-Anna Gatou et al.

Summary: This review study presents the significance of crystalline carbon-based nanomaterials in biomedical applications. These nanomaterials, including graphene, graphene oxide, reduced graphene oxide, carbon nanotubes, and graphene quantum dots, have emerged as promising materials for medical device development in various biomedical applications. Their unique properties allow for efficient interaction with biomolecules and enhanced light responses, offering promising opportunities for advancements in biomedicine.

CRYSTALS (2023)

Editorial Material Chemistry, Physical

Are Perovskite Solar Cells Reaching the Efficiency and Voltage Limits?

Gaabor Szabo et al.

ACS ENERGY LETTERS (2023)

Review Chemistry, Multidisciplinary

Advances in organic photovoltaic cells: a comprehensive review of materials, technologies, and performance

Ebru Kondolot Solak et al.

Summary: This paper provides a comprehensive overview of organic photovoltaic (OPV) cells, covering their materials, technologies, and performance. It explores the historical evolution and classification of PV cell technology, as well as a comparative analysis of different solar cell generations. The working principles, device structures, and performance of OPV cells are examined, along with the challenges and opportunities associated with the technology. The paper concludes by suggesting future research directions to improve the efficiency and address the identified challenges of OPV cells.

RSC ADVANCES (2023)

Article Nanoscience & Nanotechnology

Interfacial Engineering of PTAA/Perovskites for Improved Crystallinity and Hole Extraction in Inverted Perovskite Solar Cells

Yang Li et al.

Summary: Inverted perovskite solar cells have gained increasing research interest, but the hydrophobic property of the commonly used hole-transporting layer material PTAA hinders the growth of high-quality perovskite films. This study employs a donor-acceptor-donor type organic molecule M2 to modify the surface of PTAA, improving its hydrophobic property and enhancing hole mobility and conductivity. With the modified PTAA/M2 as the hole transport layer, the efficiency and stability of inverted PSCs are improved.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Materials Science, Multidisciplinary

Solvent influenced morphology control of hole transport layer of CuSCN on performance of organic solar cells

Neeraj Chaudhary et al.

Summary: The research focuses on the solution-processable deposition of copper(I) thiocyanate (CuSCN) as the hole transport layer (HTL) in solar cells. Different solvents were used to deposit CuSCN as HTL and their effects on the morphology of HTL and device performance were studied. Two efficient solvents, DMF and DMSO, were identified for solution-processable deposition with efficiencies of 4.56% and 4.28%, respectively. These findings provide new approaches for obtaining higher photovoltaic performance and alternative solvents in the fabrication of solution-processable devices in various solar cells.

MATERIALS CHEMISTRY AND PHYSICS (2022)

Article Optics

Large-area perovskite solar cells employing spiro-Naph hole transport material

Mingyu Jeong et al.

Summary: By utilizing a symmetry-tuned strategy at the molecular level, we have developed a new class of spiro-Naph analogues as the hole transport material in perovskite solar cells, resulting in improved stability and power conversion efficiency.

NATURE PHOTONICS (2022)

Review Chemistry, Physical

Review on Graphene-, Graphene Oxide-, Reduced Graphene Oxide-Based Flexible Composites: From Fabrication to Applications

Aamir Razaq et al.

Summary: This paper provides a comprehensive review of the recent progress in the synthesis and applications of graphene-based composites in the field of flexible devices. It also highlights the difficulties and challenges in the development of graphene, serving as a valuable reference for further innovation.

MATERIALS (2022)

Review Chemistry, Multidisciplinary

Recent Advances in Hole-Transporting Layers for Organic Solar Cells

Cinthya Anrango-Camacho et al.

Summary: This review examines the recent advancements in metal oxides, metal sulfides, nanocarbon materials, conducting polymers, and small organic molecules as hole transporting layers (HTLs) in organic solar cells (OSCs) over the past five years. The preparation and deposition methods of HTLs have been optimized, and strategies such as doping, composite/hybrid formation, and modifications have been utilized to tune the optical/electrical properties of these materials for efficient and stable OSCs.

NANOMATERIALS (2022)

Article Chemistry, Physical

Suppressing PEDOT:PSS Doping-Induced Interfacial Recombination Loss in Perovskite Solar Cells

Yi-Chun Chin et al.

Summary: PEDOT: PSS is widely used in perovskite solar cells as a hole transport layer due to its processability, scalability, and commercialization potential. However, PSCs utilizing PEDOT: PSS suffer from recombination losses. In this study, dedoping PEDOT: PSS and optimizing its layer thickness improved the device's performance by reducing recombination losses at the interface.

ACS ENERGY LETTERS (2022)

Article Chemistry, Physical

Tandem Organic Solar Cell with 20.2% Efficiency

Zhong Zheng et al.

Summary: A advanced interconnecting layer for tandem organic solar cell is developed in this study. By controlling the O-2 flux during evaporation, efficient electron extraction and low Schottky barrier are obtained, enabling effective charge recombination between two subcells. The tandem cell with the interconnecting layer shows a high efficiency of 20.27%.

