☆ 4.7 Article

Post-synthetic molecular modifications based on Schiff base condensation reactions for designing functional paddlewheel diruthenium(ii,ii) complexes

DALTON TRANSACTIONS (2024)

Related references

Note: Only part of the references are listed.

Article Chemistry, Inorganic & Nuclear

Effect of Equatorial Ligand Substitution on the Reactivity with Proteins of Paddlewheel Diruthenium Complexes: Structural Studies

Aaron Teran et al.

Summary: The study reveals that the reaction between [Ru2Cl(D-p-FPhF)(O2CCH3)3] and lysozyme forms adducts with the coordination of Asp side chains. The findings provide valuable insights into the reactivity of diruthenium complexes with proteins, offering useful information for the development of novel artificial diruthenium-containing metalloenzymes with potential applications in catalysis, biomedicine, and biotechnology.

INORGANIC CHEMISTRY (2023)

Add to Collection

Article Chemistry, Multidisciplinary

A Host-Guest Electron Transfer Mechanism for Magnetic and Electronic Modifications in a Redox-Active Metal-Organic Framework

Jun Zhang et al.

Summary: Host-guest electron transfer is a critical factor for functional changes in molecular framework systems. This study achieved reversible magnetic phase transition by adsorbing iodine and demonstrated a significant enhancement in electrical conductivity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Multidisciplinary

High Stabilization of Low Valency in a Homoleptic ortho-Hydroxybenzoate-bridged Paddlewheel Diruthenium(II,II) Complex

Wataru Kosaka et al.

Summary: A new palladium complex, [Ru-2(o-OHPhCO2)(4)(THF)(2)], was synthesized and characterized. The complex consists of two palladium atoms bridged by ortho-hydroxybenzoate and tetrahydrofuran ligands. The use of different hydroxybenzoate ligands resulted in the formation of different oxidation states, [Ru2(II,III)]. In one of the complexes, the formation of intramolecular hydrogen bonds stabilized the [Ru2(II,II)] species significantly.

CHEMISTRY LETTERS (2022)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Role of intramolecular hydrogen bonding in the redox chemistry of hydroxybenzoate-bridged paddlewheel diruthenium(II, II) complexes

Wataru Kosaka et al.

Summary: The synthesis of a series of trans-heteroleptic paddlewheel diruthenium(II, II) complexes with various hydroxy-substituted benzoate ligands is reported. The redox properties are linearly dependent on the acidity of the OH-substituted benzoic acids, but do not depend on the number of ortho-substituted hydroxy groups. The unexpected electron-withdrawing character of the o-OH groups could be attributed to the direct effect of intramolecular hydrogen bonding on the charge density on the carboxylate oxygen.

DALTON TRANSACTIONS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A metal-organic framework that exhibits CO2-induced transitions between paramagnetism and ferrimagnetism

Jun Zhang et al.

Summary: A CO2-responsive magnetic MOF has been developed in this study, which converts from ferrimagnetic to paramagnetic on CO2 adsorption, and returns to the ferrimagnetic state on CO2 desorption. This magnetic phase change, along with modifications to the electronic conductivity and permittivity of the MOF, are electronically stabilized by guest CO2 molecules accommodated in the framework.

NATURE CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Spontaneous N2 formation by a diruthenium complex enables electrocatalytic and aerobic oxidation of ammonia

Michael J. Trenerry et al.

Summary: The study presents a stable metal-metal complex that produces dinitrogen from ammonia at low temperatures without the need for exogenous oxidizing reagents or high potentials. It also acts as a redox mediator for the oxidation of ammonia, operating at potentials as low as -255 mV and below the potential for the oxygen reduction reaction in alkaline conditions, showing thermodynamic viability for future development of DAFCs.

NATURE CHEMISTRY (2021)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Electrochemistry of metal-metal bonded diruthenium complexes

Eric Van Caemelbecke et al.

Summary: This review summarizes the electrochemistry of metal-metal bonded diruthenium complexes with different core structures and bridging ligands, focusing on the effects of electrochemical solvent properties and compound characteristics. Most studies have been conducted in nonaqueous media, with redox reactions primarily involving the diruthenium core.

