4.8 Article

Integrated Assessment of the Leading Paths to Mitigate CO2 Emissions from the Organic Chemical and Plastics Industry

Journal

ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 57, Issue 49, Pages 20571-20582

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.est.3c05202

Keywords

plastics; chemicals; decarbonization; carbon capture; bioliquids; circular economy

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The chemical industry contributes significantly to CO2 emissions, but the implementation of emerging decarbonization strategies and processes can lead to substantial reductions. However, achieving net-zero emissions is dependent on the global deployment of carbon capture and storage (CCS), as well as alternative feedstocks and proper waste treatment of plastics.
The chemical industry is a major and growing source of CO(2 )emissions. Here, we extend the principal U.S.-based integrated assessment model, GCAM, to include a representation of steam cracking, the dominant process in the organic chemical industry today, and a suite of emerging decarbonization strategies, including catalytic cracking, lower-carbon process heat, and feedstock switching. We find that emerging catalytic production technologies only have a small impact on midcentury emissions mitigation. In contrast, process heat generation could achieve strong mitigation, reducing associated CO2 emissions by similar to 76% by 2050. Process heat generation is diversified to include carbon capture and storage (CCS), hydrogen, and electrification. A sensitivity analysis reveals that our results for future net CO2 emissions are most sensitive to the amount of CCS deployed globally. The system as defined cannot reach net-zero emissions if the share of incineration increases as projected without coupling incineration with CCS. Less organic chemicals are produced in a net-zero CO2 future than those in a no-policy scenario. Mitigation of feedstock emissions relies heavily on biogenic carbon used as an alternative feedstock and waste treatment of plastics. The only scenario that delivers net-negative CO2 emissions from the organic chemical sector (by 2070) combines greater use of biogenic feedstocks with a continued reliance on landfilling of waste plastic, versus recycling or incineration, which has trade-offs.

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