JOULE (2022)

Article Energy & Fuels

Multistrategy Toward Highly Efficient and Stable CsPbI2Br Perovskite Solar Cells Based on Dopant-Free Poly(3-Hexylthiophene)

Jing Song et al.

Summary: The study demonstrated a multi-strategy approach to optimize CsPbI2Br perovskite solar cells, achieving high efficiency and long-term stability by enhancing phase stability and passivating film defects.

SOLAR RRL (2022)

Article Chemistry, Multidisciplinary

Triarylamine/Bithiophene Copolymer with Enhanced Quinoidal Character as Hole-Transporting Material for Perovskite Solar Cells

Hao-Sheng Lin et al.

Summary: Polytriarylamine, a popular hole-transporting material in solar cells, has suboptimal conductivity and recombination at the interface. By inserting a bithiophene unit between two triarylamine units, the conjugation and performance of the material are improved, resulting in high efficiency solar cells.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Engineering, Environmental

Photoconductive NiOx hole transport layer for efficient perovskite solar cells

Xiaoyan Zhao et al.

Summary: This study proposes a photoconductive NiOx-Pc hole transport layer in perovskite solar cells (PSCs) by combining with phthalocyanine (Pc) to improve the conductivity of NiOx film. The experimental results show that the conductivity of NiOx-Pc film significantly increases, leading to improved efficiency and stability of PSCs.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Energy & Fuels

Development of MXene/WO3 embedded PEDOT:PSS hole transport layers for highly efficient perovskite solar cells and X-ray detectors

Sajjad Hussain et al.

Summary: In this study, a simple solution process was used to decorate WO3 nanoparticles on 2D conductive Ti3C2TX MXene sheets, forming MXene/WO3 hybrid structure, which was applied for the first time as the hole transport layer (HTL) in perovskite solar cells and X-ray detectors. The results showed that the perovskite solar cell with MXene/WO3/PEDOT: PSS HTL achieved a high power conversion efficiency, while the X-ray photodetector with MXene/WO3 blended HTL device exhibited superior sensitivity. The research findings revealed that the MXene/WO3 heterostructure effectively tuned the HTL/perovskite interface, facilitating charge extraction and shortest charge carrier lifetime.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

Review Engineering, Electrical & Electronic

A Critical Review of the Role of Carbon Nanotubes in the Progress of Next-Generation Electronic Applications

Rajalakshmi Maheswaran et al.

Summary: This paper reviews the application and advantages of carbon nanotubes (CNTs) in electronic products, including biosensing, energy storage, and data storage devices. It also discusses the research progress of CNT-based field emission devices and the challenges and future development of CNT-based electronics.

JOURNAL OF ELECTRONIC MATERIALS (2022)

Article Chemistry, Multidisciplinary

Performance Analysis and Optimization of a PBDB-T:ITIC Based Organic Solar Cell Using Graphene Oxide as the Hole Transport Layer

Ghazi Aman Nowsherwan et al.

Summary: This study investigates the use of graphene oxide as a replacement for the conventional hole transport layer in organic solar cells. The results show that graphene oxide can improve the performance of the cells and overcome stability issues. By comparing different absorber layers, it is found that PBDB-T:ITIC performs the best when paired with graphene oxide as the hole transport layer.

NANOMATERIALS (2022)

Article Energy & Fuels

High-Efficiency P3HT-Based All-Polymer Solar Cells with a Thermodynamically Miscible Polymer Acceptor

Youle Li et al.

Summary: This study reports highly efficient all-polymer solar cells based on P3HT by blending it with a thermodynamically miscible polymer acceptor. The well-mixed fibrillary active layer morphology generated by the blend leads to a record power conversion efficiency of 7.35% for P3HT-based all-PSCs.

SOLAR RRL (2022)

Article Materials Science, Multidisciplinary

Comparative study of hole transporting layers commonly used in high-efficiency perovskite solar cells

Divya Sharma et al.

Summary: This review paper provides a detailed overview of various hole transport materials used in perovskite solar cells and discusses their impact on the performance of the cells. By elucidating the advantages and disadvantages of different materials and their categorization, it serves as a reference for further research and application.

JOURNAL OF MATERIALS SCIENCE (2022)

Article Multidisciplinary Sciences

Constructing molecular bridge for high-efficiency and stable perovskite solar cells based on P3HT

Dongdong Xu et al.

Summary: In this study, a molecular bridge is constructed to improve the poor contact and severe recombination at the P3HT/perovskite interface, resulting in significantly enhanced efficiency of perovskite solar cells. Furthermore, using MDN as the hole transport material also improves the long-term stability of the devices.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

Enhanced Efficiency and Stability of n-i-p Perovskite Solar Cells by Incorporation of Fluorinated Graphene in the Spiro-OMeTAD Hole Transport Layer

Qiang Lou et al.

Summary: The efficiency and stability of perovskite solar cells can be significantly enhanced by adding fluorinated graphene into the hole transport layer, improving hole mobility and reducing lithium ion content.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Multidisciplinary

Organic Solar Cell With Efficiency Over 20% and VOC Exceeding 2.1 V Enabled by Tandem With All-Inorganic Perovskite and Thermal Annealing-Free Process

Xiaoyu Gu et al.

