4.6 Article

Investigation of Ce-based buffer layers on electrochemical performance of YSZ-based symmetric solid oxide fuel cells

Journal

CHEMICAL PHYSICS LETTERS
Volume 834, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.cplett.2023.140981

Keywords

SSOFCs; Ce-based buffer layer; Distribution of relaxation time; Electrochemical performance

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It has been found that the introduction of buffer layers improves the electrical performance of solid oxide fuel cells (SSOFCs). In this study, varying ratios of Gd-doped CeO2 were used as buffer layers in YSZ-based SSOFCs. The results demonstrate that the performance of SSOFCs is enhanced when a buffer layer is added, with the highest performance achieved using Ce0.8Gd0.2O2-delta (GDC20) as the buffer layer. This suggests that the use of GDC series buffer layers is an attractive strategy to optimize performance loss due to electrolyte-electrode interactions.
It is well known that the introduction of buffer layers can enhance the electrical performance of SSOFCs. Hence, we studied varying ratios of Gd-doped CeO2 as a buffer layer and applied it to YSZ-based SSOFCs. The results demonstrate that the performance is enhanced by adding a buffer layer to the single cell, which is superior compared to that without the buffer layer. The highest performance was obtained when Ce0.8Gd0.2O2-delta (GDC20) was used as the buffer layer. The results suggest the use of GDC series buffer layers as an attractive strategy to optimize the performance loss due to electrolyte-electrode interactions.

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