Polymeric, metallic and carbon membranes for hydrogen separation: A review

Hydrogen (H2) as an energy carrier can deliver or/and store a huge amount of energy. Hydrogen can be used in internal combustion engines or in fuel cells to generate electricity, with only byproducts water and heat. It is no coincidence that it has been characterized as the energy carrier of the future. Nevertheless, irrespectively of its production method, raw hydrogen must first be separated/purified from other co-produced compounds. Among other separation methods membrane separation processes present numerous advantages and for this reason membrane technology has attracted the interest of many research groups worldwide.In this review article the main characteristics of three major membrane categories, namely polymeric, metallic and carbon membranes, are summarized. For each membrane material category, both their strengths and limitations are mentioned, discussed and highlighted. In addition, selected articles, mainly those which have been published recently, are reviewed and their highlighted evidences are presented and discussed.

Automated summary

Hydrogen serves as an efficient energy carrier with the capability to store and deliver a substantial amount of energy. Regardless of the production method, raw hydrogen needs to be separated/purified from other co-produced compounds. Membrane separation processes have gained significant attention due to their numerous advantages. This review article provides a summary of the main characteristics of three major membrane categories, namely polymeric, metallic, and carbon membranes. The strengths and limitations of each membrane material category are discussed, along with the review of selected articles and their highlighted evidence.