Summary: This study demonstrates a 2-terminal monolithic perovskite/organic tandem solar cell (TSC) configuration, which incorporates wide bandgap all-inorganic perovskites as front cell absorber and organic blend as rear cell absorber, to extend the absorption range of organic solar cells (OSCs) into high-energy photon region. By optimizing the electron transporting layer and interface structure, high open-circuit voltage and charge transport efficiency are achieved. The remarkable power conversion efficiency (PCE) obtained in this study highlights the potential of this strategy to improve the efficiency of OSCs.

ADVANCED SCIENCE (2022)

Article Nanoscience & Nanotechnology

Cu2SnS3 Nanocrystal-Based Hole-Transport Layer for Carbon Electrode-Based Perovskite Solar Cells

Zhen Yu et al.

Summary: In this study, the potential of Cu2SnS3 nanocrystals as hole-transport layers in perovskite solar cells is evaluated for the first time. The results show that the Cu2SnS3 hole-transport layer can improve the power conversion efficiency of the cells and suppress charge carrier recombination.

ACS APPLIED NANO MATERIALS (2022)

Article Chemistry, Physical

Hydrogen bonding drives the self-assembling of carbazole-based hole-transport material for enhanced efficiency and stability of perovskite solar cells

Cheng Wang et al.

Summary: Designing a hole-transport material that self-assembles at the perovskite-HTM interface with the formation of an ordered interlayer has emerged as a promising strategy for high-performance and stable perovskite solar cells. This study demonstrates the advantages of a novel HTM design that can self-assemble into a long-range ordered interlayer via hydrogen bonding, leading to enhanced hole extraction reaction, suppressed interfacial charge recombination, and increased power conversion efficiency and stability.

NANO ENERGY (2022)

Article Nanoscience & Nanotechnology

High-Performance Indium-Tin Oxide (ITO) Electrode Enabled by a Counteranion-Free Metal-Polymer Complex

Gyeongbae Park et al.

Summary: This study achieved the preparation of high-performance transparent conducting oxides (TCOs) through the removal of counteranions in the solution and accurate acid-base titration, with Sn-doped In-2 Omega(3) (ITO) film being the most representative.

ACS NANOSCIENCE AU (2022)

Review Engineering, Electrical & Electronic

Recent progress in solution-processed flexible organic photovoltaics

Lulu Sun et al.

Summary: This review summarizes recent progress in solution-processed flexible organic photovoltaics (OPV), focusing on the behavior of narrow bandgap small-molecule acceptors and wide bandgap polymer donor active layer, as well as discussing the existing challenges and future directions.

NPJ FLEXIBLE ELECTRONICS (2022)

Article Materials Science, Multidisciplinary

CuSCN as a hole transport layer in an inorganic solution-processed planar Sb2S3 solar cell, enabling carbon-based and semitransparent photovoltaics

Pankaj Kumar et al.

Summary: Sb2S3 is an emerging inorganic photovoltaic absorber material with attractive properties. The use of CuSCN as a hole transport layer in Sb2S3 solar cells has shown high power conversion efficiencies and semitransparency.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Chemistry, Multidisciplinary

How varying surface wettability of different PEDOT:PSS formulations and their mixtures affects perovskite crystallization and the efficiency of inverted perovskite solar cells

Zekarias Teklu Gebremichael et al.

Summary: This study investigated the impact of three commercially available PEDOT:PSS formulations and three mixtures as HTLs on the crystallization of perovskite films and the performance of associated PSCs. The results showed that PEDOT:PSS PH exhibited the best crystallization and solar cell performance. PSCs using mixed PEDOT:PSS as HTLs showed higher fill factor and open-circuit voltage values. This mixing strategy can potentially lead to the development of PEDOT:PSS combinations with tunable properties.

RSC ADVANCES (2022)

Article Chemistry, Multidisciplinary

Novel dopant-free hole transport materials enabling 20.9% efficiency in perovskite solar cells

Xinxing Yin et al.

Summary: Two new donor-acceptor-donor (D-A-D) type dopant-free hole transport materials (HTMs), named BDD-T and BTT-T, were developed and successfully applied in perovskite solar cells, achieving an impressive power conversion efficiency (PCE) of 20.9%.

CHEMICAL COMMUNICATIONS (2022)

Review Green & Sustainable Science & Technology

Analytical Review of Spiro-OMeTAD Hole Transport Materials: Paths Toward Stable and Efficient Perovskite Solar Cells

Laxmi Nakka et al.

Summary: This article discusses the importance of hole transport materials (HTM) in organic-inorganic perovskite solar cells (PVSCs), focusing on the most widely used HTM material, spiro-OMeTAD. It provides an overview of the synthesis, properties, and strategies for improving the efficiency and stability of spiro-OMeTAD-based PVSCs.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2022)

Article Materials Science, Multidisciplinary

Interface compatibility: how to outperform classical spiro-OMeTAD in perovskite solar cells with carbazole derivatives

Zeinab Kadi et al.

