Journal
CHEMICAL COMMUNICATIONS
Volume 60, Issue 3, Pages 340-343Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc05382b
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A new lead tellurium borate material with a unique fundamental building block [B4O10] was synthesized and found to exhibit high birefringence. The structure-property relationship was discussed using first-principles calculations.
Herein, the first lead tellurium borate, PbTeB4O9, with an unprecedented fundamental building block [B4O10] was successfully synthesized. The near-parallel alignment of [B4O10] groups and [TeO3] polyhedra resulted in a high birefringence (0.099@1064 nm). The structure-property relationship was discussed by using the first-principles calculations.
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