COORDINATION CHEMISTRY REVIEWS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Magnet Creation by Guest Insertion into a Paramagnetic Charge-Flexible Layered Metal-Organic Framework

Jun Zhang et al.

Summary: This study demonstrates the transformation of nonmagnetic materials to spontaneous magnets through chemical modification, based on the adsorbed guest molecule. The magnetic phase can be altered to either a ferrimagnet or an antiferromagnet, depending on the guest molecule accommodated. This represents a significant advancement in materials science research.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Charge Manipulation in Metal-Organic Frameworks: Toward Designer Functional Molecular Materials

Hitoshi Miyasaka

Summary: Multi-dimensional coordination frameworks with controllable charge states offer fascinating targets for the design of electronic/magnetic functional materials. D/A metal-organic frameworks can be designed by assembling electron donor and electron acceptor units with electronically conjugated linkages, allowing precise tuning of charge distribution between internal subunits by varying their electronic structure. The diverse charge states, anisotropic framework, and porous nature of D/A-MOFs are correlated with their bulk electronic and magnetic properties.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2021)

Add to Collection

Article Chemistry, Physical

Chiral paddle-wheel diruthenium complexes for asymmetric catalysis

Taku Miyazawa et al.

NATURE CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Hammett-law Correlation in the Electron-donation Ability of trans-Heteroleptic Benzoate-bridged Paddlewheel-type Diruthenium(II,II) Complexes

Yoshihiro Sekine et al.

CHEMISTRY LETTERS (2018)

Add to Collection

Article Multidisciplinary Sciences

Gas-responsive porous magnet distinguishes the electron spin of molecular oxygen

Wataru Kosaka et al.

NATURE COMMUNICATIONS (2018)

Add to Collection

Article Chemistry, Inorganic & Nuclear

The effect of chlorine and fluorine substitutions on tuning the ionization potential of benzoate-bridged paddlewheel diruthenium(II, II) complexes

Wataru Kosaka et al.

DALTON TRANSACTIONS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Control of Charge Transfer in Donor/Acceptor Metal-Organic Frameworks

Hitoshi Miyasaka

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Tuning of the ionization potential of paddlewheel diruthenium(II, II) complexes with fluorine atoms on the benzoate ligands

Hitoshi Miyasaka et al.

DALTON TRANSACTIONS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Control of Charge Transfer in a Series of Ru2II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magnetic/Conducting Materials

Hitoshi Miyasaka et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru2]2TCNQ Charge-Transfer System

Natsuko Motokawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Magnetic interactions in one-, two-, and three-dimensional assemblies of dinuclear ruthenium carboxylates

Masahiro Mikuriya et al.

COORDINATION CHEMISTRY REVIEWS (2006)

Add to Collection

Article Spectroscopy

Background defining during the imine formation reaction in FT-IR liquid cell

H Namli et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2006)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Unligated diruthenium(II,II) tetra(trifluoroacetate):: The first X-ray structural study, thermal compressibility, Lewis acidity, and magnetism

EV Dikarev et al.

INORGANIC CHEMISTRY (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Water-soluble diruthenium complexes bearing acetate and carbonate bridges: highly efficient catalysts for aerobic oxidation of alcohols in water

Naruyoshi Komiya et al.

CHEMICAL COMMUNICATIONS (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Building blocks for 2D molecule-based magnets: The diruthenium tetrapivalate monocation [Ru(II/III)2(O(2)CtBu)(4)](+)

TE Vos et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Recent developments in the synthesis and properties of diruthenium tetracarboxylates

MAS Aquino

COORDINATION CHEMISTRY REVIEWS (2004)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Neutral paddlewheel diruthenium complexes with tetracarboxylates of large π-conjugated substituents:: Facile one-pot synthesis, crystal structures, and electrochemical studies

S Furukawa et al.

INORGANIC CHEMISTRY (2004)

Add to Collection

Article Polymer Science

New synthesis, electroluminescence, and photophysical properties of poly [(formylphenyl)methylsilanediyl] and its derivatives

D Vyprachticky et al.

MACROMOLECULES (2002)

Add to Collection

Article Chemistry, Inorganic & Nuclear

The first crystal structure of a one-dimensional chain of linked Ru-II=Ru-II units

H Miyasaka et al.

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (2001)

Add to Collection

© Peeref 2019-2024. All rights reserved.