Summary: The efficiency and stability of perovskite solar cells can be improved by optimizing the interface layer and hole transport material compatibility. A polymer interface layer based on PV(Cz-DMPA) has been used to engineer the perovskite/HTM interface, reducing trap state density and improving charge extraction. Chemically compatible carbazole-based HTMs, Cz-P and Cz-Pyr, have been selected to enhance IL/HTM interactions, resulting in significantly improved device performance.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Review Chemistry, Multidisciplinary

Graphene and its derivatives: understanding the main chemical and medicinal chemistry roles for biomedical applications

Tais Monteiro Magne et al.

Summary: The review addresses the growing potential use of graphene and its derivatives in various biomedical areas, with particular focus on cancer therapy and diagnosis. The different physicochemical properties of graphene and its derivatives dictate their biocompatibility and toxicity, requiring further research to explain their interactions with biological systems. Despite the increasing studies on the bioavailability and toxicity of graphene and its derivatives, there is still much to be unveiled to develop safe and effective formulations.

JOURNAL OF NANOSTRUCTURE IN CHEMISTRY (2022)

Review Engineering, Electrical & Electronic

Review on applications of PEDOTs and PEDOT:PSS in perovskite solar cells

Yijie Xia et al.

Summary: PEDOT:PSS is a successful conducting polymer with wide applications in perovskite solar cells, where approaches to modifying the PEDOT:PSS layer have been explored to enhance device performance. The review highlights the latest advances in perovskite solar cells utilizing PEDOT:PSS.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

Article Engineering, Electrical & Electronic

Carbazole-based material: synthesis, characterization, and application as hole transporting material in perovskite solar cells

Diego Magaldi et al.

Summary: A novel oligomeric cyclic carbazole-based material PCz1 was synthesized and characterized for application as a hole transporter in hybrid perovskite photovoltaic devices. Preliminary application in mixed perovskite solar cells showed comparable power conversion efficiency to Spiro-OMeTAD reference cells, and the novel HTM effectively protected the perovskite surface, resulting in highly stable PSC devices.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2021)

Article Chemistry, Multidisciplinary

Intramolecular Electric Field Construction in Metal Phthalocyanine as Dopant-Free Hole Transporting Material for Stable Perovskite Solar Cells with >21 % Efficiency

Zefeng Yu et al.

Summary: Ni phthalocyanine (NiPc)with methoxyethoxy units as HTMs showed improved conductivity and hole mobility in PSCs, achieving a record efficiency of 21.23%. The extracted holes in NiPc are mainly concentrated on the phthalocyanine core and transferred between molecules, demonstrating good stability in moisture, heating, and light.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Multidisciplinary Sciences

Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes

Hanul Min et al.

Summary: By introducing an interlayer between the electron-transporting and perovskite layers in perovskite solar cells, researchers have successfully enhanced charge extraction and transport from the perovskite, leading to higher power conversion efficiency and fewer interfacial defects. The coherent interlayer allowed the fabrication of devices with a certified efficiency of 25.5%, which maintained about 90% of its initial efficiency even after continuous light exposure for 500 hours. The findings provide guidelines for designing defect-minimizing interfaces in metal halide perovskites and electron-transporting layers.

NATURE (2021)

Article Energy & Fuels

Influence of donor units on spiro[fluorene-9,9′-xanthene]-based dopant-free hole transporting materials for perovskite solar cells

Yajie Fu et al.

Summary: Three spiro[fluorene-9,9'-xanthene] (SFX)-based organic molecules with different donor units were synthesized and utilized as dopant-free hole-transport materials (HTMs) in perovskite solar cells (PSCs). The PSCs based on SFX-2CZ achieved the highest power conversion efficiency (PCE), while SFX-4CZ exhibited the lowest efficiency due to its inferior film forming ability. This study provides insights into the design of efficient HTMs based on SFX core with considerations of molecular planarity and number of donor groups.

SOLAR ENERGY (2021)

Article Chemistry, Physical

Modified P3HT materials as hole transport layers for flexible perovskite solar cells

Francesca De Rossi et al.

Summary: A new method of modifying P3HT hole-transporting materials by adding BTD groups has been proposed, which improves long-term stability while maintaining efficiency, showing great potential for application.

JOURNAL OF POWER SOURCES (2021)

Review Materials Science, Multidisciplinary

A brief review of hole transporting materials commonly used in perovskite solar cells

Song Li et al.

Summary: Perovskite solar cells (PSCs) have gained significant attention in the field of photovoltaics due to their exceptional performance, with the power conversion efficiency reaching up to 25.2%. This review focuses on discussing various hole transporting materials (HTMs) in PSCs, emphasizing their role in improving photovoltaic performance. Different organic and inorganic HTMs are categorized and their advantages and disadvantages are demonstrated, with the aim of providing insights for the design and application of novel HTMs to further enhance PSCs performance.

RARE METALS (2021)

Article Polymer Science

Polyaniline/Reduced Graphene Oxide Composites for Hole Transporting Layer of High-Performance Inverted Perovskite Solar Cells

Jae Woong Jung et al.

Summary: The study demonstrates that the polyaniline composite film has enhanced electrical conductivity and suitable energy level matching with CH3NH3PbI3 to improve the photovoltaic properties of the device. The composite film-based devices achieved a maximum efficiency of 16.61%, which is 21.6% higher than the device with pristine polyaniline. Additionally, the reduced graphene oxide-based composite film showed superior long-term stability compared to the pristine polyaniline-based device, indicating great potential for high performance perovskite solar cells.

POLYMERS (2021)

Article Chemistry, Physical

Multifunctional Two-Dimensional Conjugated Materials for Dopant-Free Perovskite Solar Cells with Efficiency Exceeding 22%

Qiang Fu et al.

Summary: In this study, a solution-processable two-dimensional polymer HTM called 2DP-TDB with extended pi-electron delocalization was successfully developed for perovskite solar cells. The PSCs incorporating 2DP-TDB as dopant-free HTM showed a high efficiency of 22.17% after further optimization of the perovskite film, demonstrating the potential of 2D conjugated polymer HTMs for high-efficiency and stable PSCs.

ACS ENERGY LETTERS (2021)

Article Materials Science, Multidisciplinary

Copper nanoparticle-decorated RGO electrodes as hole transport layer of perovskite solar cells enhancing efficiency and shelf stability

Mohamed S. Soltan et al.

Summary: The addition of Cu@RGO as a hole transport layer in PSCs improved the photoconversion efficiency, outperforming Ag@RGO and pure RGO, and exhibited good shelf stability.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2021)

Review Chemistry, Multidisciplinary

Recent progress in metal sulfide-based electron transport layers in perovskite solar cells

Zhen He et al.

Summary: High-quality electron transport layers (ETLs) made of metal sulfides (MSs) are essential for stable and efficient perovskite solar cells (PSCs). The quality of MS films plays a crucial role in the photovoltaic performance of PSCs, but there is a lack of focus on the preparation, characteristics, and mechanisms of MS-based ETLs. This review aims to summarize MS-based ETLs and their preparation strategies, hoping to provide insights for further research in this area.

NANOSCALE (2021)

Review Chemistry, Multidisciplinary

Lessons learned from spiro-OMeTAD and PTAA in perovskite solar cells

Florine M. Rombach et al.

Summary: Organic semiconductors are crucial in thin-film electronic devices, especially as hole transport layers (HTLs) in perovskite solar cells (PSCs). Spiro-OMeTAD and PTAA have been the leading materials for high efficiency HTLs, with research on their properties contributing to a better understanding of their success mechanisms. This review provides key insights into the electronic and morphological properties, doping strategies, and degradation pathways of spiro-OMeTAD and PTAA, guiding the development of future HTL materials with improved stability and efficiency for PSCs.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Materials Science, Multidisciplinary

Efficient hole transport layers based on cross-linked poly(N-vinylcarbazole) for high-performance perovskite photodetectors

Lijuan He et al.

Summary: A novel HTL material PVK doped with F4TCNQ was explored in this study and introduced in p-i-n type OIHP photodetectors for improved device performance; non-wetting PVK HTL leads to larger perovskite grains, while F4TCNQ assists hole transport and reduces carrier recombination.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

Review Green & Sustainable Science & Technology

Recent Developments in Organic Tandem Solar Cells toward High Efficiency

Fateh Ullah et al.

Summary: The development of organic tandem solar cells (OTSCs) has shown inspiring breakthroughs in efficiency and absorption losses reduction, providing new dimensions for sustainable electronic technologies. Recent advancements in OTSCs, including design rules, interconnecting layer implementation, and utilization of photoactive materials, are comprehensively described to offer insights for future development.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Review Chemistry, Physical

Advanced research trends in dye-sensitized solar cells

Mikko Kokkonen et al.

Summary: This paper reviews the recent progress in DSSC research to achieve high photovoltaic efficiency and performance stability under typical indoor conditions by developing new device structures, alternative redox shuttles, solid-state hole conductors, TiO2 photoelectrodes, catalyst materials, and sealing techniques. It proposes a scalable cell fabrication process that integrates these developments to a new monolithic cell design based on several features. Finally, the need to design new stability testing protocols to assess the probable deployment of DSSCs in portable electronics and internet-of-things devices is discussed.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Physical

An efficacious multifunction codoping strategy on a room-temperature solution-processed hole transport layer for realizing high-performance perovskite solar cells

Dan Ouyang et al.

Summary: This study demonstrates a novel room-temperature solution-processed Li and Cu co-doped NiOx nanoparticle-based hole transport layer, which improves electrical conductivity, optical transmittance, and facilitates the formation of high-quality perovskite films. With these multiple functions, the PSCs utilizing Li and Cu co-doped NiOx HTLs achieved high efficiencies on both rigid and flexible substrates.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Energy & Fuels

Metal oxide charge transport layers in perovskite solar cells-optimising low temperature processing and improving the interfaces towards low temperature processed, efficient and stable devices

Yantao Wang et al.

Summary: This review focuses on recent progress in metal oxide charge transport layers in perovskite solar cells, particularly on achieving high efficiency devices under mild deposition conditions. The research includes applications of metal oxides above and below the perovskite layer, various approaches to improve device performances, and commonly employed characterization techniques.

JOURNAL OF PHYSICS-ENERGY (2021)

Article Nanoscience & Nanotechnology

Improved Efficiency of Perovskite Solar Cells Using a Nitrogen-Doped Graphene-Oxide-Treated Tin Oxide Layer

Ji A. Hong et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Energy & Fuels

Nickel sulphide nano-composite assisted hole transport in thin film polymer solar cells

Mohammed S. G. Hamed et al.

SOLAR ENERGY (2020)

Article Nanoscience & Nanotechnology

Nature and origin of unusual properties in chemically exfoliated 2D MoS2

Debasmita Pariari et al.

APL MATERIALS (2020)

Review Polymer Science

Polycarbazole and its derivatives: progress, synthesis, and applications

V Nayana et al.

JOURNAL OF POLYMER RESEARCH (2020)

Article Energy & Fuels

CuSx hole transport layer for PbS quantum dot solar cell

Jinhuan Li et al.

SOLAR ENERGY (2020)

Article Energy & Fuels

Light-induced improvement of dopant-free PTAA on performance of inverted perovskite solar cells

Zahra Bagheri et al.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2020)

Review Materials Science, Multidisciplinary

A Systematic Review of Metal Oxide Applications for Energy and Environmental Sustainability

Mir Sayed Shah Danish et al.

METALS (2020)

Article Chemistry, Multidisciplinary

Impacts of the Hole Transport Layer Deposition Process on Buried Interfaces in Perovskite Solar Cells

Shen Wang et al.

CELL REPORTS PHYSICAL SCIENCE (2020)

Article Nanoscience & Nanotechnology

Improving stability of organometallic-halide perovskite solar cells using exfoliation two-dimensional molybdenum chalcogenides

Meiying Liang et al.

NPJ 2D MATERIALS AND APPLICATIONS (2020)

Article Chemistry, Multidisciplinary

A hole-transport material that also passivates perovskite surface defects for solar cells with improved efficiency and stability

By Xiaoming Zhao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Materials Science, Multidisciplinary

Liquid phase exfoliation of MoS2 and WS2 in aqueous ammonia and their application in highly efficient organic solar cells

Begimai Adilbekova et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

Article Materials Science, Multidisciplinary

Carbon-based HTL-free modular perovskite solar cells with improved contact at perovskite/carbon interfaces

Ransheng Chen et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

Review Chemistry, Physical

Hole transport layers for organic solar cells: recent progress and prospects

Haitao Xu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Materials Science, Multidisciplinary

Recent progresses and challenges of metal sulfides as advanced anode materials in rechargeable sodium-ion batteries

Xu Yang et al.

JOURNAL OF PHYSICS-MATERIALS (2020)

Article Multidisciplinary Sciences

Efficient, stable and scalable perovskite solar cells using poly(3-hexylthiophene)

Eui Hyuk Jung et al.

NATURE (2019)

Article Nanoscience & Nanotechnology

Hole-Transport Layer Molecular Weight and Doping Effects on Perovskite Solar Cell Efficiency and Mechanical Behavior

Inhwa Lee et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Physical

Rapid Charge-Transfer Cascade through SWCNT Composites Enabling Low-Voltage Losses for Perovskite Solar Cells

Severin N. Habisreutinger et al.

ACS ENERGY LETTERS (2019)

Article Materials Science, Multidisciplinary

Achieving efficient inverted planar perovskite solar cells with nondoped PTAA as a hole transport layer

Qian Zhao et al.

ORGANIC ELECTRONICS (2019)

Article Chemistry, Multidisciplinary

Mg Doped CuCrO2 as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells

Boya Zhang et al.

NANOMATERIALS (2019)

Review Chemistry, Physical

Tuning the work function of graphene toward application as anode and cathode

Samira Naghdi et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2019)

Article Materials Science, Multidisciplinary

Functionalized and reduced graphene oxide as hole transport layer and for use in ternary organic solar cell

Juan Nicasio-Collazo et al.

OPTICAL MATERIALS (2019)

Article Materials Science, Multidisciplinary

Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells

Heather M. Yates et al.

JOURNAL OF MATERIALS CHEMISTRY C (2019)

Article Nanoscience & Nanotechnology

Combustion,Synthesis of p-Type Transparent Conducting CuCrO2+x and Cu:CrOx Thin Films at 180 °C

Jian Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Long-Term Stability of the Oxidized Hole-Transporting Materials used in Perovskite Solar Cells

Ernestas Kasparavicius et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Article Crystallography

Growth of Highly Crystalline and Large Scale Monolayer MoS2 by CVD: The Role of substrate Position

Nand Kumar et al.

CRYSTAL RESEARCH AND TECHNOLOGY (2018)

Article Materials Science, Multidisciplinary

Nickel sulphide-carbon composite hole transporting material for (CH3NH3PbI3) planar heterojunction perovskite solar cell

Selvakumar Pitchaiya et al.

MATERIALS LETTERS (2018)

Article Nanoscience & Nanotechnology

Vertically Aligned Ultrathin 1T-WS2 Nanosheets Enhanced the Electrocatalytic Hydrogen Evolution

Qunying He et al.

NANOSCALE RESEARCH LETTERS (2018)

Article Chemistry, Physical

Understanding the Doping Effect on NiO: Toward High-Performance Inverted Perovskite Solar Cells

Wei Chen et al.

ADVANCED ENERGY MATERIALS (2018)

Article Nanoscience & Nanotechnology

Vertically Aligned Ultrathin 1T-WS2 Nanosheets Enhanced the Electrocatalytic Hydrogen Evolution

Qunying He et al.

NANOSCALE RESEARCH LETTERS (2018)

Article Chemistry, Multidisciplinary

Atomic Layer Deposited TiO2-IrOx Alloy as a Hole Transport Material for Perovskite Solar Cells

Wanliang Tan et al.

ADVANCED MATERIALS INTERFACES (2018)

Article Chemistry, Multidisciplinary

Low-Temperature Combustion Synthesis of a Spinel NiCo2O4 Hole Transport Layer for Perovskite Photovoltaics

Ioannis T. Papadas et al.

ADVANCED SCIENCE (2018)

Article Chemistry, Multidisciplinary

Novel p-dopant toward highly efficient and stable perovskite solar cells

Ji-Youn Seo et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Review Nanoscience & Nanotechnology

Dye-Sensitized Solar Cells: Fundamentals and Current Status

Khushboo Sharma et al.

NANOSCALE RESEARCH LETTERS (2018)

Article Materials Science, Multidisciplinary

MoS2 incorporated hybrid hole transport layer for high performance and stable perovskite solar cells

Dian Wang et al.

SYNTHETIC METALS (2018)

Article Chemistry, Physical

Zinc as a New Dopant for NiOx-Based Planar Perovskite Solar Cells with Stable Efficiency near 20%

Xingxing Wan et al.

ACS APPLIED ENERGY MATERIALS (2018)

Article Materials Science, Multidisciplinary

Mo(SxOy) thin films deposited by electrochemistry for application in organic photovoltaic cells

F. Martinez-Rojas et al.

MATERIALS CHEMISTRY AND PHYSICS (2017)

Article Materials Science, Multidisciplinary

Low temperature processed NiOx hole transport layers for efficient polymer solar cells

Sudam D. Chavhan et al.

ORGANIC ELECTRONICS (2017)

Article Energy & Fuels

Solution processed Cu2CdSnS4 as a low-cost inorganic hole transport material for polymer solar cells

M. Suresh Kumar et al.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2017)

Review Chemistry, Physical

Hole transporting materials for mesoscopic perovskite solar cells - towards a rational design?

Anurag Krishna et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Materials Science, Multidisciplinary

Enhanced efficiency and stability of polymer solar cells using solution processed nickel oxide as hole transport material

Shaninugam Parthiban et al.

CURRENT APPLIED PHYSICS (2017)

Article Nanoscience & Nanotechnology

Study of Arylamine-Substituted Porphyrins as Hole-Transporting Materials in High-Performance Perovskite Solar Cells

Song Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Nanoscience & Nanotechnology

Accelerated Degradation Due to Weakened Adhesion from Li-TFSI Additives in Perovskite Solar Cells

Inhwa Lee et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Chemistry, Physical

Work Function Tuning of Reduced Graphene Oxide Thin Films

Lamprini Sygellou et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

Article Nanoscience & Nanotechnology

MoS2 Quantum Dots with a Tunable Work Function for High-Performance Organic Solar Cells

Wang Xing et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Nanoscience & Nanotechnology

Solution-Processed CuS NPs as an Inorganic Hole-Selective Contact Material for Inverted Planar Perovskite Solar Cells

Haixia Rao et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Engineering, Environmental

(NH4)2WS4 precursor as a hole-injection layer in organic optoelectronic devices

Quyet Van Le et al.

CHEMICAL ENGINEERING JOURNAL (2016)

Article Chemistry, Physical

Role of the Dopants on the Morphological and Transport Properties of Spiro-MeOTAD Hole Transport Layer

Emilio J. Juarez-Perez et al.

CHEMISTRY OF MATERIALS (2016)

Article Chemistry, Multidisciplinary

Dopant-free polymeric hole transport materials for highly efficient and stable perovskite solar cells

Guan-Woo Kim et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

Article Materials Science, Multidisciplinary

Enhanced efficiency of polymer solar cells by structure-differentiated silver nano-dopants in solution-processed tungsten oxide layer

Wenfei Shen et al.

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS (2016)

Article Chemistry, Multidisciplinary

Investigation on a dopant-free hole transport material for perovskite solar cells

Fei Wu et al.

RSC ADVANCES (2016)

Article Materials Science, Multidisciplinary

Bottom-Up Synthesis of MeSx Nanodots for Optoelectronic Device Applications

Quyet Van Le et al.

ADVANCED OPTICAL MATERIALS (2016)

Article Chemistry, Physical

An aqueous solution-processed CuOX film as an anode buffer layer for efficient and stable organic solar cells

Zhikai Yu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

Article Materials Science, Multidisciplinary

Enhanced efficiency of polymer solar cells by structure-differentiated silver nano-dopants in solution-processed tungsten oxide layer

Wenfei Shen et al.

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS (2016)

Review Chemistry, Multidisciplinary

Two-dimensional transition metal dichalcogenide nanosheet-based composites

Chaoliang Tan et al.

CHEMICAL SOCIETY REVIEWS (2015)

Review Chemistry, Multidisciplinary

A comprehensive review on synthesis methods for transition-metal oxide nanostructures

Ting Guo et al.

CRYSTENGCOMM (2015)

Article Chemistry, Physical

Electronic and Optical Properties of Graphene Quantum Dots: The Role of Many-Body Effects

Yunhai Li et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

Article Chemistry, Physical

Charge Transfer Dynamics from Organometal Halide Perovskite to Polymeric Hole Transport Materials in Hybrid Solar Cells

Jan C. Brauer et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Article Chemistry, Physical

Low-Temperature and Solution-Processed Amorphous WOx as Electron-Selective Layer for Perovskite Solar Cells

Kai Wang et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

Review Chemistry, Physical

Nanocarbons for mesoscopic perovskite solar cells

Munkhbayar Batmunkh et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

Review Chemistry, Physical

Benzo[1,2-b: 4,5-b′]dithiophene (BDT)-based small molecules for solution processed organic solar cells

Miaomiao Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

Article Nanoscience & Nanotechnology

Highly Efficient Polymer-Based Optoelectronic Devices Using PEDOT:PSS and a GO Composite Layer as a Hole Transport Layer

Jae Choul Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

Article Materials Science, Ceramics

Structure, composition and properties of p-type CuCrO2 thin films

Ruei-Sung Yu et al.

CERAMICS INTERNATIONAL (2014)

Article Chemistry, Multidisciplinary

Interface energetics in organo-metal halide perovskite-based photovoltaic cells

Philip Schulz et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Article Chemistry, Multidisciplinary

o-Methoxy Substituents in Spiro-OMeTAD for Efficient Inorganic-Organic Hybrid Perovskite Solar Cells

Nam Joong Jeon et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Review Optics

The emergence of perovskite solar cells

Martin A. Green et al.

NATURE PHOTONICS (2014)

Article Materials Science, Multidisciplinary

UV/ozone-treated WS2 hole-extraction layer in organic photovoltaic cells

Quyet Van Le et al.

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS (2014)

Article Chemistry, Physical

Dual use of tantalum disulfides as hole and electron extraction layers in organic photovoltaic cells

Quyet Van Le et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Article Chemistry, Physical

The use of UV/ozone-treated MoS2 nanosheets for extended air stability in organic photovoltaic cells

Quyet Van Le et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2014)

Article Chemistry, Multidisciplinary

Solution-Processed Nickel Oxide Hole Transport Layers in High Efficiency Polymer Photovoltaic Cells

Jesse R. Manders et al.

ADVANCED FUNCTIONAL MATERIALS (2013)

Article Chemistry, Multidisciplinary

25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research

Letian Dou et al.

ADVANCED MATERIALS (2013)

Review Chemistry, Multidisciplinary

Metal dichalcogenide nanosheets: preparation, properties and applications

Xiao Huang et al.

CHEMICAL SOCIETY REVIEWS (2013)

Article Chemistry, Physical

Graphene quantum dots as the hole transport layer material for high-performance organic solar cells

Miaomiao Li et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

Article Chemistry, Physical

Single-layer MoS2 as an efficient photocatalyst

Yunguo Li et al.

CATALYSIS SCIENCE & TECHNOLOGY (2013)

Article Chemistry, Multidisciplinary

A Solution-Processed MoOx Anode Interlayer for Use within Organic Photovoltaic Devices

Jacek J. Jasieniak et al.

ADVANCED FUNCTIONAL MATERIALS (2012)

Review Chemistry, Multidisciplinary

Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications

Da Chen et al.

CHEMICAL REVIEWS (2012)

Article Chemistry, Physical

Sulfated Graphene Oxide as a Hole-Extraction Layer in High-Performance Polymer Solar Cells

Jun Liu et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

Article Chemistry, Multidisciplinary

Graphene Quantum Dots Derived from Carbon Fibers

Juan Peng et al.

NANO LETTERS (2012)

Article Multidisciplinary Sciences

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites

Michael M. Lee et al.

SCIENCE (2012)

Review Chemistry, Multidisciplinary

Polymer-Fullerene Bulk-Heterojunction Solar Cells

Christoph J. Brabec et al.

ADVANCED MATERIALS (2010)

Article Materials Science, Multidisciplinary

Graphene, a promising transparent conductor

Jonathan K. Wassei et al.

MATERIALS TODAY (2010)

Article Chemistry, Multidisciplinary

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells

Akihiro Kojima et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Review Energy & Fuels

Fabrication and processing of polymer solar cells: A review of printing and coating techniques

Frederik C. Krebs

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2009)

Article Chemistry, Multidisciplinary

Accurate measurement and characterization of organic solar cells

Vishal Shrotriya et al.

ADVANCED FUNCTIONAL MATERIALS (2006)

Article Materials Science, Multidisciplinary

Structure and optical properties of molybdenum disulphide (MoS2) thin film deposited by the dip technique

SC Ray

JOURNAL OF MATERIALS SCIENCE LETTERS (2000)